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The purpose of this study was to gain a better understanding of the effects of in-cylinder gas temperature stratification on reducing the pressure-rise rate in HCCI combustion. HCCI combustion was investigated using an optically accessible engine and direct visualization of the combustion chemiluminescence. The engine was fueled with Di-Methyl Ether. Computational work was conducted on the gas compression and expansion strokes in HCCI engine with simple 0-dimensinal multi-zones model. When fuel inhomogeneous charging in experiment, maximum heat release rate decreased. Combustion duration got longer. Maximum pressure-rise rate decreased. Chemiluminescence, of which transition was identified from the side of intake valve to the side of exhaust valve, was observed. It is need for total moderate heat release to get local moderate combustion with not overall but continuous combustion in chamber.