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The turbulent flow field inside the cylinder plays a major role in spark ignition (SI) engines. Multiple phenomena that occur during the high pressure part of the engine cycle, such as early flame kernel development, flame propagation and gas-to-wall heat transfer, are influenced by in-cylinder turbulence. Turbulence inside the cylinder is primarily generated via high shear flows that occur during the intake process, via high velocity injection sprays and by the destruction of macro-scale motions produced by tumbling and/or swirling structures close to top dead center (TDC) . Understanding such complex flow phenomena typically requires detailed 3D-CFD simulations. Such calculations are computationally very expensive and are typically carried out for a limited number of operating conditions. On the other hand, quasi-dimensional simulations, which provide a limited description of the in-cylinder processes, are computationally inexpensive.

Autoignition correlations are widely used to predict knock in internal combustion engines as opposed to detailed kinetics mechanisms involving hundreds of reactions due to computational cost. Several autoignition correlations exist in the literature for different fuels, and their functional form depends on the operating parameters like fuel type and temperature range, among other things. In the literature different types of correlations are proposed for gasoline fuel, but to the best of the authors’ knowledge none of these correlations can be used for gasoline-ethanol blends with varying levels of ethanol percentage and a wide range of equivalence ratios and temperatures. In this paper, a new empirical correlation is developed to predict the autoignition of gasoline-ethanol blends over a wide range of temperatures including Negative Temperature Coefficient (NTC) region.

In order to meet the increasingly stringent emissions standard it is imperative that a two pronged approach is pursued for reduction of tailpipe emissions. In this regard emissions, and often the exhaust compositions, are needed to be controlled both at its source and then subsequently cleaned up at the exhaust system. In addition, an aftertreatment system often consists of an array of catalysts and its performance depends on the transient characteristics of the exhaust gas composition. To complicate the matter furthermore, relevant technologies are still evolving at a rapid pace. Consequently, an aftertreatment modeling approach should not only be system based but also offer a high level of configurability. Thus a system level approach that includes a model of an engine and vehicle may provide an efficient means to analyze system performance and examine relative effects of competing phenomena and technologies.

In order to reduce the cost of exhaust aftertreatment development, OEMs are increasingly relying on simulation of catalysts, traps and associated control systems. In this regards, for example, considerable progresses have been made on modeling diesel particulate filters. The work described in this paper was sought to provide a valid diesel particulate filter (DPF) model for coupling with engine/vehicle models under the same toolbox. A comprehensive two-level modeling approach, including a lumped parameter model and a detailed 1-D 3-layer-kinetics model, has been proposed for modeling wall-flow diesel particulate filters. Both are capable of modeling virtually all aspects of filter performance in terms of deep-bed filtration, particulate matter loading and filter regeneration.

This article describes a system level 1D simulation tool that has been constructed on the Quasi-steady (QS) method. By assuming that spatial changes are much greater than the temporal ones, rigorous 1D governing equations can be considerably simplified thus becoming less computationally demanding to solve and therefore suitable for control oriented modeling purposes. With the proposed tool exhaust pipe wall temperature profiles, including multiple-wall-layer configurations, are solved through a finite difference scheme. Momentum equation is included for predicting pressure losses due to frictions and geometric irregularity. Exhaust fluid properties (transport and thermodynamic) are evaluated according to NASA or JANAF polynomial thermal data basis. The proposed tool allows the consideration of an arbitrary number of chemical species and reactions in the entire system. A novel semi-automatic approach was developed to handle catalytic reaction kinetics intuitively.

Recently there has been a substantial interest in adopting asymmetric geometry design inside wall-flow diesel particular filters (DPFs) with larger inlet channel width to accommodate soot/ash accumulation and to reduce back pressure and thus to increase filter operation life time. The current work is sought to develop a model based approach to investigate various aspects of this strategy and to compare results with conventional channel design. This paper describes assumptions and modeling methodologies used to evaluate the impact of asymmetries arising out of geometric design as well as due to ash deposition/accumulation on the overall pressure drop across the filter. Special attention is given to the challenges and strategies associated with flow and thermal solutions (during soot loading or regeneration) since transient ash accumulation causes a time varying reduction of effective wall-flow filtration length.

It has recently been suggested in an experimental study that an aged DOC could be net consumer of engine out NO2 (Katare et al, 2007) thus inhibiting the fast reaction (2NH3 + NO + NO2 => 2N2+3H2O) in an SCR that might follow. Both engine test and flow reactor results indicated that at low temperatures CO and HC reduces NO2 to NO and that CO is much better reductant than HC. The present study investigates the mechanistic story behind this experimentally observed phenomenon by means of a global reaction mechanism. It also investigates the role of CO inhibition of NO oxidation at higher temperature which also plays key role in the overall oxidation efficiency of a DOC. Once a suitable mechanism is defined by comparing against measurements, the current study will use it to examine conditions under which DOC can destroy NO2 and to propose possible strategies to avoid NO2 consumption in order to obtain high SCR efficiency.

A zero-dimensional model is introduced that combines recently presented empirical relationships for diesel jet penetration and flame lift-off length in order to produce a realistic heat release rate and predict the temperature and equilibrium species concentrations in five zones within the combustion chamber. The new model describes the compression, combustion and expansion portions of a diesel cycle. During fuel injection and combustion, the temperature, geometry, and composition of five zones are calculated: 1) vaporizing fuel and air, 2) vaporized reactants, 3) premixed products, 4) adiabatic flame sheath, and 5) surrounding charge gas. The apparent heat release rate predicted by the model is compared with data from a constant volume combustion vessel (CVCV) and two single-cylinder direct-injection diesel engines. The rate of charge air entrainment is determined from the correlation of a non-vaporizing, non-reacting jet with no wall impingement.

The potential of fuel cells as an automotive power source is well recognized due to their high efficiency and zero tailpipe emissions. However, significant technical and economic hurdles need to be overcome in order to make this technology commercially viable. A proton-exchange membrane (PEM) fuel cell model has been developed to assess some of these technical issues. The fuel cell model can be operated in a standalone mode or it can be integrated with vehicle and fuel supply system models. A detailed thermal model of the fuel cell stack was used to identify significant design parameters that affect the performance of PEM fuel cell vehicles. The integrated vehicle model was used to explore the relative benefits of hybridization options.

Exhaust NOx and particulate measurements were obtained at equivalent operating conditions in a direct-injection compression ignition engine for diesel and diethyl ether fuel. Particulate levels for diethyl ether were very low relative to the diesel fuel and did not increase significantly until the fuel to oxygen equivalence ratio was above 0.8. The log of fuel specific NOx for both the diesel and diethyl ether fuel were found to correlate well with the inverse of adiabatic flame temperature as has been observed by others in previous research. A newly defined heat release averaged, adiabatic flame temperature improved the correlation of both fuels. Differences in the correlations of the two fuels with this newly defined temperature were smaller than the scatter of the data.

The combustion process in diesel engines deposits soot on the in-cylinder surfaces. Previous works have suggested that these soot deposits eventually break off during cylinder blow-down and the exhaust stroke and contribute significantly to exhaust soot emissions. In order to better understand this potential pathway to soot emissions, the authors recently investigated combusting fuel-jet/wall interactions in a diesel engine. This work, published as a companion paper, showed how soot escaped from the combusting fuel jet and was brought in close proximity to the wall so that it could become a deposit. The current study extends this earlier work with laser-extinction measurements of the soot-deposition rate in the same single-cylinder, heavy-duty DI diesel engine. Measurements were made by passing the beam of a CW-diode laser through a window in the piston bowl rim that was in-line with one of the fuel jets.

Over the past decade, laser diagnostics have improved our understanding of many aspects of diesel combustion. However, interactions between the combusting fuel jet and the piston-bowl wall are not well understood. In heavy-duty diesel engines, with typical fuels, these interactions occur with the combusting vapor-phase region of the jet, which consists of a central region containing soot and other products of rich-premixed combustion, surrounded by a diffusion flame. Since previous work has shown that the OH radical is a good marker of the diffusion flame, planar laser-induced fluorescence (PLIF) imaging of OH was applied to an investigation of the diffusion flame during wall interaction. In addition, simultaneous OH PLIF and planar laser-induced incandescence (PLII) soot imaging was applied to investigate the likelihood for soot deposition on the bowl wall.

Significant reductions of particulate matter (PM) and nitrogen oxides (NOx) emissions from diesel engines have been realized through fueling with water-fuel emulsions. However, the physical and chemical in-cylinder mechanisms that affect these pollutant reductions are not well understood. To address this issue, laser-based and chemiluminescence imaging experiments were performed in an optically-accessible, heavy-duty diesel engine using both a standard diesel fuel (D2) and an emulsion of 20% water, by mass (W20). A laser-based Mie-scatter diagnostic was used to measure the liquid-phase fuel penetration and showed 40-70% greater maximum liquid lengths with W20 at the operating conditions tested. At some conditions with low charge temperature or density, the liquid phase fuel may impinge directly on in-cylinder surfaces, leading to increased PM, HC, and CO emissions because of poor mixing.

To better understand the factors affecting soot formation in diesel engines, in-cylinder soot and diffusion flame lift-off were measured in a heavy-duty, direct-injection diesel engine. Measurements were obtained at two operating conditions using two commercial diesel fuels and a range of oxygenated paraffinic fuel blends. A line-of-sight laser extinction diagnostic was improved and employed to measure the relative soot concentration within the jet (“jet-soot”) and the rates of soot-wall deposition on the piston bowl-rim. An OH chemiluminescence imaging technique was developed to determine the location of the diffusion flame and to measure the lift-off lengths of the diffusion flame to estimate the amount of oxygen entrainment in the diesel jets. Both the jet-soot and the rate of soot-wall deposition were found to decrease with increasing fuel oxygen-to-carbon ratio (O/C) over a wide range of O/C.

A single cylinder, Cummins NH, direct-injection, diesel engine has been operated in order to evaluate the effects of aromatic content and aromatic structure on diesel engine particulates. Results from three fuels are shown. The first fuel, a low sulfur Chevron diesel fuel was used as a base fuel for comparison. The other fuels consisted of the base fuel and 10% by volume of 1-2-3-4 tetrahydronaphthalene (tetralin) a single-ring aromatic and naphthalene, a double-ring aromatic. The fuels were chosen to vary aromatic content and structure while minimizing differences in boiling points and cetane number. Measurements included exhaust particulates using a mini-dilution tunnel, exhaust emissions including THC, CO2, NO/NOx, O2, injection timing, two-color radiation, soluble organic fraction, and cylinder pressure. Particulate measurements were found to be sensitive to temperature and flow conditions in the mini-dilution tunnel and exhaust system.

The two-color method for measuring temperature and optical thickness of soot (KL) has become a standard diagnostic tool for the evaluation of engine designs and technologies relative to soot formation and flame temperature. Implementation of the two-color technique typically requires two cameras or a set of half-pass mirrors and optical narrow band-pass filters. In this paper, a technique for collecting and interpreting two-color images with a single calibrated camera without image splitting and filtering hardware is demonstrated and discussed. This method uses a relatively inexpensive commercial, 10-bit, RGB color, CCD camera capable of 16 μs exposure times. The CCD has published spectral response curves in the visible range, but a method for obtaining the spectral response for the optical system using a monochromator is discussed.

An S.I. combustion model has been developed for application in phenomenological engine simulations. The model is based on a turbulent flame concept, linked to an in-cylinder flow and turbulence calculation. The flame front is assumed to spread from the spark plug and propagate through the cylinder, while interacting with the combustion chamber geometry. The model predictions were compared to combustion rate measurements made in a single cylinder four valve passenger car engine. The data spanned a wide range of operating conditions, from an idle timing sweep, to part load EGR and mixture ratio sweeps, to a wide open throttle speed sweep. The results of the comparisons showed a generally good agreement. Some difficulties were encountered at idle, where cycle-to-cycle variability makes modeling difficult especially at early timing settings.

A model for oil consumption due to in-cylinder evaporation of oil in reciprocating engines, has been developed. The model is based on conservation of mass and energy on the surface of the oil film left on the cylinder by a piston ring pack, at the oil/gas interface, and also conservation of energy within the oil film and cylinder/coolant interface. The model is sensitive to in-cylinder conditions and is part of an integrated model of ring pack performance, which provides the geometry of the oil film left by the ring pack on the cylinder. Preliminary simulation results indicate that a relatively small but not insignificant fraction (2-5%) of the total oil consumption may be due to evaporation losses for a heavy duty diesel at the rated condition. The evaporation rate was shown to be sensitive to oil grade and upper cylinder temperature. Much of these losses occur during the non-firing half of the cycle.

In-cylinder measurements of soot particle size, number density, and temperature have been made using optical measurements in a direct injection diesel engine. The measurements were made at one location approximately 5 mm long and 1.5 mm wide above the bowl near the head. Two optical techniques were used simultaneously involving light scattering, extinction and radiation. An optical probe was designed and mounted in a modified exhaust valve which introduced a beam of light into the cylinder and collected the scattered and radiating light from the soot. The resulting measurements were semi-quantitative, giving an absolute uncertainty on the order of ± 50% which was attributed mainly to the uncertainty of the optical properties of the soot and the heterogeneous nature of the soot cloud. Measurements at three speeds and three overall equivalence ratios were made.

Measurements have been made to determine the effect of piston crown surface properties on combustion. Back-to-back engine tests were conducted to compare surface modified pistons to a production piston. Each modified piston was found to prolong combustion duration. Porous coatings and a non porous, roughened piston were observed to increase fuel consumption. Increase in fuel consumption was determined to be the result of increased heat release duration. The data show surface roughness alone affects the duration of heat release. The shift in magnitude of the centroid of heat release was similar to the shift observed in insulated engine experiments.