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Ignition delay time is key to any hydrocarbon combustion process. In that sense, this parameter has to be known accurately, and especially for internal combustion engine applications. Combustion timing is one of the most important factors influencing overall engine performances like power output, combustion efficiency, emissions, in-cylinder peak pressure, etc. In the case of low temperature combustion (LTC) mode (e.g. HCCI mode), this parameter is controlled by chemical kinetics. In this paper, an ignition delay time model including 7 direct reactions and 13 species coupled with a temperature criterion is described. This mechanism has been obtained from the previous 26-step n-heptane reduced mechanism, focusing on the low temperature region which is the most important phase during the two stage combustion process. The complete model works with 7 reactions until the critical temperature is reached, leading to the detection of the ignition delay time value.

This work reports on the application of spectroscopic measurements coupled with data processing techniques in order to study, in terms of spectral emissions, the dynamic of the HCCI (Homogeneous charge compression ignition) combustion that occurs inside the combustion chamber of an optically accessible direct injection Diesel engine. A pre-processing of the recorded spectra is required for a correct analysis. The procedure of pre-processing consists of two main steps, that is: noise filtering with a technique based on the POD (Proper Orthogonal Decomposition); estimate and subtraction of the baseline. The analysis of the dynamics of the recorded spectra was carried out by the estimates of the synchronous and asynchronous 2D correlation spectra.

In order to meet the requirements in the stringent emission regulations, more and more research work has been focused on homogeneous charge compression ignition (HCCI) and partially premixed combustion (PPC) or partially premixed compression ignition (PCCI) as they have the potential to produce low NOx and soot emissions without adverse effects on engine efficiency. The mixture formation and charge stratification influence the combustion behavior and emissions for PPC/PCCI, significantly. An ultra-high speed burst-mode laser is used to capture the mixture formation process from the start of injection until several CADs after the start of combustion in a single cycle. To the authors’ best knowledge, this is the first time that such a high temporal resolution, i.e. 0.2 CAD, PLIF could be accomplished for imaging of the in-cylinder mixing process. The capability of resolving single cycles allows for the influence of cycle-to-cycle variations to be eliminated.

Transported probability density function (PDF) methods are currently being pursued as a viable approach to model the effects of turbulent mixing and mixture stratification, especially for new alternative combustion modes as for example Homogeneous Charge Compression ignition (HCCI) which is one of the advanced low temperature combustion (LTC) concepts. Recently, they have been applied to simple engine configurations to demonstrate the importance of accurate accounting for turbulence/chemistry interactions. PDF methods can explicitly account for the turbulent fluctuations in species composition and temperature relative to mean value. The choice of the mixing model is an important aspect of PDF approach. Different mixing models can be found in the literature, the most popular is the IEM model (Interaction by Exchange with the Mean). This model is very similar to the LMSE model (Linear Mean Square Estimation).