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The present paper describes an experimental study on the effect of the compression ratio on the performance of a LD diesel engine operating with a PCCI calibration, near the estimated EURO 6/Tier2 Bin5 NOx emission limits. The research activity is the result of a collaborative project between Istituto Motori and Centro Ricerche Fiat aimed to carry out an exhaustive analysis of the compression ratio (CR) influence on the performance of a LD diesel engine. Starting from a reference engine configuration the CR was reduced in two steps sequentially. Each CR value was characterized under PCCI operation mode and, under conventional diesel operating mode, at maximum torque. The exploration of the PCCI application in the NEDC operating area was performed prefixing limits on maximum fuel consumption, maximum pressure rise and maximum tolerable smoke. The main result was that no significant increment in PCCI application area reducing the CR was possible without overcoming the limits.

The present paper describes an experimental study on the application of a Low Pressure EGR system, equipped with an high efficiency cooler, to a LD diesel engine operating with both conventional combustion and PCCI mode. The research activity is aimed to carry out an analysis of the potentiality of the cooling (with engine water at 90°C) and super-cooling (with external water at 20°C) of the low pressure EGR flow gas on the simultaneous reduction of fuel consumption and pollutant emissions. The effects were evaluated running the engine with diesel conventional combustion and PCCI mode in several engine operating points. The employed engine was a 4-cyliders LD CR diesel engine of two liters of displacement at the state of art of the current engine technology. The overall results identified benefits on both the fuel consumption and emissions with the use of a low pressure EGR system with respect to the “classical” high pressure EGR one.

When increasing EGR from low levels to a level that corresponds to low temperature combustion, soot emissions initially increase due to lower soot oxidation before decreasing to almost zero due to very low soot formation. At the EGR level where soot emissions start to increase, the NOx emissions are low, but not sufficiently low to comply with future emission standards and at the EGR level where low temperature combustion occurs CO and HC emissions are too high. The purpose of this study was to investigate the possibilities for shifting the so-called soot bump (where soot levels are increased) to higher EGR levels, or to reduce the magnitude of the soot bump using very high injection pressures (up to 240 MPa) while reducing the NOx emissions using EGR. The possibility of reducing the CO and HC emissions at high EGR levels due to the increased mixing caused by higher injection pressure was also investigated and the flame was visualized using an endoscope at chosen EGR values.

The present paper describes some results of a research project aimed at studying the impact of alternative fuels blends on the emissions and fuel consumption of an Euro 5 automotive diesel engine. Two alternative fuels were chosen for the experiments: RME and GTL. The tests were done in the three most important operating conditions for the engine emission calibration. Moreover, the NOx-PM trade-off by means of EGR sweep was performed in the same operating conditions, in order to evaluate the engine EGR tolerability when burning low sooting fuels as the RME. The investigations put in evidence that the impact of the alternative fuels on modern diesel engines remains significant. This also depends on the interaction between the alternative fuel characteristics and the engine-management strategies, as described in detail in the paper.

The present paper reassumes the results of an experimental study focused on the effects of the nozzle injector's coking varying the flow number (FN); the performance and emissions of an automotive Euro5 diesel engine have been analyzed using diesel fuel. As the improvement of the diesel engine performance requires a continuous development of the injection system and in particular of the nozzle design, in the last years the general trend among OEMs is lowering nozzle flow number and, as a consequence, nozzle holes size. The study carried out moves from the consideration that a reduction of the nozzle holes diameter could increase the impact of their coking process. For this purpose, an experimental campaign has been realized, testing the engine in steady state in three partial load operating points, representative of the European homologation driving cycle, and in full load conditions.

Studies have shown that premixed combustion concepts such as PCCI and RCCI can achieve high efficiencies while maintaining low NOx and soot emissions. The RCCI (Reactivity Controlled Compression Ignition) concept use blending port-injected high-octane fuel with early direct injected high-cetane fuel to control auto-ignition. This paper describes studies on RCCI combustion using CNG and diesel as the high-octane and high-cetane fuels, respectively. The test was conducted on a heavy-duty single cylinder engine. The influence of injection timing and duration of the diesel injections was examined at 9 bar BMEP and1200 rpm. In addition, experiments were conducted using two different compression ratios, (14 and 17) with different loads and engine speeds. Results show both low NOx and almost zero soot emissions can be achieved but at the expense of increasing of unburned hydrocarbon emissions which could potentially be removed by catalytic after-treatment.

The paper reports an experimental study on the effect of compression ratio variation on the performance and pollutant emissions of a single-cylinder light-duty research diesel engine operating in DF mode. The architecture of the combustion system as well as the injection system represents the state-of-the-art of the automotive diesel technology. Two pistons with different bowl volume were selected for the experimental campaign, corresponding to two CR values: 16.5 and 14.5. The designs of the piston bowls were carefully performed with the 3D simulation in order to maintain the same air flow structure at the piston top dead center, thus keeping the same in-cylinder flow characteristics versus CR. The engine tests choice was performed to be representative of actual working conditions of an automotive light-duty diesel engine.

Catalysts that have been extensively investigated for direct soot oxidation in Catalyzed Diesel Particulate Filters (CDPFs) are very often based on mixed oxides of ceria with zirconia, materials known to assist soot oxidation by providing oxygen to the soot through an oxidation-reduction catalytic cycle. Besides the catalyst composition that significantly affects soot oxidation, other parameters such as morphological characteristics of the catalyst largely determined by the synthesis technique followed, as well as the reagents used in the synthesis may also contribute to the activity of the catalysts. In the present work, two ceria-zirconia catalyst samples with different zirconia content were subjected to different milling protocols with the aim to shift the catalyst particle size distribution to lower values. The produced catalysts were then evaluated with respect to their soot oxidation activity following established protocols from previous works.

The paper describes the challenges and results achieved in developing a new high-speed Diesel combustion system capable of exceeding the imaginative threshold of 100 kW/l. High-performance, state-of-art prototype components from automotive diesel technology were provided in order to set-up a single-cylinder research engine demonstrator. Key design parameters were identified in terms boost, engine speed, fuel injection pressure and injector nozzle flow rates. In this regard, an advanced piezo injection system capable of 3000 bar of maximum injection pressure was selected, coupled to a robust base engine featuring ω-shaped combustion bowl and low swirl intake ports. The matching among the above-described elements has been thoroughly examined and experimentally parameterized.

Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Gas engines (fuelled with CNG, LNG or Biogas) for generation of power and heat are, to this date, taking up larger shares of the market with respect to diesel engines. In order to meet the limit imposed by the TA-Luft regulations on stationary engines, lean combustion represents a viable solution for achieving lower emissions as well as efficiency levels comparable with diesel engines. Leaner mixtures however affect the combustion stability as the flame propagation velocity and consequently heat release rate are slowed down. As a strategy to deliver higher ignition energy, an active pre-chamber may be used. This work focuses on assessing the performance of a pre-chamber combustion configuration in a stationary heavy-duty engine for power generation, operating at different loads, air-to-fuel ratios and spark timings.

Research activities in the development of reliable computational models for aftertreatment systems are constantly increasing in the automotive field. These investigations are essential in order to get a complete understanding of the main catalytic processes which clearly have a great impact on tailpipe emissions. In this work, a 1D chemical reaction model to simulate the catalytic activity of a Pd/Rh Three-Way Catalyst (TWC) for a Natural Gas heavy-duty engine is presented. An extensive database of tests carried out with the use of a Synthetic Gas Bench (SGB) has been collected to investigate the methane abatement pathways, linked to the lambda variation and oxide formation on palladium surface. Specific steady-state tests have shown a dynamics of the methane conversion even at fixed λ and temperature conditions, essentially due to the Pd/PdO ratio.

Gasoline and gasoline-ethanol sprays from an outward-opening piezo-injector were studied in a constant volume/pressure chamber using high-speed imaging and phase doppler anemometry (PDA) under stratified cold start conditions corresponding to a vehicle ambient temperature of 243 K (−30°C/−22°F); in-cylinder air pressure of 5 bar, air temperature of 350 K (−30°C/−22°F) and fuel temperature of 243 K. The effects of varying in-cylinder pressure and temperature, fuel injection pressure and fuel temperature on the formation of gasoline, E75 and pure ethanol sprays were investigated. The results indicate that fuel composition affects spray behaviour, but less than expected. Furthermore, varying the temperature of the fuel or the air surrounding the spray also had minor effects. As expected, the fuel injection pressure was found to have the strongest influence on spray formation under stratified conditions.

Catalyzed Diesel Particulate Filters (CDPFs) continue to be an important emission control solution and are now also expanding to include additional functionalities such as gas species oxidation (such as CO, hydrocarbons and NO) and even storage phenomena (such as NOx and NH3 storage). Therefore an in depth understanding of the coupled transport - reaction phenomena occurring inside a CDPF wall can provide useful guidance for catalyst placement and improved accuracy over idealized effective medium 1-D and 0-D models for CDPF operation. In the present work a previously developed 3-D simulation framework for porous materials is applied to the case of NO-NO2 turnover in a granular silicon carbide CDPF. The detailed geometry of the CDPF wall is digitally reconstructed and micro-simulation methods are used to obtain detailed descriptions of the concentration and transport of the NO and NO2 species in the reacting environment of the soot cake and the catalyst coated pores of the CDPF wall.

The increasing need for controlled diesel engine emissions and the strict regulations in the abatement of diesel exhaust products lead to an ever increasing use of Diesel Particulate Filters (DPFs) in OEM applications. The periodic regeneration of DPFs (oxidation of soot particles) demands temperatures that rarely appear during engine operation. It is therefore necessary to employ direct or indirect catalytic measures. In the present work, the development and synthesis via aerosol-based routes, of nanostructured base metal oxides for direct soot oxidation, along with their characterization and their evaluation in engine exhaust is described. The synthesized powders were characterized with respect to their phase composition and morphology. XRD, SEM and TEM analysis have shown the nanostructured character of the powders, while Raman spectroscopy was employed for the preliminary characterization of the materials surface chemistry.

Future pressures to reduce the fuel consumption of passenger cars may require the exploitation of alternative combustion strategies for gasoline engines to replace, or use in combination with the conventional stoichiometric spark ignition (SSI) strategy. Possible options include homogeneous lean charge spark ignition (HLCSI), stratified charge spark ignition (SCSI) and homogeneous charge compression ignition (HCCI), all of which are intended to reduce pumping and thermal losses. In the work presented here four different combustion strategies were evaluated using the same engine: SSI, HLCSI, SCSI and HCCI. HLCSI was achieved by early injection and operating the engine lean, close to its stability limits. SCSI was achieved using the spray-guided technique with a centrally placed multi-hole injector and spark-plug. HCCI was achieved using a negative valve overlap to trap hot residuals and thus generate auto-ignition temperatures at the end of the compression stroke.

The present work relates to the investigation of the basic oxidation characteristics of iron and aluminium nanoparticles as well as the feasibility of their combustion under both Internal Combustion Engine (ICE)-like and real engine conditions. Based on a series of proof-of-concept experiments, combustion was found to be feasible taking place in a controllable way and bearing similarities to the respective case of conventional fuels. These studies were complimented by relevant in-situ and ex-situ/post-analysis, in order to elaborate the fundamental phenomena occurring during combustion as well as the extent and ‘quality’ of the process. The oxidation mechanisms of the two metallic fuels appear different and -as expected- the energy release during combustion of aluminium is significantly higher than that released in the case of iron.

The diesel particulate filters (DPF) are considered the most robust technologies for particle emission reduction both in terms of mass and number. On the other hand, the increase of the backpressure in the exhaust system due to the accumulation of the particles in the filter walls leads to an increase of the engine fuel consumption and engine power reduction. To limit the filter loading, and the backpressure, a periodical regeneration is needed. Because of the growing interest about particle emission both in terms of mass, number and size, it appears important to monitor the evolution of the particle mass and number concentrations and size distribution during the regeneration of the DPFs. For this matter, in the presented work the regeneration of a catalyzed filter was fully analyzed. Particular attention was dedicated to the dynamic evolution both of the thermodynamic parameters and particle emissions.

The present paper describes the results of a cooperative research project between GM Powertrain Europe and Istituto Motori - CNR aimed at studying the capability of GM Combustion Closed-Loop Control (CLCC) in enabling seamless operation with high biodiesel blending levels in a modern diesel engine for passenger car applications. As a matter of fact, fuelling modern electronically-controlled diesel engines with high blends of biodiesel leads to a performance reduction of about 12-15% at rated power and up to 30% in the low-end torque, while increasing significantly the engine-out NOx emissions. These effects are both due to the interaction of the biodiesel properties with the control logic of the electronic control unit, which is calibrated for diesel operation. However, as the authors previously demonstrated, if engine calibration is re-tuned for biodiesel fuelling, the above mentioned drawbacks can be compensated and the biodiesel environmental inner qualities can be fully deployed.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.