Search Results

Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

In the last ten years, the number of natural gas vehicles worldwide has grown rapidly with the biggest contribution coming from the Asia-Pacific and Latin America regions. As natural gas is the cleanest fossil fuel, the exhaust emissions from natural gas spark ignition vehicles are lower than those of gasoline powered vehicles. Moreover, natural gas is less affected by price fluctuations and its resources are more evenly widespread over the globe than to oil. However, as natural gas vehicles are usually bi-fuel gasoline and natural gas, the excellent knock resistant characteristics of natural gas cannot be completely exploited. This paper shows the results of an experimental activity performed on a passenger car fuelled alternatively by gasoline and compressed natural gas (CNG). The vehicle has been tested on a chassis dynamometer over standard (NEDC) and real driving cycles (Artemis CADC), allowing to investigate a wide range of operating conditions.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.

An experimental campaign was carried out to evaluate the influence of CNG and gasoline on the exhaust emissions and fuel consumption of a bi-fuel passenger car over on-road tests performed in the city of Naples. The chosen route is very traffic congested during the daytime of experimental measurements. An on-board analyzer was used to measure CO, CO2, NOx tailpipe concentrations and the exhaust flow rate. Throughout a carbon balance on the exhaust pollutants, the fuel consumption was estimated. The exact spatial position was acquired by a GPS which allowed to calculate vehicle speed and the traffic condition was monitored by a video camera. Whole trip realized by the vehicle was subdivided in succession of kinematic sequences and the vehicle emissions and fuel consumption were analyzed and presented as value on each kinematic sequence. Moreover, throughout a multivariate statistical analysis of sequences, the driving cycles characterizing the use of vehicle were identified.

Trends towards lower vehicle fuel consumption and smaller environmental impact will increase the share of Diesel hybrids and Diesel Range Extended Vehicles (REV). Because of the Diesel engine presence and the ever tightening soot particle emissions, these vehicles will still require soot particle emissions control systems. Ceramic wall-flow monoliths are currently the key players in the Diesel Particulate Filter (DPF) market, offering certain advantages compared to other DPF technologies such as the metal based DPFs. The latter had, in the past, issues with respect to filtration efficiency, available filtration area and, sometimes, their manufacturing cost, the latter factor making them less attractive for most of the conventional Diesel engine powered vehicles. Nevertheless, metal substrate DPFs may find a better position in vehicles like Diesel hybrids and REVs in which high instant power consumption is readily offered enabling electrical filter regeneration.

As different Diesel Particulate Filter (DPF) designs and media are becoming widely adopted, research efforts in the characterization of their influence on particle emissions intensify. In the present work the influence of a Diesel Oxidation Catalyst (DOC) and five different Diesel Particulate Filters (DPFs) under steady state and transient engine operating conditions on the particulate and gaseous emissions of a common-rail diesel engine are studied. An array of particle measuring instrumentation is employed, in which all instruments simultaneously measure from the engine exhaust. Each instrument measures a different characteristic/metric of the diesel particles (mobility size distribution, aerodynamic size distribution, total number, total surface, active surface, etc.) and their combination assists in building a complete characterization of the particle emissions at various measurement locations: engine-out, DOC-out and DPF-out.

Although engine emissions per vehicle have been reduced for twenty years with technical developments in the fields of engine, after-treatment technologies and fuels the urban air pollution problem still exists in many cities around the world. Forthcoming emission regulations will require further development of new complex technologies to reach low emissions. On-board driving assessment of such technologies offers significant advantages in the development phase of novel emission reduction. In this paper we present the design, development and commissioning of a mobile laboratory able to monitor on-board along the exhaust line gaseous and particulate pollutants as well as measure these pollutants in the ambient environment around the vehicle.

Future diesel emission control systems have to effectively operate under non-conventional low-temperature combustion engine operating conditions. In this work the research and development efforts for the realization of a Multi-Functional catalyst Reactor (MFR) for the exhaust of the upcoming diesel engines is presented. This work is based on recent advances in catalytic nano-structured materials synthesis and coating techniques. Different catalytic functionalities have been carefully distributed in the filter substrate microstructure for maximizing the direct and indirect (NO2-assisted) soot oxidation rate, the HC and CO conversion efficiency as well as the filtration efficiency. Moreover, a novel filter design has been applied to enable internal heat recovery capability by the implementation of heat exchange between the outlet and the inlet to the filter flow paths.

Establishing a certain maintenance-free time period regarding modern diesel exhaust emission control systems is of major importance nowadays. One of the most serious problems Diesel Particulate Filter (DPF) manufacturers face concerning system's durability is the performance deterioration due to the filter aging because of the accumulation of the ash particles. The evaluation of the effect of the ash aging on the filter performance is a time and cost consuming task that slows down the process of manufacturing innovative filter structures and designs. In this work we present a methodology for producing filter samples aged by accumulating ash produced by the controlled pyrolysis of oil-fuel solutions. Such ash particles bear morphological (size) and compositional similarity to ash particles collected from engine aged DPFs. The ash particles obtained are compared to those from real engine operation.

Diesel particulate trap regeneration is a complex process involving the interaction of phenomena at several scales. A hierarchy of models for the relevant physicochemical processes at the different scales of the problem (porous wall, filter channel, entire trap) is employed to obtain a rigorous description of the process in a multidimensional context. The final model structure is validated against experiments, resulting in a powerful tool for the computer-aided study of the regeneration behavior. In the present work we employ this tool to address the effect of various spatial non-uniformities on the regeneration characteristics of diesel particulate traps. Non-uniformities may include radial variations of flow, temperature and particulate concentration at the filter inlet, as well as variations of particulate loading. In addition, we study the influence of the distribution of catalytic activity along the filter wall.

In the present work we apply a computational simulation framework developed for square-cell shaped honeycomb Diesel Particulate Filters to study the filtration, pressure drop and soot oxidation characteristics of recently developed triangular-cell-shaped, high porosity wall-flow filters. Emphasis is placed on the evaluation of the applicability and adaptation of the previously developed models to the case of triangular channels. To this end Computational Fluid Dynamics, asymptotic analysis, multichannel and “unit-cell” calculations are employed to analyze filter behavior and the results are shown to compare very well to experiments available in the literature.

In recent years advanced computational tools of Diesel Particulate Filter (DPF) regeneration have been developed to assist in the systematic and cost-effective optimization of next generation particulate trap systems. In the present study we employ an experimentally validated, state-of-the-art multichannel DPF simulator to study the regeneration process over the entire spatial domain of the filter. Particular attention is placed on identifying the effect of inlet cones and boundary conditions, filter can insulation and the dynamics of “hot spots” induced by localized external energy deposition. Comparison of the simulator output to experiment establishes its utility for describing the thermal history of the entire filter during regeneration. For effective regeneration it is recommended to maintain the filter can Nusselt number at less than 5.

Diesel particulate filter (DPF) is the most effective emission control device for reducing particle emissions (both mass, PM, and number, PN) from diesel engines, however many studies reported elevated emissions of nanoparticles (<50 nm) during its regeneration. In this paper the results of an extensive literature survey is presented. During DPF active regeneration, most of the literature studies showed an increase in the number of the emitted nanoparticles of about 2-3 orders of magnitude compared to the normal operating conditions. Many factors could influence their amount, size distribution, chemical-physical nature (volatiles, semi-volatiles, solid) and the duration of the regenerative event: i.e. DPF load and thermodynamic conditions, lube and fuel sulfur content, engine operative conditions, PN sampling and measurement methodologies.

All the experimental investigations performed in the last years on newly sold motorcycles, equipped with a three-way catalyst and electronic mixture control, clearly indicate that CO and HC cold additional emissions, if compared with those exhausted in hot conditions, represent an important proportion of total emissions. Consequently, calculation programs for estimating emissions from road transports for air quality modeling in dedicated local areas should take into consideration this effect. From this motivation, an experimental activity on motorcycles cold emissive behavior is being jointly conducted by Istituto Motori of the National Research Council (IM-CNR) and the Department of Mechanic and Energetic (DiME) of the University of Naples.

This paper is based on a Research Project of the Department of Mechanical Engineering (DiME) in collaboration with Aprilia, the Italian motorbike manufacturer. In an attempt to simulate the functioning of the cooling plant of the Aprilia RSV-4 motorbike a numerical model was constructed using mono-dimensional and three-dimensional simulation codes. Our ultimate aim was to create a simulation model which could be of assistance to engine designers to improve cooling plant performance, thereby reducing research and development costs. The model allows to simulate the running conditions of the whole cooling circuit upon variations in environmental and running conditions. In particular, the centrifugal pump of the cooling plant was simulated by a 3D commercial software, while the whole circuit was built by a 1D commercial code which allows simulation of all the thermal exchanges and pressure drops in the cooling circuit.

A wide investigation on powered two-wheelers (PTWs) is presented, aiming at the analysis of the influence of the driving characteristics on PTWs exhaust emissions and fuel consumption, a deeper comprehension of the engine and after-treatment system behavior within the cold start transient and the evaluation of cold start additional emissions for different two-wheelers classes. The study was developed with reference to an European context focusing on Euro 3 motorcycles and Euro 2 mopeds. An experimental investigation on instantaneous speed measurements was carried out with instrumented motorcycles, considering typical urban trips in the city of Genoa. A selection of speed profiles was then performed by processing experimental values.

In this paper some results relative to tests performed on road with a Fiat Panda Bipower, (CNG and gasoline powered), and a New Panda Twin Air with auto Start & Stop system, are presented. Gaseous emissions are measured with Portable Emission Measurement Systems (PEMS) on two different urban routes, in terms of traffic and slope characteristics during in use experiments. PEMS testing offers an easy and efficient way to evaluate the vehicle emissions over a huge variety of conditions and provides us a direct way to study the in-use emissions of combustion engines, when you want to verify the effect of the traffic and of a particular device on fuel economy and emissions reduction. Moreover now PEMS performances are very comparable to those obtained by standard laboratory instrumentation systems.

Diesel Particulate Filters (DPFs) need to be periodically regenerated in order to achieve efficient and safe vehicle operation. Under typical diesel exhaust conditions, this invariably requires the raising of the exhaust gas temperature by active means, up to the point that particulate (soot) oxidation can be self-sustained in the filter. In the present work the development path of an advanced catalytic filter technology is presented. Full scale optimized Catalytic Diesel Particulate Filters (CDPFs) are tested in the exhaust of a light-duty modern diesel engine in line with a Diesel Oxidation Catalyst (DOC). The management of the DOC-CDPF emission control system is facilitated by a virtual soot sensor in order to ensure energy-efficient operation of the emission control system.

Nowadays, real-world emissions and consumption behaviour of Light Duty (LDV) and Heavy Duty (HDV) vehicles are key factors in achieving greenhouse gas (GHG) targets. With the introduction of EURO VI in 2013 there were already low emission levels and real fuel consumption of new HDV vehicles. Furthermore, the available public literature regarding fuel consumption of European HDV vehicles is not very extensive. Hence, the development of an experimental activity related to HDVs real consumption measurement and the subsequent data analysis can be considered in this field. To this end, the fuel consumption data of four rear-loader garbage Diesel trucks, managed by a multiservice company in the Southern Italy, were collected during real use. Vehicles in pairs have different technical characteristics (i.e. engine capacity and maximum load capacity of the garbage).