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Sources of unburned hydrocarbon (UHC) emissions are examined for a highly dilute (10% oxygen concentration), moderately boosted (1.5 bar), low load (3.0 bar IMEP) operating condition in a single-cylinder, light-duty, optically accessible diesel engine undergoing partially-premixed low-temperature combustion (LTC). The evolution of the in-cylinder spatial distribution of UHC is observed throughout the combustion event through measurement of liquid fuel distributions via elastic light scattering, vapor and liquid fuel distributions via laser-induced fluorescence, and velocity fields via particle image velocimetry (PIV). The measurements are complemented by and contrasted with the predictions of multi-dimensional simulations employing a realistic, though reduced, chemical mechanism to describe the combustion process.

The objective of this research is a detailed investigation of multiple injections in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the performance and emissions benefits of multiple injections via experiments and simulations in a 0.48L signal cylinder light-duty engine operating at 2000 r/min and 5.5 bar IMEP. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2]. This study examines the effects of fuel split distribution, injection event timing, rail pressure, and boost pressure which are each explored within a defined operation range in LTC.

The objective of this research is a detailed investigation of unburned hydrocarbon (UHC) in a highly-dilute diesel low temperature combustion (LTC) regime. This research concentrates on understanding the mechanisms that control the formation of UHC via experiments and simulations in a 0.48L signal-cylinder light duty engine operating at 2000 r/min and 5.5 bar IMEP with multiple injections. A multi-gas FTIR along with other gas and smoke emissions instruments are used to measure exhaust UHC species and other emissions. Controlled experiments in the single-cylinder engine are then combined with three computational tools, namely heat release analysis of measured cylinder pressure, analysis of spray trajectory with a phenomenological spray model using in-cylinder thermodynamics [1], and KIVA-3V Chemkin CFD computations recently tested at LTC conditions [2].

The post-flame oxidation of unburned hydrocarbons released from the ring-pack crevice was investigated for a small, air-cooled, spark-ignition utility engine. Spark timing sweeps were performed at 50, 75 and 100% load and speeds of 1800, 2400 and 3060 RPM while operating at a 12:1 air-fuel ratio, which is typical for these engines. A global HC consumption rate (GCR) was introduced based on the temporal profile of the mass released from the ring pack; the mass release after CA90 and up to the point where the remainder of the ring pack HC mass is equal to the exhaust HC level was taken as the mass oxidized, and a rate was defined based on this mass and the corresponding crank angle period over which this took place. For all conditions tested, the GCR varied with the spark timing; advanced spark timing gave higher GCR.

An experimental study has been conducted to provide insight into heat transfer to the piston of a light-duty single-cylinder research engine under Conventional Diesel (CDC), Homogeneous Charge Compression Ignition (HCCI), and Reactivity Controlled Compression Ignition (RCCI) combustion regimes. Two fast-response surface thermocouples embedded in the piston top measured transient temperature. A commercial wireless telemetry system was used to transmit thermocouple signals from the moving piston. A detailed comparison was made between the different combustion regimes at a range of engine speed and load conditions. The closed-cycle integrated and peak heat transfer rates were found to be lower for HCCI and RCCI when compared to CDC. Under HCCI operation, the peak heat transfer rate showed sensitivity to the 50% burn location.

The transient response of an engine with both High Pressure (HP) and Low Pressure (LP) EGR loops was compared by conducting step changes in EGR fraction at a constant engine speed and load. The HP EGR loop performance was shown to be closely linked to turbocharger performance, whereas the LP EGR loop was relatively independent of turbocharger performance and vice versa. The same experiment was repeated with the variable geometry turbine vanes completely open to reduce turbocharger action and achieve similar EGR rate changes with the HP and LP EGR loops. Under these conditions, the increased loop volume of the LP EGR loop prolonged the response of intake O2 concentration following the change in air-fuel ratio. The prolonged change of intake O2 concentration caused emissions to require more time to reach steady state as well. Strong coupling between the HP EGR loop and turbochargers was again observed using a hybrid EGR strategy.

An experimental investigation was conducted to explore the impact in-cylinder pressure oscillations have on piston heat transfer. Two fast-response surface thermocouples embedded in the piston top measured transient temperature and a commercial wireless telemetry system was used to transmit thermocouple signals from the moving piston. Measurements were made in a light-duty single-cylinder research engine operated under low temperature combustion regimes including Homogeneous Charge Compression Ignition (HCCI) and Reactivity Controlled Compression Ignition (RCCI) and Conventional Diesel (CDC). The HCCI data showed a correlated trend of higher heat transfer with increased pressure oscillation strength, while the RCCI and CDC data did not. An extensive HCCI data set was acquired. The heat transfer rate - when corrected for differences in cylinder pressure and gas temperature - was found to positively correlate with increased pressure oscillations.

High resolution planar laser-induced fluorescence (PLIF) measurements were performed in an optically accessible internal combustion (IC) engine to investigate the behavior of scalar dissipation and the fine-scale structures of the turbulent scalar field. The fluorescent tracer fluorobenzene was doped into one of the two intake streams and nitrogen was used as the carrier gas to permit high signal-to-noise ratio fluorescence measurements without oxygen quenching effects. The resulting two-dimensional images allowed for an analysis of the structural detail of the scalar and scalar dissipation fields defined by the mixing of the two adjacent intake streams. High levels of scalar dissipation were found to be located within convoluted, sheet-like structures in accordance with previous studies. The fluorescence data, which were acquired during the intake stroke, were also used to examine the scalar energy and dissipation spectra.

A detailed comparison of cylinder pressure derived combustion performance and engine-out emissions is made between an all-metal single-cylinder light-duty diesel engine and a geometrically equivalent engine designed for optical accessibility. The metal and optically accessible single-cylinder engines have the same nominal geometry, including cylinder head, piston bowl shape and valve cutouts, bore, stroke, valve lift profiles, and fuel injection system. The bulk gas thermodynamic state near TDC and load of the two engines are closely matched by adjusting the optical engine intake mass flow and composition, intake temperature, and fueling rate for a highly dilute, low temperature combustion (LTC) operating condition with an intake O2 concentration of 9%. Subsequent start of injection (SOI) sweeps compare the emissions trends of UHC, CO, NOx, and soot, as well as ignition delay and fuel consumption.

In-cylinder velocity measurements were acquired in a two-valve, single-cylinder research engine to study the bulk fluid motion and small-scale turbulence. Different port geometries (two), different port orientations (two) and both shrouded and non-shrouded intake valves were tested to vary the intake-generated flow. Tests were performed at engine speeds of 300, 600, 900 and 1200 RPM with an atmospheric intake pressure. Prior to testing on the engine, the different head configurations were tested on a steady flow bench. Particle image velocimetry data were taken on a single plane, parallel to the piston surface, in the engine using both a low magnification to characterize the large-scale flow phenomena, and a high magnification to characterize the turbulence field. The low-magnification results showed that the swirl center location was relatively insensitive to engine speed, but did change position throughout the cycle.

Reactivity controlled compression ignition combustion was investigated for three fuel combinations: isooctane-diesel, PRF90-diesel, and E85-diesel. Experiments were conducted at 1200 rpm, 160 kPa absolute intake pressure, and fixed total fuel energy using ‘optimal’ operating condition for each fuel combination that were chosen based on combustion performance from SOI timing and premixed energy fraction sweeps. The heat release duration was found to scale with the difference in reactivity between the premixed and direction injected fuel; a small difference gives rise to short heat release duration, similar to that of HCCI combustion. Conversely, as the difference increases, the heat release period lengthens. The high-speed optical data confirmed that the combustion occurred in a staged manner from the high-reactivity zones, which were located at the periphery of the chamber, to low-reactivity zones in the field of view.

Deviations between transient and steady state operation of a modern light duty diesel engine were identified by comparing rapid load transitions to steady state tests at the same speeds and fueling rates. The validity of approximating transient performance by matching the transient charge air flow rate and intake manifold pressure at steady state was also assessed. Results indicate that for low load operation with low temperature combustion strategies, transient deviations of MAF and MAP from steady state values are small in magnitude or short in duration and have relatively little effect on transient engine performance. A new approximation accounting for variations in intake temperature and excess oxygen content of the EGR was more effective at capturing transient emissions trends, but significant differences in magnitudes remained in certain cases indicating that additional sources of variation between transient and steady state performance remain unaccounted for.

In current systems, for a given nozzle and injection pressure (pump speed), the shape of the injection rate is fixed and the injection timing is the only variable the engine designer can vary. For this non-interactive injection system, changing the injector nozzle (number and diameter of holes) will proportionately change the injection shape. New injection systems in which the rate of injection is a controlled variable are being developed. Results from one such injector, called the UCORS (Universal Combustion Optimization and Rate Shaping), are reported in this paper. The system can dynamically control its injection rate shape by controlling the position and size of a pilot injection relative to the main injection. Data and analysis from an out-of-engine and combustion chamber study of the UCORS injection system are presented.

There is a significant global effort to study low temperature combustion (LTC) as a tool to achieve stringent emission standards with future light duty diesel engines. LTC utilizes high levels of dilution (i.e., EGR > 60% with <10%O2 in the intake charge) to reduce overall combustion temperatures and to lengthen ignition delay, This increased ignition delay provides time for fuel evaporation and reduces in-homogeneities in the reactant mixture, thus reducing NOx formation from local temperature spikes and soot formation from locally rich mixtures. However, as dilution is increased to the limits, HC and CO can significantly increase. Recent research suggests that CO emissions during LTC result from the incomplete combustion of under-mixed fuel and charge gas occurring after the premixed burn period [1, 2]1. The objective of the present work was to increase understanding of the HC/CO emission mechanisms in LTC at part-load.

This computational study compares predictions and experimental results for the use of direct injected iso-octane fuel during the negative valve overlap (NVO) period to achieve HCCI combustion. The total fuel injection was altered in two ways. First the pre-DI percent, (the ratio of direct injected fuel during the NVO period “pre-DI” to the secondary fuel supplied at the intake manifold “PI”), was varied at a fixed pre-DI injection timing, Secondly the timing of the pre-DI injection was varied while all of the fuel was supplied during the NVO period. A multi-zone, two-dimensional CFD simulation with chemistry was performed using KIVA-3V release 2 implemented with the CHEMKIN solver. The simulations were performed during the NVO period only.

A single cylinder Yamaha research engine was operated with gasoline HCCI combustion using negative valve overlap (NVO). The injection strategy for this study involved using fuel injected directly into the cylinder during the NVO period (pre-DI) along with a secondary injection either in the intake port (PI) or directly into the cylinder (DI). The effects of timing of the pre-DI injection along with the percent of fuel injected during the pre-DI injection were studied in two sets of experiments using secondary PI and DI injections in separate experiments. Results have shown that by varying the pre-DI timing and pre-DI percent the main HCCI combustion timing can be influenced as a result of varied heat release during the negative valve overlap period along with hypothesized varied degrees of reformation of the pre-DI injected fuel. In addition to varying the main combustion timing the ISFC, emissions and combustion stability are all influenced by changes in pre-DI timing and percent.

Multi-zone CFD simulations with detailed kinetics were used to model iso-octane HCCI experiments performed on a single-cylinder research engine. The modeling goals were to validate the method (multi-zone combustion modeling) and the reaction mechanism (LLNL 857 species iso-octane) by comparing model results to detailed exhaust speciation data, which was obtained with gas chromatography. The model is compared to experiments run at 1200 RPM and 1.35 bar boost pressure over an equivalence ratio range from 0.08 to 0.28. Fuel was introduced far upstream to ensure fuel and air homogeneity prior to entering the 13.8:1 compression ratio, shallow-bowl combustion chamber of this 4-stroke engine. The CFD grid incorporated a very detailed representation of the crevices, including the top-land ring crevice and head-gasket crevice. The ring crevice is resolved all the way into the ring pocket volume. The detailed grid was required to capture regions where emission species are formed and retained.

Predictive models of soot formation during Diesel combustion are of great practical interest, particularly in light of newly proposed strict regulations on particulate emissions. A modified version of the phenomenological model of soot formation developed previously has been implemented in KIVA-II CFD code. The model includes major generic processes involved in soot formation during combustion, i.e., formation of soot precursors, formation of surface growth species, soot particle nucleation, coagulation, surface growth and oxidation. The formulation of the model within the KIVA-II is fully coupled with the mass and energy balances in the system. The model performance has been tested by comparison with the results of optical in-cylinder soot measurements in a single cylinder Cummins NH Diesel engine. The predicted soot volume fraction, number density and particle size agree reasonably well with the experimental data.

The effects of fuel composition on homogeneous charge compression ignition (HCCI) combustion were studied experimentally in an engine employing negative valve overlap (NVO). Three test fuels, varying in ignition quality and volatility, were investigated for their effect on engine performance and combustion phasing; comparisons were made to a full-run 87-octane base fuel. The three test fuels, which varied in research octane number from 69 to 98, were all found to advance the combustion timing slightly relative to the base fuel, suggesting some differences in the ignition chemistry. The combustion performance at a fixed combustion phasing, however, was found to be comparable, within the limits of the system, for all of the fuels. A major testing issue that limited the system repeatability was the formation of combustion chamber deposits under some operating conditions. A methodology to mitigate these effects was employed with some success.

Multi-dimensional computational efforts using comprehensive and skeletal kinetics have been made to investigate the cool flame region in HCCI combustion. The work was done in parallel to an experimental study that showed the impact of the negative temperature coefficient and the cool flame on the start of combustion using different fuels, which is now the focus of the simulation work. Experiments in a single cylinder CFR research engine with n-butane and a primary reference fuel with an octane number of 70 (PRF 70) were modeled. A comparison of the pressure and heat release traces of the experimental and computational results shows the difficulties in predicting the heat release in the cool flame region. The behavior of the driving radicals for two-stage ignition is studied and is compared to the behavior for a single-ignition from the literature. Model results show that PRF 70 exhibits more pronounced cool flame heat release than n-butane.