Search Results

In the paper the results of an experimental campaign regarding the steady characterization of a turbocharger waste-gated turbine (IHI-RHF3) for gasoline engine application are presented. The turbine behavior is analyzed in a specialized test rig operating at the University of Genoa, under different openings of the waste-gate valve. The test facility allows to measure inlet and outlet static pressures, mass flow rate and turbocharger rotational speed. The above data constitute the basis for the tuning and validation of a numerical procedure, recently developed at the University of Naples, following a 1D approach (1D turbine model - 1DTM). The model geometrically schematizes the entire turbine based on few linear and angular dimensions directly measured on the hardware. The 1D steady flow equations are then solved within the stationary and rotating channels constituting the device. All the main flow losses are properly taken into account in the model.

Downsizing is widely considered one of the main path to reduce the fuel consumption of spark ignition internal combustion engines. As known, despite the reduced size, the required torque and power targets can be attained thanks to an adequate boost level provided by a turbocharger. However, some drawbacks usually arise when the engine operates at full load and low speeds. In fact, in the above conditions, the boost pressure and the engine performance is limited since the compressor experiences close-to-surge operation. This occurrence is even greater in case of extremely downsized engines with a reduced number of cylinders and a small intake circuit volume, where the compressor works under strongly unsteady flow conditions and its instantaneous operating point most likely overcomes the steady surge margin. In the paper, both experimental and numerical approaches are followed to describe the unsteady behavior of a small in-series turbocharger compressor.

Catalysts that have been extensively investigated for direct soot oxidation in Catalyzed Diesel Particulate Filters (CDPFs) are very often based on mixed oxides of ceria with zirconia, materials known to assist soot oxidation by providing oxygen to the soot through an oxidation-reduction catalytic cycle. Besides the catalyst composition that significantly affects soot oxidation, other parameters such as morphological characteristics of the catalyst largely determined by the synthesis technique followed, as well as the reagents used in the synthesis may also contribute to the activity of the catalysts. In the present work, two ceria-zirconia catalyst samples with different zirconia content were subjected to different milling protocols with the aim to shift the catalyst particle size distribution to lower values. The produced catalysts were then evaluated with respect to their soot oxidation activity following established protocols from previous works.

Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Catalyzed Diesel Particulate Filters (CDPFs) continue to be an important emission control solution and are now also expanding to include additional functionalities such as gas species oxidation (such as CO, hydrocarbons and NO) and even storage phenomena (such as NOx and NH3 storage). Therefore an in depth understanding of the coupled transport - reaction phenomena occurring inside a CDPF wall can provide useful guidance for catalyst placement and improved accuracy over idealized effective medium 1-D and 0-D models for CDPF operation. In the present work a previously developed 3-D simulation framework for porous materials is applied to the case of NO-NO2 turnover in a granular silicon carbide CDPF. The detailed geometry of the CDPF wall is digitally reconstructed and micro-simulation methods are used to obtain detailed descriptions of the concentration and transport of the NO and NO2 species in the reacting environment of the soot cake and the catalyst coated pores of the CDPF wall.

The increasing need for controlled diesel engine emissions and the strict regulations in the abatement of diesel exhaust products lead to an ever increasing use of Diesel Particulate Filters (DPFs) in OEM applications. The periodic regeneration of DPFs (oxidation of soot particles) demands temperatures that rarely appear during engine operation. It is therefore necessary to employ direct or indirect catalytic measures. In the present work, the development and synthesis via aerosol-based routes, of nanostructured base metal oxides for direct soot oxidation, along with their characterization and their evaluation in engine exhaust is described. The synthesized powders were characterized with respect to their phase composition and morphology. XRD, SEM and TEM analysis have shown the nanostructured character of the powders, while Raman spectroscopy was employed for the preliminary characterization of the materials surface chemistry.

Turbocharging technique will play a fundamental role in the near future not only to improve automotive engine performance, but also to reduce fuel consumption and exhaust emissions both in Spark Ignition and diesel automotive applications. To achieve excellent engine performance for road application, it is necessary to overcome some typical turbocharging drawbacks i.e., low end torque level and transient response. Experimental studies, developed on dedicated test facilities, can supply a lot of information to optimize the engine-turbocharger matching, especially if tests can be extended to the typical engine operating conditions (unsteady flow). Different numerical procedures have been developed at the University of Naples to predict automotive turbocharger compressor performance both under steady and unsteady flow conditions. A classical 1D approach, based on the employment of compressor characteristic maps, was firstly followed.

In the last ten years, the number of natural gas vehicles worldwide has grown rapidly with the biggest contribution coming from the Asia-Pacific and Latin America regions. As natural gas is the cleanest fossil fuel, the exhaust emissions from natural gas spark ignition vehicles are lower than those of gasoline powered vehicles. Moreover, natural gas is less affected by price fluctuations and its resources are more evenly widespread over the globe than to oil. However, as natural gas vehicles are usually bi-fuel gasoline and natural gas, the excellent knock resistant characteristics of natural gas cannot be completely exploited. This paper shows the results of an experimental activity performed on a passenger car fuelled alternatively by gasoline and compressed natural gas (CNG). The vehicle has been tested on a chassis dynamometer over standard (NEDC) and real driving cycles (Artemis CADC), allowing to investigate a wide range of operating conditions.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.

An experimental campaign was carried out to evaluate the influence of CNG and gasoline on the exhaust emissions and fuel consumption of a bi-fuel passenger car over on-road tests performed in the city of Naples. The chosen route is very traffic congested during the daytime of experimental measurements. An on-board analyzer was used to measure CO, CO2, NOx tailpipe concentrations and the exhaust flow rate. Throughout a carbon balance on the exhaust pollutants, the fuel consumption was estimated. The exact spatial position was acquired by a GPS which allowed to calculate vehicle speed and the traffic condition was monitored by a video camera. Whole trip realized by the vehicle was subdivided in succession of kinematic sequences and the vehicle emissions and fuel consumption were analyzed and presented as value on each kinematic sequence. Moreover, throughout a multivariate statistical analysis of sequences, the driving cycles characterizing the use of vehicle were identified.

Asymmetric and Variable Cell (AVC) geometry Diesel Particulate Filters (DPF) occupy an increasing portion of the DPFs currently offered by various DPF manufacturers, aiming at providing higher filtration area in the same filter volume to meet demanding emission control applications for passenger cars but also for heavy duty vehicles. In the present work we present an approach for designing and optimizing such DPFs by providing a quantitative description of the flow and deposition of soot in these structures. Soot deposit growth dynamics in AVC DPFs is studied computationally, primary and secondary flows over the inlet channels cross-sectional perimeters are analyzed and their interactions are elucidated. The result is a rational description of the observed growth of soot deposits, as the flow readjusts to transport the soot particles along the path of least resistance (which is not necessarily the shortest geometric path between the inlet and outlet channel, i.e. the wall thickness).

The flow in turbocharger compressors and turbines for automotive engine application is highly unsteady in nature, as it responds to the intake and exhaust manifolds of the internal combustion engine. The optimization of the turbocharger system is therefore a very difficult task, since only steady flow maps are generally provided by turbocharger manufacturer. For several years a specialized components test facility operates at the University of Genoa, particularly suitable to test turbochargers under steady and unsteady flow conditions. The test bench has been continuously upgraded in order to study components under pulsating flow condition by using different layout configurations. A recent set-up makes it possible to study turbocharger compressor under unsteady flow condition by using a rotating valve pulse generator system. Measurements of pressure signals downstream the compressor, instantaneous mass flow rate and turbocharger rotational speed are performed.

Turbocharging is becoming a key technology for automotive spark ignition engines (fed with both liquid and gaseous fuel) as a support to the downsizing concept in order to reduce fuel consumption and exhaust emissions. A waste-gate valve is usually fitted as turbocharger control system in these applications, due to its ability to work at very high exhaust gas temperatures. However, not much information is generally available on turbine behaviour in the opened waste-gate area. This paper presents the results of an experimental study developed on a waste-gated turbocharger for downsized SI automotive engines, performed on the test rig operating at the University of Genoa (Italy), extended both to steady and unsteady flow operation. Mass flow through the by-pass valve and turbine impeller was measured at different waste-gate settings in steady flow conditions.

The results of an extensive investigation developed on the wastegated radial flow turbine of a small automotive turbocharger are presented in this paper. Test rig measurements were performed to point out the influence of the by-pass opening on turbine performance. The analysis was extended both to steady and pulsating flow conditions, and controlled values of the main parameters of generated unsteady flow were obtained by a new dedicated turbine feeding line. A specific test method was followed in order to prevent inaccuracies in the definition of the waste-gate opening. The hypothesis assuming the turbine impeller and the waste-gate as two independent nozzles was studied in steady flow conditions. Turbine measured pulsating performance, which generally resulted higher than steady flow, was compared with the values supplied by analytical predicting models based on the quasi-steady flow assumption.

As different Diesel Particulate Filter (DPF) designs and media are becoming widely adopted, research efforts in the characterization of their influence on particle emissions intensify. In the present work the influence of a Diesel Oxidation Catalyst (DOC) and five different Diesel Particulate Filters (DPFs) under steady state and transient engine operating conditions on the particulate and gaseous emissions of a common-rail diesel engine are studied. An array of particle measuring instrumentation is employed, in which all instruments simultaneously measure from the engine exhaust. Each instrument measures a different characteristic/metric of the diesel particles (mobility size distribution, aerodynamic size distribution, total number, total surface, active surface, etc.) and their combination assists in building a complete characterization of the particle emissions at various measurement locations: engine-out, DOC-out and DPF-out.

It is a big challenge how to satisfy both the purification of exhaust gas and the decrease of fuel penalty, that is, carbon-dioxide emission. Regarding the Diesel Particulate Filter (DPF) applied in the diesel after-treatment system, it must be effective for lowering the fuel penalty to prolong the interval and reduce the frequency of the DPF regeneration operation. This can be achieved by a DPF that has high Particulate Matter (PM) mass limit and high PM oxidation performance that is enough to regenerate the DPF continuously during the normal running operation. In this study, the examination of the pore structure of the wall of a DPF that could expand the continuous regeneration region in the engine operation map was carried out. Several porous materials with a wide range of pore structure were prepared and coated with a Mixed Oxide Catalyst (MOC). The continuous regeneration performance was evaluated under realistic conditions in the exhaust of a diesel engine.

Following the successful market introduction of diesel particulate filters (DPFs), this class of emission control devices is expanding to include additional functionalities such as gas species oxidation (such as CO, HC and NO), storage phenomena (such as NOx and NH3 storage) to the extent that we should today refer not to DPFs but to Multifunctional Reactor Separators. This trend poses many challenges for the modeling of such systems since the complexity of the coupled reaction and transport phenomena makes any direct general numerical approach to require unacceptably high computing times. These multi-functionalities are urgently needed to be incorporated into system level emission control simulation tools in a robust and computationally efficient manner. In the present paper we discuss a new framework and its application for the computationally efficient implementation of such phenomena.

Direct catalytic soot oxidation is expected to become an important component of future diesel particulate emission control systems. The development of advanced Catalytic Diesel Particulate Filters (CDPFs relies on the interplay of chemistry and geometry in order to enhance soot-catalyst proximity. An extensive set of well-controlled experiments has been performed to provide direct catalytic soot oxidation rates in CDPFs employing small-scale side-stream sample exposure. The experiments are analyzed with a state-of-the-art diesel particulate filter simulator and a set of kinetic parameters are derived for direct catalytic soot oxidation by fuel-borne catalysts as well as by catalytic coatings. The influence of soot-catalyst proximity, on catalytic soot oxidation is found to be excellently described by the so-called Two-Layer model, developed previously by the authors.

Novel catalytic coatings with a variety of methods based on conventional and novel synthesis routes are developed for Diesel Particulate Filters (DPFs). The developed catalytic composition exhibits significant direct soot oxidation as evaluated by reacting mixtures of diesel soot and catalyst powders in a thermogravimetric analysis apparatus (TGA). The catalyst composition was further deposited on oxide and non-oxide porous filter structures that were evaluated on an engine bench with respect to their filtration efficiency, pressure drop behavior and direct soot oxidation activity under realistic conditions. The effect of the catalyst amount on the filtration efficiency of non-oxide filters was also investigated. Evaluation of the indirect soot oxidation was conducted on non-oxide catalytic filters coated with precious metal.

A new platform of advanced ceramic composite filter materials for diesel particulate matter and exhaust gas emission control has been developed. These materials exhibit high porosity, narrow pore-size distribution, robust thermo-mechanical strength, and are extruded into high cell density honeycomb structures for wall-flow filter applications. These new high porosity filters provide a structured filtration surface area and a highly connected wall pore space which is fully accessible for multi-phase catalytic reactions. The cross-linked microstructure (CLM™) pore architecture provides a large surface area to host high washcoat/catalyst loadings, such as those required for advanced multi-functional catalysts (4-way converter applications).