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To date, the DME combustion mechanism has been investigated by in-cylinder gas sampling, numerical calculations and observation of combustion radicals. It has been possible to quantify the emission intensities of in-cylinder combustion using a monochromator, and to observe the emitting species as images by using band-pass filters. However, the complete band images were not observed since the broadband (thermal) intensity may be stronger than band spectra intensities. Emission intensities of DME combustion radicals from a pre-mixed burner flame have been measured using a spectroscope and photomultiplier. Results were compared to other fuels, such as n-butane and methane, then, in this study, to better understand the combustion characteristics of DME, emission intensities near CH bands of an actual DI diesel engine fueled with DME were measured, and band spectra emitted from the engine were defined. Near TDC, emission intensities did not vary with wavelength.

To better understand the combustion characteristics of DME, emission intensities of DME combustion radicals from a pre-mixed burner flame were measured by a spectroscope and photomultiplier, Results were compared to other fuels, such as methane and butane. Large peaks in the band spectra from pre-mixed and diffusion DME flames were found near 310 nm, 430 nm, and 515 nm, arising from OH, CH and C2, respectively. The DME emission intensities decreased with increasing the equivalence ratio in this study. Notably, the relative decrease in the C2 band spectra peak was greater than that of the OH band. Comparing the pre-mixed DME and butane flames, the butane band spectra peaks were similar in shape, but much stronger than those for DME. However, it was remarkable that CH and C2 band spectra peaks decreased only slightly with increase in equivalence ratio compared to the DME case.

We developed a novel ignition method called laser breakdown-assisted long-distance discharge ignition (LBALDI) that combines laser breakdown with a discharge to realize lean combustion. The creation of laser breakdown plasma between electrodes for discharge enables discharges over longer distances than those of conventional sparkplug as inferred from laser-triggered lightning or laser-triggered gas switches. This method should help realize volumetric ignition through the creation of a long-distance discharge. Experiments on the fundamental discharge and ignition of methane/air mixtures were conducted. The optimum incident time of the laser prior to the application of a high voltage was found to reduce the sparkover voltage and markedly reduce the voltage required by LBALDI under pressurized air conditions. In the ignition experiment, LBALDI showed the fastest heat release rate at the lean flammable limit.

Technology for the enhancement of compression ignition for a natural-gas homogeneous charge compression ignition (HCCI) engine was developed using nonthermal plasma. Specifically, nonthermal plasma was utilized to enhance the ignition of the methane/air premixture by irradiating it in an intake tube. The effect of the irradiation on compression ignition was investigated using a rapid compression and expansion machine; the ignition delay was found to shorten by the influence of irradiation. The dependence of the ignition delay time on the temperature at the end of compression was determined. Chemical analysis of the plasma-processed gas was performed using a gas detection tube as a simple method and ion-attachment ionization mass spectrometry (IAMS) as a novel method. A chemical kinetic simulation was also conducted to examine the temperature dependence of the ignition delay.