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Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Catalyzed Diesel Particulate Filters (CDPFs) continue to be an important emission control solution and are now also expanding to include additional functionalities such as gas species oxidation (such as CO, hydrocarbons and NO) and even storage phenomena (such as NOx and NH3 storage). Therefore an in depth understanding of the coupled transport - reaction phenomena occurring inside a CDPF wall can provide useful guidance for catalyst placement and improved accuracy over idealized effective medium 1-D and 0-D models for CDPF operation. In the present work a previously developed 3-D simulation framework for porous materials is applied to the case of NO-NO2 turnover in a granular silicon carbide CDPF. The detailed geometry of the CDPF wall is digitally reconstructed and micro-simulation methods are used to obtain detailed descriptions of the concentration and transport of the NO and NO2 species in the reacting environment of the soot cake and the catalyst coated pores of the CDPF wall.

Current progress in the development of diesel engines substantially contributes to the reduction of NOx and Particulate Matter (PM) emissions but will not succeed to eliminate the application of Diesel Particulate Filters (DPFs) in the future. In the past we have introduced a Multi-Functional Reactor (MFR) prototype, suitable for the abatement of the gaseous and PM emissions of the Low Temperature Combustion (LTC) engine operation. In this work the performance of MFR prototypes under both conventional and advanced combustion engine operating conditions is presented. The effect of the MFR on the fuel penalty associated to the filter regeneration is assessed via simulation. Special focus is placed on presenting the performance assessment in combination with the existing differences in the morphology and reactivity of the soot particles between the different modes of diesel engine operation (conventional and advanced). The effect of aging on the MFR performance is also presented.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.

In the frame of tighter emission requirements and environmental protection, future standards will soon lead to the use of an OBD soot sensor to monitor DPF leakage. Such a sensor will first be introduced in the US by MY 2015 and then in Europe for Euro 6.2 in 2017. The resistive ceramic sensing technology has been selected by most OEM as the most appropriate. The sensor collects the soot in a time cumulative manner and has an internal heater to clean the ceramic before each measurement sequence. The actual challenge of the hardware is to design a wide band collecting system with a high sensitivity and repeatability circuit processing. Electricfil has overcome major drawbacks of the resistive technology with an innovative sensor tip, with filtration features and a boosting electronic scheme. This sensor integrates internal diagnostic capability at power on and during operation.

Asymmetric and Variable Cell (AVC) geometry Diesel Particulate Filters (DPF) occupy an increasing portion of the DPFs currently offered by various DPF manufacturers, aiming at providing higher filtration area in the same filter volume to meet demanding emission control applications for passenger cars but also for heavy duty vehicles. In the present work we present an approach for designing and optimizing such DPFs by providing a quantitative description of the flow and deposition of soot in these structures. Soot deposit growth dynamics in AVC DPFs is studied computationally, primary and secondary flows over the inlet channels cross-sectional perimeters are analyzed and their interactions are elucidated. The result is a rational description of the observed growth of soot deposits, as the flow readjusts to transport the soot particles along the path of least resistance (which is not necessarily the shortest geometric path between the inlet and outlet channel, i.e. the wall thickness).

Trends towards lower vehicle fuel consumption and smaller environmental impact will increase the share of Diesel hybrids and Diesel Range Extended Vehicles (REV). Because of the Diesel engine presence and the ever tightening soot particle emissions, these vehicles will still require soot particle emissions control systems. Ceramic wall-flow monoliths are currently the key players in the Diesel Particulate Filter (DPF) market, offering certain advantages compared to other DPF technologies such as the metal based DPFs. The latter had, in the past, issues with respect to filtration efficiency, available filtration area and, sometimes, their manufacturing cost, the latter factor making them less attractive for most of the conventional Diesel engine powered vehicles. Nevertheless, metal substrate DPFs may find a better position in vehicles like Diesel hybrids and REVs in which high instant power consumption is readily offered enabling electrical filter regeneration.

Diesel urban buses and refuse trucks are part of the particulate emissions sources that affect city air quality. In order to reduce particulate pollutant emissions, a development program has been carried out based on a Euro 4 engine with a DPF technology. Currently, for Euro 4 compliance, SCR is the favoured technology. To avoid a completely new development, the Exoclean™ DPF system was located after the SCR. Catalyst. The severe operating conditions and the location of the DPF necessitated the development of an active system based on the association of a DPF and a Fuel-Borne Catalyst. A Renault Trucks MD9 engine was used. This work was funded by ADEME (French Agency for Environment and Energy Management). Due to severe stop and go duty cycles and the interest to fit the DPF downstream of the SCR, this study shows the benefit of using an active DPF with an FBC to ensure full regeneration even at low temperatures.

As different Diesel Particulate Filter (DPF) designs and media are becoming widely adopted, research efforts in the characterization of their influence on particle emissions intensify. In the present work the influence of a Diesel Oxidation Catalyst (DOC) and five different Diesel Particulate Filters (DPFs) under steady state and transient engine operating conditions on the particulate and gaseous emissions of a common-rail diesel engine are studied. An array of particle measuring instrumentation is employed, in which all instruments simultaneously measure from the engine exhaust. Each instrument measures a different characteristic/metric of the diesel particles (mobility size distribution, aerodynamic size distribution, total number, total surface, active surface, etc.) and their combination assists in building a complete characterization of the particle emissions at various measurement locations: engine-out, DOC-out and DPF-out.

Following the successful market introduction of diesel particulate filters (DPFs), this class of emission control devices is expanding to include additional functionalities such as gas species oxidation (such as CO, HC and NO), storage phenomena (such as NOx and NH3 storage) to the extent that we should today refer not to DPFs but to Multifunctional Reactor Separators. This trend poses many challenges for the modeling of such systems since the complexity of the coupled reaction and transport phenomena makes any direct general numerical approach to require unacceptably high computing times. These multi-functionalities are urgently needed to be incorporated into system level emission control simulation tools in a robust and computationally efficient manner. In the present paper we discuss a new framework and its application for the computationally efficient implementation of such phenomena.

Direct catalytic soot oxidation is expected to become an important component of future diesel particulate emission control systems. The development of advanced Catalytic Diesel Particulate Filters (CDPFs relies on the interplay of chemistry and geometry in order to enhance soot-catalyst proximity. An extensive set of well-controlled experiments has been performed to provide direct catalytic soot oxidation rates in CDPFs employing small-scale side-stream sample exposure. The experiments are analyzed with a state-of-the-art diesel particulate filter simulator and a set of kinetic parameters are derived for direct catalytic soot oxidation by fuel-borne catalysts as well as by catalytic coatings. The influence of soot-catalyst proximity, on catalytic soot oxidation is found to be excellently described by the so-called Two-Layer model, developed previously by the authors.

The IAPAC Direct fuel Injection (DI) system, developed by IFP, has already well proven its capability to reduce pollutants emissions and fuel consumption of 2-stroke engines. This crankcase Compressed Air Assisted Fuel Injection Process allowing the introduction of the fuel separately from the scavenging air, minimizes the fuel short-circuiting. In earlier works, results of the implementation of the IAPAC system on cylinder displacement from 125 cc to 400 cc have been presented in various papers. These first prototypes were all using a camshaft to drive the IAPAC DI poppet valve, which was considered as a limitation for applying this system to small displacement 2-stroke engines. The new SCIP™ system is no more using a camshaft neither driveshaft, or any electric power supply to drive the DI air assisted injection valve.

Future diesel emission control systems have to effectively operate under non-conventional low-temperature combustion engine operating conditions. In this work the research and development efforts for the realization of a Multi-Functional catalyst Reactor (MFR) for the exhaust of the upcoming diesel engines is presented. This work is based on recent advances in catalytic nano-structured materials synthesis and coating techniques. Different catalytic functionalities have been carefully distributed in the filter substrate microstructure for maximizing the direct and indirect (NO2-assisted) soot oxidation rate, the HC and CO conversion efficiency as well as the filtration efficiency. Moreover, a novel filter design has been applied to enable internal heat recovery capability by the implementation of heat exchange between the outlet and the inlet to the filter flow paths.

Establishing a certain maintenance-free time period regarding modern diesel exhaust emission control systems is of major importance nowadays. One of the most serious problems Diesel Particulate Filter (DPF) manufacturers face concerning system's durability is the performance deterioration due to the filter aging because of the accumulation of the ash particles. The evaluation of the effect of the ash aging on the filter performance is a time and cost consuming task that slows down the process of manufacturing innovative filter structures and designs. In this work we present a methodology for producing filter samples aged by accumulating ash produced by the controlled pyrolysis of oil-fuel solutions. Such ash particles bear morphological (size) and compositional similarity to ash particles collected from engine aged DPFs. The ash particles obtained are compared to those from real engine operation.

In the present work we derive analytical solutions for the problem of convection, diffusion and chemical reaction in wall-flow monoliths. The advantage of having analytical instead of numerical treatments is clear as the analytical solutions not only can be exploited to bring full scale simulations of diesel particulate filters to the real time domain, but also they enable efficient implementations on computationally limited engine control units (ECUs) for on-board management and control of emission control systems. The presentation describes the mathematical problem formulation, the governing dimensionless parameters and the corresponding assumptions. Then the analytical solution is derived and several asymptotic (for limiting values of the parameters) and approximating solutions are developed, corresponding to different physical situations. Reactant distributions in the filter are presented and discussed for several values of the parameters.

Diesel Particulate Filter (DPF) behavior depends strongly on the microstructural properties of the deposited soot aggregates. In the past the issue of the growth process of soot deposits in honeycomb ceramic filters has been addressed under non-reactive conditions and the influence of the filter operating conditions has been defined in terms of the dimensionless Peclet number. In the present work appropriate soot cake microstructural descriptors are studied under reactive conditions for different oxidation modes. To this end the effect of deposit microstructure on the soot oxidation kinetics is investigated. Different microstructural models for the reacting soot deposit are examined in a unified fashion and a generalized constitutive equation is obtained, describing several modes of microstructure evolution (shrinking layer, shrinking density, discrete columnar and continuous columnar).

In urban areas, particulate emission from Diesel engines is one of the pollutants of most concern. As a result, particulate emission control from urban bus Diesel engines using particulate filter technology is being introducing in La Rochelle. The Diesel Particulate Filter (DPF) introduction on the existing urban bus fleet has been initiated by the CDA La Rochelle through a voluntary retrofit program. The class of urban bus to be retrofitted is based on EURO 1 and EURO 2 Diesel engines, using a standard European Diesel fuel with 300ppm of Sulphur content. In that case, the appropriated technology for DPF regeneration requires a very flexible strategy for DPF regeneration, such as the use of the Ceria-based Fuel-Borne Catalysts. The paper describes the practical approach developed to install and optimize the DPF System on the urban buses.

Diesel particulate trap regeneration is a complex process involving the interaction of phenomena at several scales. A hierarchy of models for the relevant physicochemical processes at the different scales of the problem (porous wall, filter channel, entire trap) is employed to obtain a rigorous description of the process in a multidimensional context. The final model structure is validated against experiments, resulting in a powerful tool for the computer-aided study of the regeneration behavior. In the present work we employ this tool to address the effect of various spatial non-uniformities on the regeneration characteristics of diesel particulate traps. Non-uniformities may include radial variations of flow, temperature and particulate concentration at the filter inlet, as well as variations of particulate loading. In addition, we study the influence of the distribution of catalytic activity along the filter wall.

In an optical accessible 4-stroke engine laser-induced fluorescence (LIF) imaging measurements of fuel tracer (3-pentanone) and formaldehyde were performed during the compression stroke and combustion. Formaldehyde (HCHO) is intermediately present at high concentrations within the cool flame and is burned later on when the “hot” combustion proceeds. It can be used as an internally generated tracer to observe the boundaries of the hot combustion zones. Despite the fact that a frequency-tripled Nd:YAG laser excites only weak transitions in the HCHO molecule, the high concentration (several thousands ppm) provide for sufficient signal intensity when detecting fluorescence above 395 nm. Using formaldehyde LIF, auto-ignition (occurring close to 356°ca) and the further development of combustion was observed.

The IAPAC® Direct fuel Injection (DI) system, developed by IFP, has already well proven its capability to reduce pollutants emissions and fuel consumption of 2-stroke engines for both 2-wheeler and marine outboard application. This crankcase Compressed Air Assisted Fuel Injection process allowing the introduction of the fuel separately from the scavenging air, minimizes the fuel short-circuiting and has shown its potential on various prototype demonstrators. This paper presents the development and pre-industrialization work performed to apply this concept to an SELVA Marine 2-cylinder 50 HP outboard 2-stroke engine. A standard carbureted engine has been converted to a IAPAC® prototype engine by mainly modifying the cylinder head. Then, this prototype engine has been calibrated, tested and optimized on the dyno test bench to comply with future emissions regulation while keeping similar power output than the reference carbureted engine.