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Advances in aftertreatment technologies, such as Diesel Particulate Filters (DPF) and Selective Catalytic Reduction (SCR) catalysts, have responded to increasingly stringent PM and NO requirements for diesel engines. Potentially viable SCR materials include copper and iron zeolite, which possess high thermal durabilities and conversion efficiencies. However, concern exists over the metal-catalyzed synthesis of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs), especially since typical SCR operating temperatures overlap with optimal PCDD/F formation from the de novo and precursor mechanisms. Due to the lack of standardized testing methodology for measuring PCDD/F emissions from mobile sources, this study adapted EPA methods 0023A and TO-9A from their original applications of industrial stack and ambient air sampling.

Nitrous oxide (N2O), with a global warming potential (GWP) of 297 and an average atmospheric residence time of over 100 years, is an important greenhouse gas (GHG). In recognition of this, N2O emissions from on-highway medium- and heavy-duty diesel engines were recently regulated by the US Environmental Protection Agency (EPA) and National Highway Traffic Safety Administration’s (NHTSA) GHG Emission Standards. Unlike NO and NO2, collectively referred to as NOx, N2O is not a major byproduct of diesel combustion. However, N2O can be formed as a result of unselective catalytic reactions in diesel aftertreatment systems, and the mitigation of this unintended N2O formation is a topic of active research. In this study, a nonroad Tier 4 Final/Stage IV engine was equipped with a vanadium-based selective catalytic reduction (SCR) aftertreatment system. Experiments were conducted over nonroad steady and both cold and hot transient cycles (NRSC and NRTC, respectively).

Control of turbulence during the compression stroke is suggested by both theoretical calculations and experimental results obtained with an LDV measurement in a motored engine. The authors have found experimentally that when an axial distribution of swirl intensity exists, a large-scale annular vortex is formed inside the cylinder during the compression stroke and this vortex generates and transports turbulence energy. A numerical calculation is adopted to elucidate this phenomenon. Then, an axial stratification of swirl intensity is found to generate a large-scale annular vortex during the compression stroke by an interaction between the piston motion and the axial pressure gradient. The initial swirl profile is parametrically varied to assess its effect on the turbulence parameters. Among calculated results, turbulence energy is enhanced strongest when the swirl intensity is highest at the piston top surface and lowest at the bottom surface of the cylinder head.

According to previous papers on the combustion process in LHR diesel engines the combustion seems to deteriorate in LHR diesel engines. However it has been unclear whether this was caused by the high temperature gas or high temperature combustion chamber walls. This study was intended to investigate the effect of gas temperature on the rate of heat release through the heat release analysis and other measurements using a rapid compression-expansion machine. Experiments conducted at high gas temperatures which was achieved by the employment of oxygen-argon-helium mixture made it clear that the combustion at a high gas temperature condition deteriorated actually and this was probably due to the poorer mixing rate because of the increase in gas viscosity at a high gas temperature condition.

Three Cordierite diesel particulate filters (DPF) with variations in the washcoat† (bare, washcoat-only, and catalyzed washcoat) were filled with equal amounts of PM (∼2 g/l) from a single steady-state engine operating condition (30% load, 1800 rpm). Two regeneration systems were used: an electrical furnace to extract the kinetic parameters by performing Temperature Programmed Oxidation (TPO) experiments and an inline burner to study how DPF washcoat variations affect active regeneration performance. Detailed emissions measurements were performed upstream and downstream of the DPF during the filtration and regeneration processes to quantify DPF filtration and regeneration performance. These measurements included gaseous emission, PM mass concentration, and particle size distribution.

The applicability of several popular diesel particulate matter (PM) measurement techniques to low temperature combustion is examined. The instruments' performance in measuring low levels of PM from advanced diesel combustion is evaluated. Preliminary emissions optimization of a high-speed light-duty diesel engine was performed for two conventional and two advanced low temperature combustion engine cases. A low PM (<0.2 g/kg_fuel) and NOx (<0.07 g/kg_fuel) advanced low temperature combustion (LTC) condition with high levels of exhaust gas recirculation (EGR) and early injection timing was chosen as a baseline. The three other cases were selected by varying engine load, injection timing, injection pressure, and EGR mass fraction. All engine conditions were run with ultra-low sulfur diesel fuel. An extensive characterization of PM from these engine operating conditions is presented.

An experimental study was performed to investigate diesel particulate filter (DPF) performance during filtration with the use of real-time measurement equipment. Three operating conditions of a single-cylinder 2.3-liter D.I. heavy-duty diesel engine were selected to generate distinct types of diesel particulate matter (PM) in terms of chemical composition, concentration, and size distribution. Four substrates, with a range of geometric and physical parameters, were studied to observe the effect on filtration characteristics. Real-time filtration performance indicators such as pressure drop and filtration efficiency were investigated using real-time PM size distribution and a mass analyzer. Types of filtration efficiency included: mass-based, number-based, and fractional (based on particle diameter). In addition, time integrated measurements were taken with a Rupprecht & Patashnick Tapered Element Oscillating Microbalance (TEOM), Teflon and quartz filters.

Three distinct types of diesel particulate matter (PM) are generated in selected engine operating conditions of a single-cylinder heavy-duty diesel engine. The three types of PM are trapped using typical Cordierite diesel particulate filters (DPF) with different washcoat formulations and a commercial Silicon-Carbide DPF. Two systems, an external electric furnace and an in-situ burner, were used for regeneration. Furnace regeneration experiments allow the collected PM to be classified into two categories depending on oxidation mechanism: PM that is affected by the catalyst and PM that is oxidized by a purely thermal mechanism. The two PM categories prove to contribute differently to pressure drop and transient filtration efficiency during in-situ regeneration.

The relation between the characteristics of a non-evaporating spray and those of a corresponding frame achieved in a rapid compression machine was investigated experimentally. The fuel injection pressure was changed in a range of 55 to 260 MPa and the other injection parameters such as orifice diameter and injection duration were changed systematically. The characteristics of the non-evaporating spray such as the Sauter mean diameter and the mean excess air ratio of the spray were measured by an image analysis technique. The time required for a pressure rise due to combustion was taken as an index to characterize the flame. It was concluded that the mean excess air ratio of a spray is the major factor which controls the burning rate and that the high injection pressure is effective in shortening the combustion duration and reducing soot formation.

The two-dimensional distribution of a soot cloud in an unsteady spray flame in a rapid compression machine(RCM) was visualized using the laser sheet scattering technique. A 40 mm x 50 mm cross section on the flame axis was illuminated by a thin laser sheet from a single pulsed Nd:YAG laser(wavelength 532 nm). Scattered light from soot particles was taken by a CCD camera via a high speed gated image intensifier. The temporal variation of the scattered light images were presented with the injection pressure as a parameter. The results showed that scattered light was intense near the periphery of the flame tip and that the scattered light becomes weaker significantly and disappears fast after the end of injection as injection pressure is increased. This technique was also applied to the visualization of the two-dimensional distribution of liquid droplets in the non-evaporating spray to correlate it with the soot concentration distribution.

An experimental evaluation of the reliability of the Zeuch's method was carried out. The following were derived: 1) cavitation limits the minimum back pressure available; 2) the injection rate measured by the Zeuch's method agrees with that by the W.Bosch's method; 3) the effect of dynamic pressure of the injected fuel jet has a negligible effect on the pressure sensor which is attached to the chamber wall; and 4) the high-frequency noise after the end of injection observed in the Zeuch's measurement can be effectively removed by either a low-pass filter or an inverse Fourier transform processing.

The structure of dense sprays was investigated using 2-D imaging techniques. To investigate the mechanism of atomization, the liquid phase in a non-evaporating spray was visualized by a thin laser sheet formed by a single pulse from a Nd:YAG laser at the distance from 4 to 19 mm from the nozzle orifice with the injection pressure and the surrounding gas density as parameters. A new technique for the visualization of vapor phase in an evaporating spray, the SSI (Silicone particle Scattering Imaging) method, was proposed to investigate the structure of the vapor phase regions of the spray.

The formation and oxidation processes of soot particles in unsteady spray flames were investigated in a quiescent atmosphere using 2-D laser sheet visualization. The mid-plane of a flame was illuminated twice during a short time-interval by a laser sheet from a double-pulsed YAG laser. An image pair of the scattered light from soot particles was taken by two intensified gated cameras in succession. The velocity vectors of soot clouds at various location in the sooting region were estimated using the spatial correlation between the image pair. The results of temporal and spatial variation of velocity and scattering intensity in the evolving soot clusters made it clear that soot is mainly formed in the periphery of the flame tip where the air entrainment is less and flame temperature favors soot formation.

Nitrogen dioxide (NO2) is known to pose a risk to human health and contributes to the formation of ground level ozone. In recognition of its human health implications, the American Conference of Governmental Industrial Hygienists (ACGIH) set a Threshold Limit Value (TLV) of 0.2 ppmv NO2 in 2012. For mobile sources, NO2 is regulated as a component of NOx (NO + NO2). In addition, the European Commission has indicated it is considering separate Euro 6 light-duty diesel and Euro VI heavy-duty diesel NO2 emissions limits likely to mitigate the formation of ground level ozone in urban areas. In this study, we conduct component-level reactor-based experiments to understand the effects that various aftertreatment catalyst technologies including diesel oxidation catalyst (DOC), diesel particulate filter (DPF), selective catalytic reduction (SCR) catalyst and ammonia oxidation (AMOX) catalyst have on the formation and mitigation of NO2 emissions.

A thermodynamic two-zone model which assumes a stoichiornetric burned gas region and unburned air region is presented in an attempt to calculate more precise rate of heat release of diesel combustion. A comparison is made of the rate of heat release obtained by the two-zone model with that obtained by the conventional single-zone model. It shows around 10 % increase in the rate of heat release with the two-zone model. The effect of state equation of gas is also examined with the single-zone model and the use of a real gas law in stead of the perfect gas law is found to yield minor difference in the rate of heat release at a high boost operating condition.

To measure the fuel vapor concentration in an unsteady evaporating spray injected into nitrogen atmosphere, the exciplex-forming method, which produces spectrally separated fluorescence from the liquid and vapor phase, was applied in this study. Two experiments were conducted to investigate the qualitative and quantitative applicability of the technique in a high temperature and high pressure atmosphere during the fuel injection period. One is to examine the thermal decomposition of TMPD dopant at a high temperature and a high pressure nitrogen atmosphere during a short period of time. The other is to calibrate the relationship between fluorescence intensity and vapor concentration of TMPD at different vapor temperatures. And then, the qualitative measurement of fuel vapor concentration distributions in diesel sprays was made by applying the technique.

The cross-sectional distribution of fuel vapor concentration in an evaporating spray was measured quantitatively by a new scattering imaging technique, silicone particle scattering imaging method, which was proposed in a previous paper[1]. When fuel containing silicone oil injected into a nitrogen environment at high temperature, the volatile base fuel in the droplets vaporized rapidly, leaving behind small droplets of silicone oil suspended in the vapor-gas mixture. The silicone oil droplets were illuminated by a thin laser sheet, and the scattered light was imaged by a CCD camera. The cross-sectional distribution of vapor concentration was estimated from the scattering image of the silicone oil droplets by Mie scattering theory. The results demonstrated clearly the inhomogeneity of the fuel vapor concentration. The distribution of vapor concentration was discontinuous, and islands of rich mixture with a scale of several millimeters existed in the center region of the spray.

Local heat flux from the flame to the combustion chamber wall, q̇, was measured the wall surfaces of a rapid compression-expansion machine which can simulate diesel combustion. Temperature of the flame zone, T1, was calculated by a thermodynamic two-zone model using measured values of cylinder pressure and flame volume. A local heat transfer coefficient was proposed which is defined as q̇/(T1-Tw). Experiments showed that the local heat transfer coefficient depends slightly on the temperature difference, T1-Tw, but depends significantly on the velocity of the flame which contacts the wall surface.

Soot concentration is very high in the periphery near the head of an unsteady spray flame which is achieved in a quiescent atmosphere in a rapid compression machine. To reduce soot concentration in this region, it was intended to improve fuel-air mixing by letting the flame impinge on a turbulence-generating plate. Two types of turbulence-generating plates, one donut-type, the other cross-type, were tested. Soot concentration in the flame was imaged using the laser shadow technique. The effect of injection pressure on soot reduction by the flame impingement was also investigated. The overall soot concentration is reduced significantly in the case when the flame impinges on the cross-type turbulence-generating plate at 50 mm (333 nozzle diameters) from the nozzle exit. The flame impingement on the cross-type turbulence-generating plate at 333 nozzle diameters makes soot reduction little dependent on injection pressures.

Air-entrainment characteristics of non-evaporating sprays and flames were measured by means of high-speed photography including ordinary shadowgraphy of sprays, back diffused light illumination photography and laser shadow photography of flames. Effects of injection pressure and nozzle orifice diameter on air-entrainment characteristics were investigated parametrically. The amount of air entrained into a flame was calculated by a two-zone thermodynamic model with data obtained from the photographs and the pressure measurement in the combustion chamber. The air-entrainment characteristics of flames were compared with those of the corresponding sprays. It showed that immediately after the start of ignition, the air entrainment into a flame increased more rapidly as compared with the corresponding spray and then, with the development of diffusion combustion, the air entrainment gradually approached that of the spray.