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The effect that thermally and compositionally stratified flowfields have on the spatial progression of iso-octane-fueled homogeneous charge compression ignition (HCCI) combustion were directly observed using highspeed chemiluminescence imaging. The stratified in-cylinder conditions were produced by independently feeding the intake valves of a four-valve engine with thermally and compositionally different mixtures of air, vaporized fuel, and argon. Results obtained under homogeneous conditions, acquired for comparison to stratified operation, showed a small natural progression of the combustion from the intake side to the exhaust side of the engine, a presumed result of natural thermal stratification created from heat transfer between the in-cylinder gases and the cylinder walls. Large differences in the spatial progression of the HCCI combustion were observed under stratified operating conditions.

A production version of a V-8 engine was redesigned to run on partially premixed charge compression ignition (PCCI) combustion mode with conventional diesel fuel. The objective of the PCCI combustion experiments was to obtain low engine-out nitrogen oxide (NOx) and after-treatment tolerant soot emission level. Two fuel injection strategies were used during the PCCI combustion experiments: a) pilot-with-main injection strategy (Pil-M), b) pilot-with-main-and-post (PMP) injection strategy. In the Pil-M injection strategy, a significant fraction of the fuel was delivered early during the compression stroke. The early pilot helped to prepare a lean-mixture of enhanced homogeneity before the combustion was initiated. The combustion of this pilot injection followed by the main combustion helped to reduce soot for a constant NOx value. The pilot-injection timing and quantity had to be selected appropriately to retain the fuel-efficiency.

Selective Catalytic Reduction (SCR) catalysts have been designed to reduce NOx with the assistance of an ammonia-based reductant. Diesel Particulate Filters (DPF) have been designed to trap and eventually oxidize particulate matter (PM). Combining the SCR function within the wall of a high porosity particulate filter substrate has the potential to reduce the overall complexity of the aftertreatment system while maintaining the required NOx and PM performance. The concept, termed Selective Catalytic Reduction Filter (SCRF) was studied using a synthetic gas bench to determine the NOx conversion robustness from soot, coke, and hydrocarbon deposition. Soot deposition, coke derived from propylene exposure, and coke derived from diesel fuel exposure negatively affected the NOx conversion. The type of soot and/or coke responsible for the inhibited NOx conversion did not contribute to the SCRF backpressure.

This work intends to present a study about the application of a standard methodology for the evaluation of the mechanical components compromise as result of the use of biodiesel, based on the lubricating oil analyses. The fuel oil that will be analyzed is produced in PUCRS' Faculty of Chemistry. As we know, the physical-chemical analysis of lubricating oils can indicate a series of parameters that allow valuing the quality and the compromising degree of the mechanical engine components. The results of these analyses will be based on tests in an Electronic Microscopy. This type of analysis will allow us to determine the quality of the lubricating oil, degradation and contamination with metal materials (mechanical compromising). The work presupposes the functioning of Diesel engine cycle with several proportions of biodiesel (B2, B5, B10, B20 and B100).

Single cylinder optical engines are used for internal combustion (IC) engine research as they allow for the application of qualitative and quantitative non-intrusive, diagnostic techniques to study in-cylinder flow, mixing, combustion and emissions phenomena. Such experimental data is not only important for the validation of computational models but can also provide a detailed insight into the physical processes occurring in-cylinder which is useful for the further development of new combustion strategies such as gasoline homogeneous charge compression ignition (HCCI) and Diesel low temperature combustion (LTC). In this context, it is therefore important to ensure that the performance of optical engines is comparable to standard all-metal engines. A comparison of optical and all-metal engine combustion and emissions performance was performed within the present study.

Previous research has shown that elevating fuel injection pressure results in better air-fuel mixture formation, allowing for a further increase in maximum exhaust gas recirculation (EGR) rate while consequently reducing NOx emissions. The aim of this paper is to find out whether there is an optimum injection pressure for lowest soot-NOx emissions at a given boost pressure in high-speed diesel engines. Experiments are carried out on a single-cylinder research engine with a prototype common-rail system, capable of more than 200 MPa injection pressure. The effect of injection pressure on soot-NOx formation is investigated for a variety of boost conditions, representing the conditions of single to multi-stage turbocharger systems. Analysis of the data is performed at the application relevant soot to NOx ratio of approximately 1:10. It is observed that above a critical injection pressure, soot-NOx emissions are not reduced any further.

This study deals with the development of compression ignition DI alcohol engine with higher efficiency and lower emissions comparing to the conventional internal combustion engines. In order to establish such high performance alcohol engines, development of controlled ignition technology is required. This paper focuses on the main factors that govern auto-ignition phenomenon of alcohol spray from the view point of fuel properties. The reason of poor auto-ignition quality of alcohol spray was theoretically and experimentally revealed. That is difficulty of simultaneous attainments of ignition-suitable concentration and temperature in a spray mixture formation due to their smaller stoichiometric air/fuel ratio and larger latent heat for evaporation in comparison with conventional diesel fuels.

The present study investigates cold start at very low temperatures, down to −29 deg C. The experiments were conducted in an optical light duty diesel engine using a Swedish class 1 environmental diesel fuel. In-cylinder imaging of the natural luminescence using a high speed video camera was performed to get a better understanding of the combustion at very low temperature conditions. Combustion in cold starting conditions was found to be asymmetrically distributed in the combustion chamber. Combustion was initiated close to the glow plug first and then transported in the swirl direction to the adjacent jets. A full factorial study was performed on low temperature sensitivity for cold start. The effects of cooling down the engine by parts on stability and noise were studied. Furthermore, different injection strategies were investigated in order to overcome the limited fuel evaporation process at very low temperatures.

The present paper describes the first results of a cooperative research project between GM Powertrain Europe and Istituto Motori of CNR aimed at studying the impact of Fatty-Acid Methyl Esters (FAME) and gas-to-liquid (GTL) fuel blends on the performance, emissions and fuel consumption of modern automotive diesel engines. The tests were performed on the architecture of GM 1.9L Euro4 diesel engine for passenger car application, both on optical single-cylinder and on production four-cylinder engines, sharing the same combustion system configuration. Various blends of biodiesels as well as reference diesel fuel were tested. The experimental activity on the single-cylinder engine was devoted to an in-depth investigation of the combustion process and pollutant formation, by means of different optical diagnostics techniques, based on imaging multiwavelength spectroscopy.

The study measured Mass Air Flow, (MAF), Manifold Absolute Pressure, (MAP), and emissions of NO and soot during fourteen transients of speed and load, representative of the Extra Urban Drive Cycle (EUDC). The tests were conducted on a typical passenger car/light-duty truck powertrain (a turbocharged common-rail diesel engine, of in-line 4-cylinder configuration). The objective was to compare NO and soot with corresponding steady-state emission results and propose an engine measurement methodology that will potentially quantify deviation (i.e. deterioration with respect to steady state optimum) in emissions of NO and soot during transients. Comparison between steady state, quasi-steady-states (defined later in the paper) and transients indicated that discrete quasi-steady-state engine operation, can be used for accurate prediction of transient emissions of NO and soot.

Recent developments in diesel fuel injection equipment coupled with moves to using ULSD and biodiesel blends has seen an increase in the number of reports, from both engine manufacturers and fleet operators, regarding fuel system deposit issues. Preliminary work performed to characterise these deposits showed them to be complicated mixtures, predominantly carbon like but also containing other possible carbon precursor materials. This paper describes the application of the combination of hydropyrolysis, gas chromatography and mass spectrometry to the analysis of these deposits. It also discusses the insights that such analysis can bring to the constitution and origin of these deposits.

The continual reduction of diesel engine heavy-duty nitrous oxides and particulate matter emissions due to Environmental Protection Agency (EPA) regulations has resulted in significant changes to engine hardware since 1998. Such changes have included use of cooled exhaust gas recirculation, clean gas induction, oxidation catalysts, variable geometry turbochargers, lean nitrous oxide traps, urea selective catalytic reduction, passive and catalyzed particulate matter filters, and engine design changes to reduce oil consumption while allowing use of low sulfur diesel fuel (DF-2) and maintaining oil change intervals and subsystem durability levels of previous model years. The net result from a propulsion system perspective is increased heat rejection, additional induction and exhaust system volume, increased system weight, and less tolerance to military fuels and lubricants.

Ion sensors have been shown to be a low-cost and robust method of measuring start of combustion (SOC) in Homogeneous Charge Compression Ignition (HCCI) engines. The combustion event in an HCCI engine is governed by temperature sensitive chemical-kinetics and is highly fuel dependent. Autoignition variability between various fuels can also affect emissions, efficiency, and overall operating range of the HCCI engine. Ion sensors (i.e. modified spark-plugs) can be used pragmatically to detect the combustion event for various fuels in HCCI engines over a wide range of operating conditions. An investigation of the ion currents produced from the combustion of gasoline, ethanol, and n-heptane in a 1.9L 4-cylinder VW TDI diesel engine (converted to run in HCCI mode) is conducted over a range of equivalence ratios, intake temperatures, and intake pressures. Gasoline, ethanol and n-heptane have diverse autoignition characteristics which affect the overall operation of the HCCI engine.

It is generally accepted that emissions of nitrogen oxides (NOx) increase as the volume fraction of bio diesel increases in blends with conventional diesel fuel. While many mechanisms based on bio diesel effects on in-cylinder processes have been proposed to explain this observation, a clear understanding of the relative importance of each has remained elusive. To gain further insight into the cause(s) of the bio diesel NOx increase, experiments were conducted in a single-cylinder version of a heavy-duty diesel engine with extensive optical access to the combustion chamber. The engine was operated using two bio diesel fuels and two hydrocarbon reference fuels, over a wide range of loads, and using undiluted air as well as air diluted with simulated exhaust gas recirculation.

Biodiesel has been widely accepted as an alternative for fossil-derived diesel fuel for use in compression ignition (CI) engines. Poor oxidative stability and cold flow properties restrict the use of biodiesel beyond current B20 blend levels (20% biodiesel in 80% ULSD) for vehicle applications. Maintaining the properties of B20 as specified by ASTM D7476-08 is important because, once out of spec, B20 may cause injector coke formation, fuel filter plugging, increased exhaust emissions, and overall loss of engine performance. While the properties of fresh B20 may be within the specifications, under engine operating and longer storage conditions B20 could deteriorate. In a diesel engine, the fuel that goes to the injector and does not enter the cylinder is recycled back to the fuel tank. The re-circulated fuel returns to the fuel tank at an elevate temperature, which can cause thermal oxidation.

The use of butanol as an alternative biofuel blend component for conventional diesel fuel has been under extensive investigation. However, some fuel properties such as cetane number and lubricity fall below the accepted values as described by the ASTM D 975 diesel specifications. Blending 10% butanol with #2 ULSD decreases the cetane number by 7% (from 41.6 to 39.0). At higher butanol blend levels, i.e., 20% v/v, the cetane number decrease cannot be compensated for; even with the addition of a 2000 ppm level commercial cetane improver. The decreased cetane number, or in other words, increased ignition delay, can be attributed to the increased blend level of low cetane butanol as well as the critical physical properties for better atomization of fuels during auto ignition such as viscosity. The kinematic viscosity dropped sharply with increasing butanol blend level up to 25 % v/v, then increased with further increase of butanol blend level.

Heavy-duty engine experiments were conducted to explore reactivity controlled compression ignition (RCCI) combustion through addition of the cetane improver di-tert-butyl peroxide (DTBP) to pump gasoline. Unlike previous diesel/gasoline dual-fuel operation of RCCI combustion, the present study investigates the feasibility of using a single fuel stock (gasoline) as the basis for both high reactivity and low reactivity fuels. The strategy consisted of port fuel injection of gasoline and direct injection of the same gasoline doped with a small volume percent addition of DTBP. With 1.75% DTBP by volume added to only the direct-injected fuel (which accounts for approximately 0.2% of the total fueling) it was found that the additized gasoline behaved similarly to diesel fuel, allowing for efficient RCCI combustion. The single fuel results with DTBP were compared to previous high-thermal efficiency, low-emissions results with port injection of gasoline and direct injections of diesel.

The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. An investigation program is carried out to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. In this paper, fundamental results of the Diesel engine relevant combustion are presented. To enable optimum engine performance a range of different reference fuels have been investigated. The fundamental effects of different physical and chemical properties on emission formation and engine performance are investigated using a thermodynamic diesel single cylinder research engine and an optically-accessible combustion vessel. Depending on the chain length and molecular structure, fuel compounds vary in cetane number, boiling temperature etc. Therefore, different hydrocarbons including n-heptane, n-dodecane, and l-decanol were investigated.

Future synthetic diesel fuels will likely involve mixtures of straight and branched alkanes, possibly with aromatic additives to improve lubricity and durability. To simulate these future fuels, this study examined the combustion characteristics of binary mixtures of 50%, 70%, and 90% isododecane in hexadecane, and of 50%, 70%, and 80% toluene in hexadecane using a single-cylinder research diesel engine with variable injection timing. These binary blends were also compared to operation with commercial petroleum diesel fuel, military petroleum jet fuel, and five current synthetic Fischer-Tropsch diesel and jet fuels. The synthetic diesel and jet fuels showed reasonable similarity with many of the combustion metrics to mid-range blends of isododecane in hexadecane. Stable diesel combustion was possible even with the 80% toluene and 90% isododecane blends; in fact, operation with 100% isododecane was achieved, although with significantly advanced injection timing.

To meet increasingly stringent diesel exhaust emissions requirements, original equipment manufacturers (OEMs) have introduced common rail fuel injection systems that develop pressures of up to 2000 bar (30,000 psi). In addition, fuel delivery schemes have become more complicated, often involving multiple injections per cycle. Containing higher pressures and allowing for precise metering of fuel requires very tight tolerances within the injector. These changes have made injectors more sensitive to fuel particulate contamination. Recently, problems caused by internal diesel injector deposits have been widely reported. In this paper, the results of an investigation into the chemical nature and probable sources of these deposits are discussed. Using an array of techniques, internal deposits were analyzed from on a number of sticking injectors from the field and from OEM test stands in North America.