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Auto-ignition and combustion processes of dual-component fuel spray were numerically studied. A source code of SUPERTRAPP (developed by NIST), which is capable of predicting thermodynamic and transportation properties of pure fluids and fluid mixtures containing up to 20 components, was incorporated into KIVA3V to provide physical fuel properties and vapor-liquid equilibrium calculations. Low temperature oxidation reaction, which is of importance in ignition process of hydrocarbon fuels, as well as negative temperature coefficient behavior was taken into account using the multistep kinetics ignition prediction based on Shell model, while a global single-step mechanism was employed to account for high temperature oxidation reaction. Computational results with the present multi-component fuel model were validated by comparing with experimental data of spray combustion obtained in a constant volume vessel.

In a high-speed DI diesel engine, fuel sprays impinge surely on a wall of a piston cavity. Then the phenomenon of the heat transfer between the impinged spray and the wall appears and it has the strong effect on the combustion processes of the engine. The purpose of this study are to clarify basically the heat transfer characteristics. In the experiments, the fuel was injected into the quiescent inert atmosphere with a high temperature under high pressure field, and an evaporative single diesel spray was impinging upon a flat wall. And, the temperature distribution on the wall surface in a radial direction was detected by the Loex-Constantan thin film thermo-couples. Thus, the heat flux between the impinged spray and the wall surface was calculated from the temperature profile within the wall by Fourier's equation using the finite difference method, under the assumption of the one-dimensional heat conduction.

The authors have explored the potential of fuel to control spray and its combustion processes in a diesel engine. Fuel has some potential for low emission and high thermal efficiency because its volatility and ignitability are one of the ultimate performing factors of the engines. In present study, the ignition process of mixed fuel spray was investigated in a constant volume combustion vessel and in a rapid compression and expansion machine, The ignition delay based on the diagram of rate of the heat release, the imaging of natural flame emissions and the numerical simulation were carried out to clarify the effect of the physical and chemical properties of mixed fuel on ignition characteristics.

Fuel design concept has been proposed for low emission and combustion control in engine systems. In this concept, the multicomponent fuels, which are mixed with a high volatility fuel (gasoline or gaseous fuel components) and a low volatility fuel (gas oil or fuel oil components), are used for artificial control of fuel properties. In addition, these multicomponent fuels can easily lead to flash boiling which promote atomization and vaporization in the spray process. In order to understand atomization and vaporization process of multicomponent fuels in detail, the model for flash boiling spray of multicomponent fuel have been constructed and implemented into KIVA3V rel.2. This model considers the detailed physical properties and evaporation process of multicomponent fuel and the bubble nucleation, growth and disruption in a nozzle orifice and injected fuel droplets.

Ignition, combustion and emissions characteristics of dual-component fuel spray were examined for ranges of injection timing and intake-air oxygen concentration. Fuels used were binary mixtures of gasoline-like component i-octane (cetane number 12, boiling point 372 K) and diesel fuel-like component n-tridecane (cetane number 88, boiling point 510 K). Mass fraction of i-octane was also changed as the experimental variable. The experimental study was carried out in a single cylinder compression ignition engine equipped with a common-rail injection system and an exhaust gas recirculation system. The results demonstrated that the increase of the i-octane mass fraction with optimizations of injection timing and intake oxygen concentration reduced pressure rise rate and soot and NOx emissions without deterioration of indicated thermal efficiency.

Diesel sprays injected into a combustion chamber of a small sized high-speed CI engine impinge surely on a piston surface and a cylinder wall. As a consequence, their vaporization, mixture formation and combustion processes are affected by impingement phenomena. And the other important factors affecting on the processes is the injection pressure. Then, the distribution of the vapor concentration in a single diesel spray impinging on a flat and hot wall was experimented by the exciplex fluorescence method, as a simple case. The injection pressure was varied in the range from 55 MPa to 120 MPa. It is found that the distribution of the vapor concentration in this case is much leaner than that in the case of the low injection pressure of 17.8MPa.

CNG is one of the future fuel for a CI engine. Recently, the general tendency is the use of the high pressure injection system over 100 MPa in a CI engine for the near future severe regulation. Combustion phenomenon in a CI engine with such injection system is like a transient gas diffusion flame. The flow in a gas diffusion flame was investigated by the particle image velocimetry on its 2-D images, the relative soot concentration, the temperature and the relative CO2 concentration was detected in the experiments. And the model of transient gas diffusion flame was constructed by use of experimental data.

Three-dimensional large eddy simulation (LES) has been conducted for a diesel spray flame using KIVALES which is LES version of KIVA code. Modified TAB model, velocity interpolation model and rigid sphere model are used to improve the prediction of the fuel-mixture process in the diesel spray. Combustion is simulated using the Eddy-Dissipation model. CIP method was incorporated into the KIVALES in order to suppress the numerical instability on the combustible flow. The formation of soot and NO was simulated using Hiroyasu model and KIVA original model. Three different grid resolutions were used to examine the grid dependency. The result shows that the LES approach with 0.5 mm grid size is able to resolve the instantaneous spray with the intermittency in the spray periphery, the axi-symmetric shape and meandering flow after the end of injection as shown in the experimental results.

Authors propose the reformulation technique of physical properties of Biodiesel Fuel (BDF) by mixing lower boiling point fuels. In this study, waste cooking oil methyl ester (B100), which have been produced in Kyoto city, is used in behalf of BDF. N-Heptane (C7H16) and n-Dodecane (C12H26) are used as low and medium boiling point fuel. Mixed fuel of BDF with lower boiling point fuels have lighter quality as compared with neat BDF. This result is based on the chemical-thermo dynamical liquid-vapor equilibrium theory. This paper describes fundamental spray and combustion characteristics of mixed fuel of B100 with lower boiling point fuels as well as the reformulation technique. By mixing lower boiling point fuel, lighter quality fuels can be refined. Thus, mixed fuels have higher volatility and lower viscosity. Therefore, vaporization of mixed fuel spray is promoted and liquid phase penetration of mixed fuel shortens as compared with that of neat BDF.

In this study, a numerical experiment using a 2D convective equation and LES of an evaporative diesel spray for different convective schemes has been performed to examine effects of convective schemes on a fuel-air mixture formation of the diesel spray simulation and to determine the convective scheme used in KIVALES. In addition to KIVALES original schemes, such as QSOU, PDC and IDC, CIP was incorporated into KIVALES in order to calculate the convective terms with low numerical diffusion. The numerical experiment using the 2D convective equation showed that the numerical diffusion of CIP scheme was lowest in the convective schemes used in present study. However CIP scheme used was not a monotone scheme completely due to the overshoot and the undershoot of the scalar provided near the boundary. Hence, CIP scheme was employed for only the convective term of the LES momentum equation, while the other convective schemes were calculated using QSOU, which is a monotone scheme.

In this study, the purpose is placed in analysis the structure of diesel spray and, especially, making clear the mixture formation process in the evaporative diesel spray. The liquid fuel was injected from a single-hole nozzle (1/d = 1.0 mm/0.2 mm) into a constant-volume vessel possessing phenomena visualization under high pressure and temperature field. As for measurement method, in order to investigate liquid and vapor-phase of injected spray, exciplex fluorescence method was applied in the evaporative fuel spray. And the interested view region in injected spray is the downstream spray. For the minute investigation of spray flow, the liquid and vapor-phase region is taken with 35 mm still camera and CCD camera, respectively.

LES of non-evaporative diesel spray have been performed to investigate the effects of breakup models of Modified TAB, WAVE and KHRT model on computational results. KIVALES that is LES version of KIVA code was used for base code. In our KIVALES, CIP scheme was incorporated in order to suppress the numerical diffusion. Results showed that the breakup model is significantly affected on the calculated spray shape, because the droplet diameter determined by breakup models affects on the transmittance of the droplet momentum into the ambient gas, the evolution of the vortex structure in the gas phase and the droplet dispersion by the vortex structure.

The premixed charge compression ignition (PCCI) combustion in a compression ignition (Cl) engine is one of countermeasures against the very much severe regulation for exhaust gas of engine out. The authors have been proposed to use the fuel mixed with high volatility component and low volatility component to actualize PCCI combustion. This kind of fuel injected forms a fine and lean spray by the flash boiling phenomena which depends on the pressure and the temperature. The role of the former fuel is to decrease in the generation of particulate matters (PM) and that of the latter one is to break out the ignition. Thus, it is very much significant to find the distribution of vapor concentration of both fuels in a spray. This paper describes both distributions in a single diesel spray by use of the technique of laser induced fluorescence (LIF) in a constant volume chamber with high temperature at high pressure as the fundamental research.

This paper describes the results of on-board measurement of engine performance and emissions in diesel vehicle operated with bio-diesel fuels. Here, two waste-cooking oils were investigated. One fuel is a waste-cooking oil methyl esters. This fuel is actually applied to a garbage collection vehicle with DI diesel engine (B100) and the city bus (B20; 80% gas oil is mixed into B100 in volume) as an alternative fuel of gas oil in Kyoto City. Another one is a fuel with ozone treatment by removing impurities from raw waste-cooking oils. Here, in order to improve the fuel properties, kerosene is mixed 70% volume in this fuel. This mixed fuel (i-BDF) is applied into several tracks and buses in Wakayama City. Then, these 3 bio-diesel fuels were applied to the on-board experiments and the results were compared with gas oil operation case.

The maximum liquid-phase penetration and vaporization behavior was investigated by using simultaneous measurement for mie-scattered light images and shadowgraph ones. The objective of this study was to analyze effect of variant parameters (injection pressure, ambient gas condition and fuel temperature) and fuel properties on vaporization behavior, and to investigate liquid phase penetration for the single- and multi-component fuels. The experiments were conducted in a constant-volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector.

Flash-boiling occurs when a fuel is injected to a combustion chamber where the ambient pressure is lower than the saturation pressure of the fuel. It has been known that flashing is a favorable mechanism for atomizing liquid fuels. On the other hand, alternative fuels, such as gaseous fuels and oxygenated fuels, are used to achieve low exhaust emissions in recent years. In general, most of these alternative fuels have high volatility and flash-boiling takes place easily in fuel spray, when they are injected into the combustion chamber of an internal combustion engine under high pressure. In addition, fuel design concept the multicomponent fuel with high and low volatility fuels has been proposed in the previous study in order to control the spray and combustion processes in internal combustion engine. It is found that the multicomponent fuel produce flash-boiling with an increase in the initial fuel temperature.

This study proposes a hybrid model which consists of modified TAB(Taylor Analogy Breakup) model and DVM(Discrete Vortex Method). In this study, the simulation process is divided into three steps. The first step is to analyze the breakup of droplet of injected fuel by using modified TAB model. The second step based on the theory of Siebers' liquid length is analysis of spray evaporation. The liquid length analysis of injected fuel is used for connecting both modified TAB model and DVM. The final step is to reproduce the ambient gas flow and inner vortex flow injected fuel by using DVM. In order to examine the hybrid model, an experiment of a free evaporating fuel spray at early injection stage of in-cylinder like conditions had been executed. The numerical results calculated by using the present hybrid model are compared with the experimental ones.

It is expected that the analysis of the evaporation process for multicomponent fuels such as actual fuels like gasoline and diesel gas oil could be performed to assess more accurately the mixture preparation field inside the cylinder of D.I.S.I engines and diesel engines. In this paper, we suggested the importance of this multicomponent fuel consideration relating to the mixture formation and combustion characteristics from the basis of their own fuel physical and chemical properties. Then, we introduce a treatment for the phase change of a multicomponent solution through the formation of two-phase regions with the basis of chemical-thermodymical liquid-vapor equilibrium. Next, we analyze the distillation properties of a multicomponent fuel as well as the evaporation process of a multicomponent single droplet by use of the chemical-thermodymical analysis.

This paper confirms a structure for the soot formation process inside a burning diesel jet plume of oxygenated fuels. An explanation of how the soot formation process changes by the use of oxygenated fuel in comparison with that for using a conventional diesel fuel, and why oxygenated fuel drastically suppresses the soot formation has been derived from the chemical kinetic analysis. A detailed chemical kinetic mechanism, which is combined with various proposed chemical kinetic models including normal paraffinic hydrocarbon oxidation, oxygenated hydrocarbon oxidation, and poly-aromatic hydrocarbon (PAH) formation, was developed in present study. The calculated results are presented to elucidate the influence of fuel mixture composition and fuel structure, especially relating to oxygenated fuels, on PAH formation. The analysis also provides a new insight into the initial soot formation process in terms of the temperature range of PAH formation.

It is significant for understanding the phenomena in a stratified charge engine and an SI engine with direct injection system to carry out the fundamental research. The experiments were conducted in a constant volume chamber with atmospheric condition. The pre-mixed charge composed of ethylene and air was charged with various equivalence ratio, the second charge with the same composition was injected into the chamber, thereafter, the combustion started by a spark plug. The phenomena were analyzed by use of the experimental results of shadowgraph, [OH] natural emission, pressure history and NOx and UHC in the exhaust gas.