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The presentation describes technology developments and the integration of these technologies into new emission control systems. As in other years, the reader will find a wide range of topics from various parts of the world. This is reflective of the worldwide scope and effort to reduce diesel exhaust emissions. Topics include the integration of various diesel particulate matter (PM) and Nitrogen Oxide (NOx) technologies as well as sensors and other emissions related developments. Presenter Atsuo Kondo, NGK Insulators, Ltd.

The fatty acid methyl esters (FAME's) - in Europe mostly RME (Rapeseed methyl ester) - are used in several countries as alternative biogene Diesel fuels in various blending ratios with fossil fuels (Bxx). Questions often arise about the influences of these biocomponents on the modern exhaust aftertreatment systems and especially on the regeneration of Diesel particle filters (DPF). In the present work different regeneration procedures of DPF systems were investigated with biofuels B0, B20 & B100. The tested regeneration procedures were: passive regenerations: DOC + CSF; CSF alone, active regenerations: standstill burner; fuel injections & DOC. During each regeneration on-line measurements of regulated and unregulated emission components (nanoparticles & FTIR) were conducted. It can be stated that the increased portion of RME in fuel provokes longer time periods to charge the filter with soot.

Currently, two consolidated aftertreatment technologies are available for the reduction of NOx emissions from diesel engines: Urea SCR (Selective Catalytic Reduction) systems and LNT (Lean NOx Trap) systems. Urea SCR technology, which has been widely used for many years at stationary sources, is becoming nowadays an attractive alternative also for light-duty diesel applications. However, SCR systems are much more effective in NOx reduction efficiency at high load operating conditions than light load condition, characterized by lower exhaust gas temperatures.

Four-way, integrated, diesel emission control systems that combine selective catalytic reduction for NOx control with a continuously regenerating trap to remove diesel particulate matter were evaluated under real-world, on-road conditions. Tests were conducted using a semi-tractor with an emissions year 2000, 6-cylinder, 12 L, Volvo engine rated at 287 kW at 1800 rpm and 1964 N-m. The emission control system was certified for retrofit application on-highway trucks, model years 1994 through 2002, with 4-stroke, 186-373 kW (250-500 hp) heavy-duty diesel engines without exhaust gas recirculation. The evaluations were unique because the mobile laboratory platform enabled evaluation under real-world exhaust plume dilution conditions as opposed to laboratory dilution conditions. Real-time plume measurements for NOx, particle number concentration and size distribution were made and emission control performance was evaluated on-road.

The combination of advanced combustion with advanced selective catalytic reduction (SCR) catalyst formulations was studied in the work presented here to determine the impact of the unique hydrocarbon (HC) emissions from premixed charge compression ignition (PCCI) combustion on SCR performance. Catalyst core samples cut from full size commercial Fe- and Cu-zeolite SCR catalysts were exposed to a slipstream of raw engine exhaust from a 1.9-liter 4-cylinder diesel engine operating in conventional and PCCI combustion modes. The zeolites which form the basis of these catalysts are different with the Cu-based catalyst made on a chabazite zeolite which las smaller pore structures relative to the Fe-based catalyst. Subsequent to exposure, bench flow reactor characterization of performance and hydrocarbon release and oxidation enabled evaluation of overall impacts from the engine exhaust.

The 10 papers in this technical paper collection cover emissions measuring techniques and testing regimes including new analysis techniques and novel application of existing techniques and the comparison of existing and proposed testing regimes with real world experience.

The 16 papers in this technical paper collection cover diesel engine exhaust aftertreatment system models as well as the validation and application. Technologies covered include DOC, HC trap, DFP, LNT, SCR, ammonia oxidation catalysts, hybrid or combined catalysts, urea-water solution spray dynamics, and mixture non-uniformity.

This technical paper collection covers emissions measuring techniques and testing regimes including new analysis techniques and the novel application of existing techniques, the comparison of existing and proposed testing regimes with real world experience, including modeling.

This technical paper collection covers DOC, HC Trap, DPF, GPF, LNT, TWC, SCR, SCRF, ammonia oxidation catalysts, hybrid or combined catalysts, urea-water solution spray dynamics, and mixture non-uniformity. Modeling aspects range from fundamental, 3D models of individual components to system level simulation, optimization, variation, degradation, and control.

Papers in this collection focus on particle emissions from combustion engines, including measurement and testing methods, and the effects of changes in fuel composition. Topics of the environmental and health effects of elemental carbon and organic carbon that constitutes solid cored particles, plus the environmental and health effects of secondary organic aerosol emissions, are also addressed. This includes particulate emissions from both gasoline and diesel engines.

Abstract Gasoline particulate filters (GPFs) are important aftertreatment components that enable gasoline direct injection (GDI) engines to meet European Union (EU) 6 and China 6 particulate number emissions regulations for nonvolatile particles greater than 23 nm in diameter. GPFs are rapidly becoming an integral part of the modern GDI aftertreatment system. The Active Exhaust Tuning (EXTUN) Valve is a butterfly valve placed in the tailpipe of an exhaust system that can be electronically positioned to control exhaust noise levels (decibels) under various vehicle operating conditions. This device is positioned downstream of the GPF, and variations in the tuning valve position can impact exhaust backpressures, making it difficult to monitor soot/ash accumulation or detect damage/removal of the GPF substrate. The purpose of this work is to present a unique example of subsystem control and diagnostic architecture for an exhaust system combining GPF and EXTUN.

The 12 papers in this technical paper collection discuss technologies that address the treatment of engine exhaust emissions to meet commercial vehicle requirements. The scope covers developments in catalysis, materials, controls, and integration with the complete engine/vehicle system.

Papers in this collection focus on particle emissions from combustion engines, including measurement and testing methods, and the effects of changes in fuel composition. Topics of the environmental and health effects of elemental carbon and organic carbon that constitutes solid cored particles, plus the environmental and health effects of secondary organic aerosol emissions, are also addressed. This includes particulate emissions from both gasoline and diesel engines.

Engine operating strategies typically geared towards higher fuel economy and lower NOx widely affect exhaust composition and temperature. These exhaust variables critically drive the performance of After Treatment (AT) components, and hence should guide their screening and selection. Towards this end, the effect of H2 level in diesel exhaust on the performance of a Diesel Oxidation Catalyst (DOC) was studied using flow reactor experiments, vehicle emission measurements and mathematical models. Vehicle chassis dynamometer data showed that exhaust from light-duty and heavy-duty diesel trucks contained very little to almost no H2 (FTP average CO/H2 ∼ 40 to 70) as compared to that of a gasoline car exhaust (FTP average CO/H2 ∼ 3). Two identical flow reactor experiments, one with H2 (at CO/H2 ∼ 3) and another with no H2 in the feed were designed to screen DOCs under simulated feed gas conditions that mimicked these two extremes in the exhaust H2 levels.

A thorough understanding of vehicle exhaust aftertreatment system performance requires time-resolved emissions measurements that accurately follow driving transients, and that are correctly time-aligned with exhaust temperature and flow measurements. The transient response of conventional gas analyzers is characterized by both a time delay and an attenuation of high-frequency signal components. The distortion that this imposes on transient emissions measurements causes significant errors in instantaneous calculations of aftertreatment system efficiency, and thus in modal mass analysis. This creates difficulties in mathematical modeling of emissions system performance and in optimization of powertrain control strategies, leading to suboptimal aftertreatment system designs. A mathematical method is presented which improves the response time of emissions measurements. This begins with development of a model of gas transport and mixing within the sampling and measurement system.

Empirical models for engine-out oxides of Nitrogen (NOx) and smoke emissions have been developed for the purpose of minimizing transient emissions while maintaining transient response. Three major issues have been addressed: data acquisition, data processing and modeling method. Real and virtual transient parameters have been identified for acquisition. Accounting for the phase shift between transient engine events and transient emission measurements has been shown to be very important to the quality of model predictions. Several methods have been employed to account for the transient transport delays and sensor lags which constitute the phase shift. Finally several different empirical modeling methods have been used to determine the most suitable modeling method for transient emissions. These modeling methods include several kinds of neural networks, global regression and localized regression.

The challenges of flex-fuel vehicle (FFV) emissions measurements have recently come to the forefront for the emissions testing community. The proliferation of ethanol blended gasoline in fractions as high as 85% has placed a new challenge in the path of accurate measures of NMHC and NMOG emissions. Test methods need modification to cope with excess amounts of water in the exhaust, assure transfer and capture of oxygenated compounds to integrated measurement systems (impinger and cartridge measurements) and provide modal emission rates of oxygenated species. Current test methods fall short of addressing these challenges. This presentation will discuss the challenges to FFV testing, modifications made to Ford Motor Company’s Vehicle Emissions Research Laboratory test cells, and demonstrate the improvements in recovery of oxygenated species from the vehicle exhaust system for both regulatory measurements and development measurements.

Beginning in 2007, heavy-duty engine manufacturers in the U.S. have been responsible for verifying the compliance of in-use vehicles with Not-to-Exceed (NTE) standards under the Heavy-Duty In-Use Testing Program (HDIUT). This in-use testing is conducted using Portable Emission Measurement Systems (PEMS) which are installed on the vehicles to measure emissions during field operation. A key component of the HDIUT program is the generation of measurement allowances which account for the relative accuracy of PEMS as compared to conventional laboratory-based measurement techniques. A program to determine these measurement allowances for gaseous emissions was jointly funded by the U.S. Environmental Protection Agency (EPA), the California Air Resources Board (CARB), and various member companies of the Engine Manufacturer's Association (EMA). The gaseous pollutants examined in the program were carbon monoxide (CO), non-methane hydrocarbons (NMHC), and oxides of nitrogen (NOx).

Under the U.S. Environmental Protection Agency's (EPA's) Heavy-Duty In-Use Testing (HDIUT) program, emission of non-methane hydrocarbons (NMHC), carbon monoxide (CO), and oxides of nitrogen (NOx) have been regulated using Portable Emissions Measurement Systems (PEMS) during in-use field operation for heavy-duty on-highway diesel engines with 2007 or later model year designations. As directed by the EPA, the Engine Manufacturers Association (EMA), and the California Air Resources Board (CARB), additive emission measurement accuracy margins (measurement allowances) were experimentally determined for HDIUT to account for the measurement differences between laboratory testing with laboratory grade equipment and in-use testing with PEMS. As part of a three-paper series, this paper summarizes the HDIUT measurement allowance program while focusing on the laboratory evaluations of the Sensors Inc. SEMTECH-DS PEMS.

Beginning in 2007, heavy-duty engine manufacturers in the U.S. have been responsible for verifying the compliance on in-use vehicles with Not-to-Exceed (NTE) standards under the Heavy-Duty In-Use Testing Program (HDIUT). This in-use testing is conducted using Portable Emission Measurement Systems (PEMS) which are installed on the vehicles to measure emissions during real-world operation. A key component of the HDIUT program is the generation of measurement allowances which account for the relative accuracy of PEMS as compared to more conventional, laboratory based measurement techniques. A program to determine these measurement allowances for gaseous emissions was jointly funded by the U.S. Environmental Protection Agency (EPA), the California Air Resources Board (CARB), and various member companies of the Engine Manufacturer's Association (EMA).