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Combustion visualizations were carried out in a constant volume vessel to study the partially premixed combustion of a gasoline-like fuel using high speed imaging. The test fuel (G80H20) is composed by volume 80% commercial gasoline and 20% n-heptane. The effects of ambient gas composition, ambient temperature and injection pressure on G80H20 combustion characteristics were analyzed. Meanwhile, a comparison of the EGR effect on combustion process between G80H20 and diesel was made. Four ambient gas conditions that represent the in-cylinder gas compositions of a heavy-duty diesel engine with EGR ratios of 0%, 20%, 40% and 60% were used to simulate EGR conditions. Variables also include two ambient temperature (910K and 870K) and two injection pressure (20 MPa and 50 MPa) conditions.

Diesel soot suppression effects of catalytic fuel additives for a range of fuels with different properties were investigated with calcium naphthenate. A single cylinder DI diesel engine and a thermobalance were used to determine the soot reduction and its mechanism for seven kinds of fuels. Experimental results showed that the catalytic effect of the fuel additive was different for the different fuels, and could be described by a parameter considering cetane number and kinematic viscosity. The fuel additives reduced soot more effectively for fuels with higher cetane number and lower kinematic viscosity. This result was explained by soot oxidation characteristics for the different fuels. Oxidation of soot with the metallic additive proceeds in two stages: stage I, a very rapid oxidation stage; and stage II, a following slow or ordinary oxidation stage.

This research investigates the influences of the injection timing, injection pressure, and compression ratio on the combustion and exhaust emissions in a single cylinder 1.0 L DI diesel engine operating with ultra-high EGR. Longer ignition delays due to either advancing or retarding the injection timing reduced the smoke emissions, but advancing the injection timing has the advantages of maintaining the thermal efficiency and preventing misfiring. Smokeless combustion is realized with an intake oxygen content of only 9-10% regardless of the injection pressure. Reduction in the compression ratio is effective to reduce the in-cylinder temperature and increase the ignition delay as well as to expand the smokeless combustion range in terms of EGR and IMEP. However, the thermal efficiency deteriorates with excessively low compression ratios.

Soot emissions in the combustion process of diesel engines are greatly harmful to the environment and human health. Consequently, there is large interest and great efforts in decreasing soot emission from diesel engines to meet the increasingly stringent emission standards. The mechanisms of soot formation and oxidation so far have not been well understood. Laser induced incandescence (LII) is particularly suited to measure the instantaneous spatial distribution of the soot volume concentration, which can offer much needed detailed information of soot distribution for better understanding of soot formation and oxidation. In this paper, a two-color laser induced incandescence (2C-LII) technique was implemented for measuring absolute soot volume fraction in a laminar diesel fuel diffusion flame.

Urea Selective Catalytic Reduction (SCR) has been proven to significantly reduce NOx emissions from diesel engines. The thermal decomposition of urea, which forms the ammonia as the reactant, has a crucial effect on the performance and durability of the NOx-SCR system. The incomplete thermal decomposition of urea not only reduces the NOx conversion ratio and increases the ammonia slip, but also leads to deposit formation on the catalyst surface, which will block the pore and the active sites of the catalyst and then decreases the durability of the SCR systems. In this paper, the urea thermolysis was measured using the Thermal Gravimetric Analysis (TGA) and Fourier Transform Infrared Spectroscopy (FTIR). Then, the performance of the SCR systems under different injection parameters of the Urea-water solution was investigated on a diesel engine test bench. Finally, the deposits on the catalyst were also analyzed using TGA and FTIR.

Beijing will implement the 4th stage emission regulations (equivalent to Euro IV) in 2008 ahead of other provinces or cites in China. Beijing Environmental Protection Bureau (EPB) organized petroleum corporations, automobile and engine manufactories as well as research institutes to test the adaptability of the fuels from Chinese refineries to the modern vehicles or engines on the road running conditions in China. In this paper, the effects of diesel fuel quality on combustion and emission of a Euro IV heavy-duty diesel engine as one part of the program were studied to provide technical data to stipulate the feasible diesel fuel standard, which should guarantee modern vehicles or engines to meet the 4th stage regulations. Eight kinds of diesel fuels with different properties, such as cetane number, distillation temperature (T90) and sulfur content, were tested on a Euro IV Cummins heavy-duty diesel engine with urea SCR after-treatment.

A concept of high density-low temperature combustion (HD-LTC) is put forward in this paper, showing potential of its high thermal efficiency and very low engine-out emissions by engine experimental and CFD modeling study. A single cylinder test engine has been built-up equipped with mechanisms of variable boost pressure and intake valve closing timing (IVCT). By delaying IVCT and raising boost pressure to certain values according to engine loads, the in-cylinder charge density is regulated much higher than in conventional engines. It is found that the high charge density can play the role of rising of heat capacity as exhaust gas recirculation (EGR) does. Thereby low temperature combustion is realized with less EGR (about 18~19% oxygen concentration) to achieve very low NOx and soot emissions, which is extremely important at high and full loads.

In a DI diesel engine, THC emissions increase significantly with lower compression ratios, a low coolant temperature, or during the transient state. During the transient after a load increase, THC emissions are increased significantly to very high concentrations from just after the start of the load increase until around the 10th cycle, then rapidly decreased until the 20th cycle, before gradually decreasing to a steady state value after 1000 cycles. In the fully-warmed steady state operation with a compression ratio of 16 and diesel fuel, THC is reasonably low, but THC increases with lower coolant temperatures or during the transient period just after increasing the load. This THC increase is due to the formation of over-lean mixture with the longer ignition delay and also due to the fuel adhering to the combustion chamber walls. A low distillation temperature fuel such as normal heptane can eliminate the THC increase.

On the basis of modular pulse converter (MPC) exhaust system the authors present a new swirl exhaust system. Structural parameters on the swirl exhaust system and MPC system for N8160ZC diesel engine were calculated by a mathematical optimum method, and the two systems were tested under the same engine operation for comparison. Experimental results show that the swirl exhaust system has a better engine performance under most of the operating conditions than MPC system, but worse under the low-speed and part-load conditions. In order to understand the mechanism of this swirl exhaust system well, a three-dimensional particle dynamic analyzer (3D-PDA) was utilized to measure the steady turbulent airflow in a swirl three-branched model. The computational fluid dynamics (CFD) code KIVA was modified to simulate the flows. Computational results are in good agreement with measuring ones and reveal the swirl flow behavior in the junction.

The thermal cracking and polyaromatic hydrocarbon (PAH) formation processes of dimethyl ether (DME), ethanol, and ethane were investigated with chemical kinetics to determine the soot formation mechanism of oxygenated fuels. The modeling analyzed three processes, an isothermal constant pressure condition, a temperature rising condition under a constant pressure, and an unsteady condition approximating diesel combustion. With the same mole number of oxygen atoms, the DME rich mixtures form much carbon monoxide and methane and very little non-methane HC and PAH, in comparison with ethanol or ethane mixtures. This suggests that the existence of the C-C bond promotes the formation of PAH and soot.

Time resolved changes in unburned hydrocarbon emissions and their components were investigated in a DI diesel engine with a specially developed gas sampling system and gas chromatography. The tested transient operations include starting and increasing loads. At start-up with high equivalence ratios the total hydrocarbon (THC) at first increased, and after a maximum gradually decreased to reach a steady state value. Reducing the equivalence ratio of the high fueling at start-up and shortening the high fueling duration are effective to reduce THC emissions as long as sufficient startability is maintained. Lower hydrocarbons, mainly C1-C8, were the dominant components of the THC and mainly determined the THC behavior in the transient operations while the proportion of hydrocarbon (HC) components did not significantly change. The unregulated toxic substances, 1,3 butadiene and benzene were detected in small quantities.

Smokeless and ultra low NOx combustion without knocking in a dual-fuel diesel engine with induced LPG as the main fuel was established with a uniquely developed piston cavity divided by a lip in the sidewall. A small quantity of diesel fuel was directly injected at early compression stroke into the lower part of the cavity as an ignition source for this confined area, and this suppressed explosively rapid combustion just after ignition and spark-knock like combustion at later stage. A combination of the divided cavity, EGR, and intake air throttling was effective to simultaneously eliminate knocking, and reduce THC and NOx significantly.

The control of fuel ignition timing and suppression of rapid combustion in a premixed charge compression ignition (PCCI) engine was attempted with direct in-cylinder injection of water as a reaction suppressor. The water injection significantly reduced the heat release at low temperature oxidation, which suppressed the increase in charge temperature after the low temperature oxidation and the rapid combustion caused by the high temperature oxidation. The possible engine operating range with ultra low NOx and smokeless combustion was extended to a higher load range with the water injection. Rapid combustion was suppressed by reductions in the maximum in-cylinder gas temperature due to water injection while the combustion efficiency suffered. Therefore, the maximum charge temperature needs to be controlled within an extremely limited range to maintain a satisfactory compromise between mild combustion and high combustion efficiency.

The fundamental parameters related to engine combustion and performances, such as, heating value, theoretical air-fuel ratio, adiabatic flame temperature, carbon dioxide (CO2), and nitric oxide (NO) emissions, specific heat and engine thermal efficiency were investigated with computations for a wide range of oxygenated fuels. The computed results showed that almost all of the above combustion-related parameters are closely related to oxygen content in the fuels regardless of the kinds or chemical structures of oxygenated fuels. An interesting finding was that with the increase in oxygen content in the fuels NO emission decreased linearly, and the engine thermal efficiency was almost unchanged below oxygen content of 30 wt-% but gradually decreased above 30 wt-%.

Direct injection of various ignition suppressors, including water, methanol, ethanol, 1-propanol, hydrogen, and methane, was implemented to control ignition timing and expand the operating range in an HCCI engine with induced DME as the main fuel. Ultra-low NOx and smoke-less combustion was realized over a wide operating range. The reaction suppressors reduced the rate of low-temperature oxidation and consequently delayed the onset of high-temperature oxidation. Analysis of the chemical kinetics showed a reduction of OH radical in the premixed charge with the suppressors. Among the ignition suppressors, alcohols had a greater impact on OH radical reduction resulting in stronger ignition suppression. Although water injection caused a greater lowering of the temperature, which also suppressed ignition, the strong chemical effect of radical reduction with methanol injection resulted in the larger impact on suppression of oxidation reaction rates.

Light naphtha, which exhibits two-stage ignition, was induced from the intake manifold for ignition enhancement and a low ignitability fuel or water, which does not exhibit low temperature oxidation, was directly injected early in the compression stroke for ignition suppression in an HCCI engine. Their quantitative balance was flexibly controlled to optimize ignition timing according to operating condition. Ultra-low NOx and smokeless combustion without knocking or misfiring was realized over a wide operating range. Alcohols inhibit low temperature oxidation more strongly than other oxygenated or unoxygenated hydrocarbons, water, and hydrogen. Chemical kinetic modeling for methanol showed a reduction of OH radical concentration before the onset of low temperature oxidation, and this may be the main mechanism by which alcohols inhibit low temperature oxidation.

Combustion control strategy for high efficiency and low emissions in a heavy duty (H D) diesel engine was investigated experimentally in a single cylinder test engine with a common rail fuel system, EGR (Exhaust Gas Recirculation) system, boost system and retarded intake valve closing timing actuator. For the operation loads of IMEPg (Gross Indicated Mean Effective Pressure) less than 1.1 MPa the low temperature combustion (LTC) with high rate of EGR was applied. The fuel injection modes of either single injection or multi-pulse injections, boost pressure and retarded intake valve closing timing (RIVCT) were also coupled with the engine operation condition loads for high efficiency and low emissions. A higher boost pressure played an important role in improving fuel efficiency and obtaining ultra-low soot and NOx emissions.

In this study, the internal nozzle flow and macroscopic spray characteristics of a kind of wide distillation fuel (WDF) - kerosene were investigated both with numerical and experimental approaches. Simulation results indicate that compared with diesel fuel, kerosene cavitates more due to higher turbulent kinetic energy as a result of lower viscosity. The results from experiment indicate that under lower charge density, the spray penetration for kerosene is obviously shorter than that for diesel, especially for the lower injection pressure. This is because lower fuel viscosity results in a reduction in the size of the spray droplets, leading to lower momentum. However the spray angle of kerosene is larger compared with diesel due to stronger turbulence in the nozzle flow caused by increased cavitation for kerosene, which also accords well with the simulation results.

In this study, experimental and simulation investigations on the roles of charge density (ρtdc), temperature (Τtdc) at the top dead center and oxygen concentration (φO2) on the combustion paths, emissions and thermal efficiency of a high load operation diesel engine were conducted. Experimental engine was a modified single-cylinder engine equipped with variable mechanisms of boost, exhaust gas recirculation (EGR) and intake valve closing timing (IVCT) to regulate the Ptdc, φO2 and Τtdc. Simulations of engine combustion processes were performed with an ECFM-3Z combustion model. The results revealed that higher Ptdc, leading to lower overall fuel/oxygen equivalence ratio (Φm), enhanced the rate of mixing and chemical reaction and benefited improvement of the thermal efficiency.

In this study, Partially Premixed Combustion (PPC) on a modified heavy-duty diesel engine was realized by hybrid combustion control strategy with flexible fuel injection timing, injection rate pattern modulation and high ratio of exhaust gas recirculation (EGR) at different engine loads. It features with different degrees of fuel/air mixture stratifications. The very low soot emissions of the experiments called for further understanding on soot formation mechanism so that to promote the capability of prediction. A new soot model was developed with highlight in effects of surface activity on soot growth for soot formation prediction in partially premixed combustion diesel engine. According to previous results from literatures on the importance of acetylene as growth specie of PAH and soot surface growth, a gas-phase reduced kinetic model of acetylene formation was developed and integrated into the new soot model.