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Measurement of particle number was introduced in the Euro 5/6 light duty vehicle emissions regulation. Although particle number measurement systems have to be calibrated by the manufacturers, labs have to validate the proper operation of their systems within one year of the emissions test. The systems must achieve a >99% reduction of an aerosol containing 30 nm tetracontane (CH3(CH2)38CH3) particles (C40) with an inlet concentration >104 #/cm3. They must also include an initial heated dilution stage with dilution of at least 10 which outputs a diluted sample at a temperature of 150°C–400°C. The system as a whole must achieve a particle number concentration reduction factor for particles of 30 nm and 50 nm electrical mobility diameters, that is no more than 30% and 20% respectively higher, and no more than 5% lower than that for particles of 100 nm.

The heavy duty Particle Measurement Programme (PMP) inter-laboratory exercise consists of three parts: 1) the exploratory work to refine the measurement protocol, 2) the validation exercise where each lab will measure the emissions of a “golden” engine with two “golden” particle number systems simultaneously sampling from full and partial flow dilution systems, and 3) the round-robin where the emissions of a “reference” engine will be determined with a lab’s own particle number instrumentation. This paper presents the results of the exploratory work and describes the final protocol for testing in the validation exercise (and round robin) along with the necessary facility modifications required for compliance with the protocol. Key aspects of the protocol (e.g. filter material, flow rates at the full and partial flow systems, the pre-conditioning etc.) are explained and justified.

Euro 5/6 light-duty vehicle emissions regulation introduced non-volatile particle number emission measurements. The particle number measurement system consists of a volatile removal unit followed by a particle number counter with a 50% cut-point diameter at 23 nm. The volatile removal unit must achieve a >99% concentration reduction of a monodisperse aerosol of tetracontane (CH 3 (CH 2 ) 38 CH 3 ) particles of diameter ≥30 nm with inlet concentration ≥10 4 cm −3 . In this paper the evaporation of tetracontane particles in the volatile removal unit is investigated theoretically. The temperature and the residence time in the evaporation tube are discussed, as well as the possibility of nucleation events of evaporated particles at the exit of the evaporation tube. In addition, sulfuric acid nucleation at the evaporation tube exit is analyzed. Theoretical calculations are, finally, compared to experimental data.

Human health and the environment are heavily impacted by air pollution. Air quality standards for Nitrogen dioxide (NO2) and particulate matter (PM) are commonly exceeded in Europe, particularly in urban areas with high density of traffic. Road transport contributed to 39% of NOx emissions, and 11% of PM emissions in the European Union (EU) in 2017. Measurements with Portable Emissions Measurement Systems (PEMS) showed that most Euro 5 and Euro 6b diesel vehicles emitted significantly more NOx on the road than their permissible limit in the laboratory type-approval test. In that context, EU Real Driving Emissions (EU-RDE) regulation aims at securing low on-road emissions of light duty vehicles under normal conditions of use. This paper assesses the tailpipe emissions performance of Euro 6d-TEMP gasoline and diesel passenger cars, type-approved after the entry into force of the RDE regulation in September 2017.

In this study, tailpipe-sampling was used to sample the exhaust aerosol of a Stage IV tractor equipped with Diesel Oxidation Catalyst (DOC) and Selective Catalytic Reduction (SCR) aftertreatment systems. The particle emissions were characterized in terms of number concentration (particle size of > 2.5 nm), mass concentration (particle size of 6-612 nm) BC mass concentration and chemical composition (particle size of > 30 nm). The measurements were conducted on-road by setting a mobile laboratory on a trailer and pulling it with the tractor. In addition to driving, heavy-lift work cycles were tested, where separate lifts of a 1000 kg weight were conducted with the front fork of the tractor with two minutes of idling between consecutive lifts. Both a Porous Tube Diluter (PTD) with ambient temperature dilution air as well as an ejector diluter with hot dilution air were used to sample the exhaust aerosol.

In 2011 a particle number (PN) limit was introduced in the European Union's vehicle exhaust legislation for diesel passenger cars. The PN method requires measurement of solid particles (i.e. those that do not evaporate at 350 °C) with diameters above 23 nm. In 2013 the same approach was introduced for heavy duty engines and in 2014 for gasoline direct injection vehicles. This decision was based on a long evaluation that concluded that there is no significant sub-23 nm fraction for these technologies. In this paper we examine the suitability of the current PN method for L-category vehicles (two- or three-wheel vehicles and quadri-cycles). Emission levels of 5 mopeds, 9 motorcycles, 2 tricycles (one of them diesel) and 1 quad are presented. Special attention is given to sub-23 nm emission levels. The investigation was conducted with PN legislation compliant systems with particle counters measuring above 23 nm and 10 nm.

In this article we present a design of a new miniaturized sensor with the capacity to measure exhaust particle concentrations on board vehicles and engines. The sensor is characterized by ultra-fast response time, high sensitivity, and a wide dynamic range. In addition, the physical dimensions of the sensor enable its placement along the exhaust line. The concentration response and temporal performance of a prototype sensor are discussed and characterized with aerosol laboratory test measurements. The sensor performance was also tested with actual engine exhaust in both chassis and engine dynamometer measurements. These measurements demonstrate that the sensor has the potential to meet and even exceed any requirements around the world in terms of on-board diagnostic (OBD) sensitivity and frequency of monitoring.

Particle number emissions from an off-road diesel engine without exhaust after-treatment were studied by using five different heavy-duty lubricating oils in the engine. The study extends understanding on how the properties of lubricating oil affect the nanoparticle emissions from an off-road diesel engine. The lubricants were selected among the performance classes of the European Automobile Manufacturers Association, at least one lubricant from each category intended for heavy-duty diesel engines. Particle size distributions were measured by the means of an engine exhaust particle sizer (EEPS), but soot emissions, gaseous emissions and the basic engine performance were also determined. During the non-road steady state cycle, the most of the differences were detected at the particle size range of 6-15 nm. In most cases, the lowest particle quantities were emitted when the highest performance category lubricant was used.

Since 2011 a particle number (PN) limit was introduced in the European light-duty diesel vehicles legislation. The PN measurement systems consist of i) a hot diluter and an evaporation tube at 300-400°C for the removal of the volatiles (Volatile Particle Remover, VPR) and ii) a particle number counter (PNC) with a 50% cut-point (cut-off) at 23 nm. The PN measurement systems are calibrated and validated annually with monodisperse aerosol: The VPR for the particle concentration reduction factor (PCRF) and the PNC for the linearity and the cut-off size. However, there are concerns that the PN measurement systems can drift significantly over this period of time, raising concerns regarding the validity of the previous measurements, especially if the yearly validation fails.

Recently, a particle number (PN) limit was introduced in the European light-duty vehicles legislation. The legislation requires measurement of PN, and particulate mass (PM), from the full dilution tunnel with constant volume sampling (CVS). Furthermore, PN measurements will be introduced in the next stage of the European Heavy-Duty regulation. Heavy-duty engine certification can be done either from the CVS or from a partial flow dilution system (PFDS). For research and development purposes, though, measurements are often conducted from the raw exhaust, thereby avoiding the high installation costs of CVS and PFDS. Although for legislative measurements requirements exist regarding sampling and transport of the aerosol sample, such requirements do not necessarily apply for raw exhaust measurements. Thus, measurement differences are often observed depending on where in the experimental set up sampling occurs.

Particulate emissions cause adverse health effects and for this reason they are regulated since the 80s. Vehicle regulations cover particulate emission measurements of a model before its sale, known as type approval or homologation. For heavy-duty engines the emissions are measured on an engine dynamometer with steady state points and transient cycles. For light-duty vehicles (i.e. the full power train) the particulate emissions are assessed on a chassis dynamometer. The measurement of particulate emissions is conducted either by diluting the whole exhaust in a dilution tunnel with constant volume sampling or by extracting a small proportional part of the exhaust gas and diluting it. Particulate emissions are measured by passing part of the diluted exhaust aerosol through a filter paper. The increase of the weight of the filter is used to calculate the particulate matter mass (PM) emissions.

The effect of SCR on nanoparticle emissions has been a subject for some recent diesel particle emission related studies. In this study, the effect of after-treatment (DOC and SCR) on particle emissions was studied with a heavy-duty off-road diesel engine (emission level stage 3b with an SCR). A special “transient cold test cycle” (TCTC) was designed to describe the SCR system operation at low exhaust gas temperatures. The particle instrumentation made it possible to measure on-line the particle number concentration, particle size distribution and chemical composition of particles. The largest particle number concentrations were measured after the exhaust manifold. The exhaust after-treatment was observed to reduce the total particle number concentration by 82.5% with the DOC and 95.7% with the DOC+SCR.

The aim of this paper is to analyze the quantitative impact of fuel sulfur content on particulate oxidation catalyst (POC) functionality, focusing on soot emission reduction and the ability to regenerate. Studies were conducted on fuels containing three different levels of sulfur, covering the range of 6 to 340 parts per million, for a light-duty application. The data presented in this paper provide further insights into the specific issues associated with usage of a POC with fuels of higher sulfur content. A 48-hour loading phase was performed for each fuel, during which filter smoke number, temperature and back-pressure were all observed to vary depending on the fuel sulfur level. The Fuel Sulfur Content (FSC) affected also soot particle size distributions (particle number and size) so that with FSC 6 ppm the soot particle concentration was lower than with FSC 65 and 340, both upstream and downstream of the POC.

The Particle Measurement Programme (PMP) developed an exhaust particle number measurement protocol that has been adopted by current light duty vehicle emission regulations in Europe. This includes thermal treatment of the exhaust aerosol to isolate solid particles only and a number counting device with a lower cutpoint of 23 nm to avoid measurement of smaller particles that may affect the repeatability of the measurement. In this paper, we examine a potential alternative to the PMP system, where the thermal treatment is replaced by a catalytic stripper (CS). This offers oxidation and not just evaporation of the volatile components. Alternative sampling systems, either fulfilling the PMP recommendations or utilizing a CS, have been explored in terms of their volatile particle removal efficiency. Tests have been conducted on diesel exhaust, diesel equipped with DPF and gasoline direct injection emissions.

In the current diesel vehicle exhaust emissions legislation Particle Number (PN) limits for solid particles >23 nm are prescribed. The legislation was extended to include Gasoline Direct Injection (G-DI) vehicles since September 2014. Target of this paper was to investigate whether smaller than 23 nm solid particles are emitted from engines in considerable concentration focusing on G-DI engines. The literature survey and the experimental investigation of >15 vehicles showed that engines emit solid sub-23 nm particles. The average percentage over a test cycle for G-DIs (30-40%) is similar to diesel engines. These percentages are relatively low considering the emission limit levels (6×1011 p/km) and the repeatability (10-20%) of the particle number method. These percentages are slightly higher compared to the percentages expected theoretically not to be counted due to the 23 nm cut-off size (5-15%).

In the current heavy-duty engine and light-duty diesel vehicle exhaust emission legislation Particle Number (PN) limits for solid particles >23 nm are prescribed. The legislation was extended to include Gasoline Direct Injection (G-DI) vehicles since September 2014 and will be applied to Non-Road Mobile Machinery engines in the future. However there are concerns transferring the same methodology to other engine technologies, where higher concentration of sub-23 nm particles might exist. This paper focuses on the capabilities of existing PN measurement equipment on measuring solid particles smaller than 23 nm.

The European Emissions Stage 5b standard for diesel passenger cars regulates particulate matter to 0.0045 g/km and non-volatile part/km greater than 23 nm size to 6.0x10₁₁ as determined by the PMP procedure that uses a heated evaporation tube to remove semi-volatile material. Measurement artifacts associated with the evaporation tube technique prevents reliable extension of the method to a lower size range. Catalytic stripper (CS) technology removes possible sources of these artifacts by effectively removing all hydrocarbons and sulfuric acid in the gas phase in order to avoid any chemical reactions or re-nucleation that may cause measurement complications. The performance of a miniature CS was evaluated and experimental results showed solid particle penetration was 50% at 10.5 nm. The sulfate storage capacity integrated into the CS enabled it to chemically remove sulfuric acid vapor rather than rely on dilution to prevent nucleation.

The effect of a novel particle oxidation catalyst (POC®) on diesel particle emissions is studied in heavy duty and light duty applications. Regulated particulate matter (PM) emission measurement is followed by analyzing either soluble organic fraction (SOF) or volatile organic (VOF) fraction. In addition, in heavy duty diesel application, size distributions are measured. Results show that PM reductions as high as 48-79% can be achieved when using POC in combination with a conventional diesel oxidation catalyst (DOC). As expected, the volatile fraction of the PM was very effectively reduced, but also the non-volatile fraction (i.e. soot) was reduced. In tested steady state driving modes soot reduction was found to be 31-55%.

By early 2007, all major manufacturers of light-duty diesel vehicles are marketing models equipped with diesel particulate filters (DPFs). However, there is still a lack of understanding of the particles emitted when the DPF undergoes regeneration. This paper focuses on measuring particle emissions of a representative light-duty diesel vehicle equipped with DPF and employing a fuel-borne catalyst (FBC) to aid regeneration. Particulate Matter (PM) and non-volatile particle number emissions are measured throughout testing according to the Particle Measurement Programme (PMP) proposals. In addition, an Engine Exhaust Particle Sizer (EEPS) connected directly to the CVS is used to give real time size distributions of both volatile and non-volatile particles. The paper focuses on particle emissions during regenerating New European Driving Cycles (NEDCs).

Number concentration of particles emitted by combustion engines has recently attracted attention, due to the fact that particles of the size range found in tail pipe emissions are suspected of being hazardous to human health. This paper describes the application of an Electrical Low Pressure Impactor (ELPI) to the measurement of number concentrations of diesel exhaust particles. The size distribution of particles as fine as 30 nm is determined using the aerodynamic diameter as the characteristic dimension. Results were obtained on both the engine and chassis dynamometer, in real-time, for steady state and transient tests. Swedish Environmental Class 1 diesel fuel was used, having a sulfur content of less than 10 ppm wt. A scheme for the calculation of particle losses in the sampling system was developed, showing high penetration of particles under the conditions examined.