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The effect that thermally and compositionally stratified flowfields have on the spatial progression of iso-octane-fueled homogeneous charge compression ignition (HCCI) combustion were directly observed using highspeed chemiluminescence imaging. The stratified in-cylinder conditions were produced by independently feeding the intake valves of a four-valve engine with thermally and compositionally different mixtures of air, vaporized fuel, and argon. Results obtained under homogeneous conditions, acquired for comparison to stratified operation, showed a small natural progression of the combustion from the intake side to the exhaust side of the engine, a presumed result of natural thermal stratification created from heat transfer between the in-cylinder gases and the cylinder walls. Large differences in the spatial progression of the HCCI combustion were observed under stratified operating conditions.

Planar laser-induced fluorescence (PLIF) has become a useful diagnostic for the quantification of in-cylinder flowfield conditions, and in many applications determining the homogeneity of the in-cylinder flowfield is of primary importance. In some cases, noise associated with this imaging technique (i.e., camera noise, shot-to-shot laser energy variation, and laser sheet profile variations) can dominate the flowfield inhomogeneities, leading to biased mixture stratification statistics. Presented herein are three data normalization schemes (global-, image-, and ray-mean) that can be used to correct for these noise sources when assessing mixture stratification from PLIF data. The normalization schemes are applied to in-cylinder PLIF data obtained over a wide range of inhomogeneity levels, and the conditions over which the use of each normalization scheme is appropriate are discussed.

The effect of the ring pack storage mechanism on the hydrocarbon (HC) emissions from an air-cooled utility engine has been studied using a simplified ring pack model. Tests were performed for a range of engine load, two engine speeds, varied air-fuel ratio and with a fixed ignition timing using a homogeneous, pre-vaporized fuel mixture system. The integrated mass of HC leaving the crevices from the end of combustion (the crank angle that the cumulative burn fraction reached 90%) to exhaust valve closing was taken to represent the potential contribution of the ring pack to the overall HC emissions; post-oxidation in the cylinder will consume some of this mass. Time-resolved exhaust HC concentration measurements were also performed, and the instantaneous exhaust HC mass flow rate was determined using the measured exhaust and cylinder pressure.

A direct calibration has been performed on laser-induced fluorescence measurements of the oil film in a single cylinder air-cooled research engine by simultaneously measuring the minimum oil film thickness by the capacitance technique. At the minimum oil film thickness the capacitance technique provides an accurate measure of the ring-wall distance, and this value is used as a reference for the photomultiplier voltage, giving a calibration coefficient. This calibration coefficient directly accounts for the effect of temperature on the fluorescent properties of the constituents of the oil which are photoactive. The inability to accurately know the temperature of the oil has limited the utility of off-engine calibration techniques. Data are presented for the engine under motoring conditions at speeds from 800 - 2400 rpm and under varying throttle positions.

The mixing between the flows introduced through different intake valves of a four-valve engine was investigated optically. Each valve was fed from a different intake system, and the relative sensitivity to different flow parameters (manipulated with the goal of enhancing the bulk in-cylinder stratification) was investigated. Flow manipulation was achieved in three primary ways: modifying the intake runner geometry upstream of the head, introducing flow-directing baffles into the intake port, and attaching flow break-down screens to the intake valves. The relative merits of each flow manipulation method was evaluated using planar laser-induced fluorescence (PLIF) of 3-pentanone, which was introduced to the engine through only one intake valve. Images were acquired from 315° bTDC through 45° bTDC, and the level of in-cylinder stratification was evaluated on an ensemble and cycle-to-cycle basis using a novel column-based probability distribution function (PDF) contour plot.

The role of mixture stratification on combustion rate has been investigated in a constant volume combustion vessel in which mixtures of different equivalence ratios can be added in a spatially and temporally controlled fashion. The experiments were performed in a regime of low fluid motion to avoid the complicating effects of turbulence generated by the injection of different masses of fluid. Different mixture combinations were investigated while maintaining a constant overall equivalence ratio and initial pressure. The results indicate that the highest combustion rate for an overall lean mixture is obtained when all of the fuel is contained in a stoichiometric mixture in the vicinity of the ignition source. This is the result of the high burning velocity of these mixtures, and the complete oxidation which releases the full chemical energy.

The effect of the presence of liquid fuel in the intake manifold on unburned hydrocarbon (HC) emissions of a spark-ignited, carbureted, air-cooled V-twin engine was studied. To isolate liquid fuel effects due to the poor atomization and vaporization of the fuel when using a carburetor, a specially conditioned homogeneous, pre-vaporized mixture system was developed. The homogeneous mixture system (HMS) consisted of an air assisted fuel injection system located approximately 1 meter upstream of the intake valves. The results from carburetor and HMS are compared. To verify the existence of liquid fuel in the manifold, and to obtain an estimate of its mass, a carburetor-mounted liquid fuel injection (CMLFI) system was also implemented. The conditions tested were 10% and 25% load at 1750 RPM, and 25%, 50%, and 100% at 3060 RPM. The results of the comparison show that the liquid fuel in the intake manifold does not have a statistically significant influence on the averaged HC emissions.

Measurements were made of the in-cylinder fluid velocities in a crankcase compression, piston ported two-stroke engine under both motored and fired operating conditions to investigate the effect of combustion on the scavenging process. The engine was modified to allow optical access to the clearance volume and was operated in a burst fired manner, where the firing sequence was controlled by modulating the fuel delivered to the crankcase. The burst fired sequence consisted of 30 cycles, of which there were twelve consecutive cycles where fuel was injected into the crankcase. The engine was operated at a speed of 500 RPM, with a delivery ratio of 0.54, and a fuel-air equivalence ratio of 1.28. Laser Doppler Velocimetry was used to measure two components of the in-cylinder fluid velocity at five locations in the cylinder head cup during the burst fired operation of the engine.

The contribution of fuel adsorption in engine oil and its subsequent desorption following combustion to the engine-out hydrocarbon (HC) emissions of a spark-ignited, air-cooled, V-twin utility engine was studied by comparing steady state and cycle-resolved HC emission measurements from operation with a standard full-blend gasoline, and with propane, which has a low solubility in oil. Experiments were performed at two speeds and three loads, and for different mean crankcase pressures. The crankcase pressure was found to impact the HC emissions, presumably through the ringpack mechanism, which was largely unaltered by the different fuels. The average and cycle-resolved HC emissions were found to be in good agreement, both qualitatively and quantitatively, for the two fuels. Further, the two fuels showed the same response to changes in the crankcase pressure. The solubility of propane in the oil is approximately an order of magnitude lower than for gasoline.

Engine tests were conducted to study the effect of fuel-air mixture preparation on the combustion and emission performance of a two-stroke direct-injection engine. The in-cylinder mixture distribution was altered by changing the injection system, injection timing, and by substituting the air in an air-assisted injector with nitrogen. Two injection systems which produce significantly different mixtures were investigated; an air-assisted injector with a highly atomized spray, and a single-fluid high pressure-swirl injector with a dense penetrating spray. The engine was operated at overall A/F ratios of 30:1, where stratification was necessary to ensure stable combustion; and at 20:1 and 15:1 where it was possible to operate in a nearly homogeneous mode. Moderate engine speeds and loads were investigated. The effects of the burning-zone A/F ratio were isolated by using nitrogen as the working fluid in the air-assist injector.

The scavenging process in a direct-injection two-stroke research engine was examined by using an electromagnetically controlled poppet valve to sample the trapped charge. A physical model was developed to characterize the scavenging based solely on the measured trapped gas composition. This method obviates the need to measure the post-combustion composition of the trapped charge, which significantly eases the sampling valve requirements. The valve that was developed proved to be very robust and was able to sample over 30% of the trapped mass at 3000 rpm. The measured scavenging efficiency was found to agree well with the non-isothermal two-zone perfect mixing limit of scavenging. The scavenging efficiency was found to increase with delivery ratio, and was nearly independent of speed.

The KIVA 3V code has been applied to predict combustion chamber heat flux in an air-cooled utility engine. The KIVA heat flux predictions were compared with experimentally measured data in the same engine over a wide range of operating conditions. The measured data were found to be approximately two times larger than the predicted results, which is attributed to the omission of chemical heat release in the near-wall region for the heat transfer model applied. Modifying the model with a simple scaling factor provided a good comparison with the measured data for the full range of engine load, heat flux sensor location, air-fuel ratio and spark timings tested. The detailed spatially resolved results of the KIVA predictions were then used to develop a simplified model of the combustion chamber temporally integrated heat flux using an artificial neural network (ANN).

To experimentally investigate evaporating sprays under conditions experienced in high speed direct-injection (HSDI) diesel engines, the exciplex LIF technique with the TMPD / naphthalene dopant system was applied in a combustion-type constant-volume spray chamber. The chamber allows spark ignition of a slightly rich C2H2-air mixture, and subsequent fuel injection into the high temperature and pressure products. A detailed set of calibration experiments has been performed in order to quantify the TMPD fluorescence signal. It has been demonstrated that the TMPD fluorescence intensity is directly proportional to concentration, is independent of the chamber pressure, and was not sensitive to quenching by either water vapor or carbon dioxide. Therefore, the temperature dependence of the TMPD fluorescence was the only correction factor required for quantitative measurements. Using a dual heated-jet experiment, the temperature dependence of TMPD fluorescence up to 1000 K was measured.

The effects of augmented mixing through the use of an auxiliary gas injection (AGI) were investigated in a direct-injection gasoline engine operated at a 22:1 overall air-fuel ratio, but with retarded injection timing such that the combustion was occurring in a locally rich mixture as evident by the elevated CO emissions. Two AGI gas compositions, nitrogen and air, were utilized, the gas supply temperature was ambient, and a wide range of AGI timings were investigated. The injected mass was less than 10% of the total chamber mass. The injection of nitrogen during the latter portion of the heat release phase resulted in a 25% reduction in the CO emissions. This reduction is considered to be the result of the increased mixing rate of the rich combustion products with the available excess air during a time when the temperatures are high enough to promote rapid oxidation.

Planar laser-induced fluorescence of 3-pentanone doped into the fuel (iso-octane) and OH, which is present in the combustion products, was performed in an optically accessible direct-injection spark-ignition (DISI) engine under stratified and homogeneous operating conditions. A wall-guided, swirl-based combustion chamber was utilized, and experiments were performed for light load, where the fuel-air equivalence ratio was 0.3, and high load conditions, with an equivalence ratio of 0.7, at speeds of 600 and 1200 rpm. The 3-pentanone images were calibrated through the use of a premixed charge condition of known equivalence ratio, with corrections applied for number density changes due to combustion. At the light load condition combustion of the highly stratified fuel cloud was directly measured for the first time. The equivalence ratio of the mixture at the flame front was found to be in the range from 0.5 - 0.8 for optimized combustion conditions in this engine.

Vapor concentration measurements were performed for two unit injectors typically found in small- and medium-bore applications under evaporating conditions similar to those experienced in Diesel engines. Ambient gas temperatures of 800 and 1000 K and an ambient density of 15 kg/m3 were investigated using a constant volume combustion-type spray chamber. The exciplex laserinduced fluorescence technique with TMPD/naphthalene doped into the fuel was used to quantitatively determine the vapor-phase concentration and liquid-phase extent. The vapor-phase concentration was quantified using a previously developed method that includes corrections for the temperature dependence of the TMPD fluorescence, laser sheet absorption, and the laser sheet intensity profile. The effect of increasing ambient temperature (1000 vs. 800 K) was significant on intact liquid length, and on the spray-spreading angle in the early portion of the injection period.

The noise characteristics of four camera systems representative of those typically used for laser-imaging experiments (a back-illuminated slow-scan camera, a frame-straddling slow-scan camera, an intensified slow-scan camera and an intensified video-rate camera) were investigated, and the results are presented as a function of the signal level and illumination level. These results provide the maximum possible signal-to-noise ratio for laser-imaging experiments, and represent the limit of quantitative signal interpretation. A calibration strategy for engine data that limits the uncertainties associated with thermodynamic and optical correction was presented and applied to engine data acquired with two of the camera systems. When a rigorous analysis of the signal is performed it is seen that shot noise limits the quantitative interpretation of the data for most typical laser-imaging experiments, and obviates the use of single-pixel data.

A spectroscopic diagnostic system was designed to study the effects of different engine parameters on the chemiluminescence characteristic of HCCI combustion. The engine parameters studied in this work were intake temperature, fuel delivery method, fueling rate (load), air-fuel ratio, and the effect of partial fuel reforming due to intake charge preheating. At each data point, a set of time-resolved spectra were obtained along with the cylinder pressure and exhaust emissions data. It was determined that different engine parameters affect the ignition timing of HCCI combustion without altering the reaction pathways of the fuel after the combustion has started. The chemiluminescence spectra of HCCI combustion appear as several distinct peaks corresponding to emission from CHO, HCHO, CH, and OH superimposed on top of a CO-O continuum. A strong correlation was found between the chemiluminescence light intensity and the rate of heat release.

An axisymmetric one-dimensional finite difference model has been developed to investigate the optimization of external fins on a cylindrical tube with a non-uniform heat flux applied to the inner surface. The heat flux boundary condition applied to the inner surface was determined from detailed 3-dimensional calculations using the KIVA code. The external convective boundary condition was determined from published correlations. This model encompasses the basic geometry of an air-cooled engine cylinder. The model was computationally efficient and allowed for the optimization of the fin length of each fin and its location. A genetic algorithm optimization procedure was utilized. The results show that optimum usage of material is obtained from fins of comparable length distributed over the entire outer cylinder, in spite of the concentrated heat flux at the upper end of the cylinder. The results indicate the important role of axial conduction in the thermal energy balance of this system.

Combustion under stratified operating conditions in a direct-injection spark-ignition engine was investigated using simultaneous planar laser-induced fluorescence imaging of the fuel distribution (via 3-pentanone doped into the fuel) and the combustion products (via OH, which occurs naturally). The simultaneous images allow direct determination of the flame front location under highly stratified conditions where the flame, or product, location is not uniquely identified by the absence of fuel. The 3-pentanone images were quantified, and an edge detection algorithm was developed and applied to the OH data to identify the flame front position. The result was the compilation of local flame-front equivalence ratio probability density functions (PDFs) for engine operating conditions at 600 and 1200 rpm and engine loads varying from equivalence ratios of 0.89 to 0.32 with an unthrottled intake. Homogeneous conditions were used to verify the integrity of the method.