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Electrification of Vehicles at Nissan Motor Company to achieve Zero Tailpipe Emissions

2012-03-29
Nissan Motor Company has recently released the �Nissan Green Program 2016� which is a six-year action plan embodying the company�s environmental philosophy: Symbiosis of People, Vehicles and Nature. One of the key activities of this Program is the successful penetration of Zero-Emission Vehicles into the market which includes electric vehicle (EV) cumulative sales of 1.5M units with our Alliance partner Renault, introduction of a fuel cell electric vehicle (FCEV) into the market, taking a global leadership in supplying batteries for electric drive and creating zero-emission societies. This presentation will highlight some of these key activities. Presenter Kev Adjemian, Nissan Technical Center NA
Video

Development and Demonstration of a Low Emissions Four-Stroke Outboard Marine Engine Utilizing Catalyst Technology

2012-06-18
A conceptual project aimed at understanding the fundamental design considerations concerning the implementation of catalyst systems on outboard marine engines was carried out by Mercury Marine, with the support of the California Air Resources Board. In order to keep a reasonable project scope, only electronic fuel injected four-stroke outboards were considered. While they represent a significant portion of the total number of outboard engines sold in the United States, carbureted four-strokes and direct injected two-strokes pose their own sets of design constraints and were considered to be outside the scope of this study. Recently, three-way catalyst based exhaust emissions aftertreatment systems have been introduced into series production on sterndrive and inboard marine spark ignition engines in North America. The integration of catalyst systems on outboards is much more challenging than on these other marine propulsion alternatives.
Collection

Advances in Catalyst Substrates, 2017

2017-03-28
Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.
Collection

Advances in Catalyst Substrates, 2018

2018-04-03
Papers included in this collection cover the systems engineering experience required to achieve ultra-low emission levels on gasoline light-duty vehicles. Emission system component topics include the development of advanced three-way catalysts, the development of NOX control strategies for gasoline lean burn engines, the application of high cell density substrates to advanced emission systems, and the integration of these components into full vehicle emission systems.
Journal Article

High Power-Density, High Efficiency, Mechanically Assisted, Turbocharged Direct-Injection Jet-Ignition Engines for Unmanned Aerial Vehicles

2019-05-02
Abstract More than a decade ago, we proposed combined use of direct injection (DI) and jet ignition (JI) to produce high efficiency, high power-density, positive-ignition (PI), lean burn stratified, internal combustion engines (ICEs). Adopting this concept, the latest FIA F1 engines, which are electrically assisted, turbocharged, directly injected, jet ignited, gasoline engines and work lean stratified in a highly boosted environment, have delivered peak power fuel conversion efficiencies well above 46%, with specific power densities more than 340 kW/liter. The concept, further evolved, is here presented for unmanned aerial vehicle (UAV) applications. Results of simulations for a new DI JI ICE with rotary valve, being super-turbocharged and having gasoline or methanol as working fuel, show the opportunity to achieve even larger power densities, up to 430 kW/liter, while delivering a near-constant torque and, consequently, a nearly linear power curve over a wide range of speeds.
Journal Article

Keys to Understanding Spray-guided Combustion of a Narrow-spacing Gasoline Direct Injection SI Engine with a Centrally Mounted Multi-hole Injector

2009-04-20
2009-01-1497
Spray-guided gasoline direct injection SI engines attract as one of new generation lean-burn engines to promise CO2 reduction. These typically adopt “narrow-spacing” concept in which an injector is centrally mounted close to a spark plug. Therefore, geometric targets of the fuel spray and a position of the spark plug have to be exactly limited to maintain a proper mixture in the spark gap. In addition, the stable combustion window is narrow because the spark ignition is limited in a short time during and immediately after the injection. These spatial and temporal restrictions involve some intractable problems concerning the combustion robustness due to the complicate phenomena around the spark plug. The local mixture preparation near the spark plug significantly depends on the spray-induced charge motion. The intense flow induced by the motion blows out and stretches the spark, thereby affecting the spark discharge performance.
Journal Article

SCR Catalyst Systems Optimized for Lightoff and Steady-State Performance

2009-04-20
2009-01-0901
A laboratory study was performed to optimize a zoned configuration of an iron (Fe) SCR catalyst and a copper (Cu) SCR catalyst in order to provide high NOx conversion at lean A/F ratios over a broad range of temperature for diesel and lean-burn gasoline applications. With an optimized space velocity of 8,300 hr-1, a 67% (by volume) Fe section followed by a 33% Cu section provided at least 80% NOx conversion from approximately 230°C to 640°C when evaluated with 500 ppm NO and NH3. To improve the lean lightoff performance of the SCR catalyst system during a cold start, a Cu SCR catalyst that was 1/4 as long as the rear Cu SCR catalyst was placed in front of the Fe SCR catalyst. When evaluated with an excess of NH3 (NH3/NO ratio of 2.2), the Cu+Fe+Cu SCR system had significantly improved lightoff performance relative to the Fe+Cu SCR system, although the front Cu SCR catalyst did decrease the NOx conversion at temperatures above 475°C by oxidizing some of the NH3 to N2 or NO.
Journal Article

Treatment of Vehicle Emissions from the Combustion of E85 and Gasoline with Catalyzed Hydrocarbon Traps

2009-04-20
2009-01-1080
Ethanol has been gaining attention as a partial substitute in North American pump gasoline in amounts up to 85% ethanol and 15% gasoline, or what is commonly known as “E85”. The problems with E85 fuel for cold start emissions relative to gasoline fuel are the lower energy density and vapor pressure for combustion. Each contributes to excess E85 fuel injected during cold start for comparable combustion quality and drivability to gasoline. The excess emissions occur before the first three-way catalyst (TWC) converter is warmed-up and active for engine-out exhaust conversion. The treatment of non-methane organic gas (NMOG) emissions from the combustion of E85 and gasoline was evaluated using several different zeolite based hydrocarbon (HC) traps coated with different precious metal loadings and ratios. These catalyzed HC traps were evaluated in a flow reactor and also on a gasoline Partial Zero Emissions Vehicle (PZEV) with experimental flexible fuel capability.
Journal Article

Effects of Methane/Hydrogen Blends On Engine Operation: Experimental And Numerical Investigation of Different Combustion Modes

2010-10-25
2010-01-2165
The introduction of alternative fuels is crucial to limit greenhouse gases. CNG is regarded as one of the most promising clean fuels given its worldwide availability, its low price and its intrinsic properties (high knocking resistance, low carbon content...). One way to optimize dedicated natural gas engines is to improve the CNG slow burning velocity compared to gasoline fuel and allow lean burn combustion mode. Besides optimization of the combustion chamber design, hydrogen addition to CNG is a promising solution to boost the combustion thanks to its fast burning rate, its wide flammability limits and its low quenching gap. This paper presents an investigation of different methane/hydrogen blends between 0% and 40 vol. % hydrogen ratio for three different combustion modes: stoichiometric, lean-burn and stoichiometric with EGR.
Journal Article

A Normally Aspirated Spark Initiated Combustion System Capable of High Load, High Efficiency and Near Zero NOx Emissions in a Modern Vehicle Powertrain

2010-10-25
2010-01-2196
Turbulent Jet Ignition is an advanced spark-initiated pre-chamber combustion system for an otherwise standard spark ignition engine found in current on-road vehicles. This next-generation pre-chamber design simply replaces the spark plug in a conventional spark ignition engine. Turbulent Jet Ignition enables very fast burn rates due to the ignition system producing multiple, widely distributed ignition sites, which consume the main charge rapidly. This high energy ignition system results from the partially combusted (reacting) prechamber products initiating main chamber combustion. The fast burn rates allow for increased levels of dilution (lean burn and/or EGR) when compared to conventional spark ignition combustion, with dilution levels being comparable to other low temperature combustion technologies (HCCI) without the complex control drawbacks.
Journal Article

Controlling Lubricant-Derived Phosphorous Deactivation of the Three-Way Catalysts Part 2: Positive Environmental Impact of Novel ZDP Technology

2010-10-25
2010-01-2257
Prior technical work by various OEMs and lubricant formulators has identified lubricant-derived phosphorus as a key element capable of significantly reducing the efficiency of modern emissions control systems of gasoline-powered vehicles ( 1 , 2 , 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 ). However, measuring the exact magnitude of the detriment is not simple or straightforward exercise due to the many other sources of variation which occur as a vehicle is driven and the catalyst is aged ( 1 ). This paper, the second one in the series of publications, examines quantitative sets of results generated using various vehicle and exhaust catalyst testing methodologies designed to follow the path of lubricant-derived phosphorous transfer from oil sump to exhaust catalytic systems ( 1 ).
Journal Article

Flame Kernel Development for a Spark Initiated Pre-Chamber Combustion System Capable of High Load, High Efficiency and Near Zero NOx Emissions

2010-10-25
2010-01-2260
Turbulent Jet Ignition is an advanced spark-initiated pre-chamber combustion system for an otherwise standard spark ignition engine found in current on-road vehicles. This next-generation pre-chamber design simply replaces the spark plug in a conventional spark ignition engine. Turbulent Jet Ignition enables very fast burn rates due to the ignition system producing multiple, widely distributed ignition sites, which consume the main charge rapidly. This high energy ignition system results from the partially combusted (reacting) pre-chamber products initiating main chamber combustion. The fast burn rates allow for increased levels of dilution (lean burn and/or EGR) when compared to conventional spark ignition combustion, with dilution levels being comparable to other low temperature combustion technologies (HCCI) without the complex control drawbacks.
Journal Article

Proof-of-Principle Investigation into the Use of Custom Rapid Aging Procedures to Evaluate and Demonstrate Catalyst Durability

2010-10-25
2010-01-2269
The application of accelerated catalyst aging procedures on an engine dynamometer test bed for the purpose of demonstrating catalyst durability is examined. A proof-of-principle approach is followed using catalysts from vehicles certified to U.S. Tier 2 Bin 4 and California SULEV 2 levels. Accelerated durability demonstration methods based upon conventional fuel cut cycles were employed to age catalysts to levels predicted by quantification of thermal catalyst bed severity on the Standard Road Cycle (SRC) relative to the fuel cut aging cycle using the Bench Aging Time (BAT) equation. Emissions deterioration on the accelerated aging cycle is compared to the automobile manufacturers' certification values and to whole vehicle emissions performance results from several different in-use vehicle fleets. The influence of technology on whole vehicle emissions levels and deterioration characteristics is also evaluated.
Journal Article

Achieving an 80% GHG Reduction by 2050 in California's Passenger Vehicle Fleet: Implications for the ZEV Regulation

2010-10-19
2010-01-2306
In recognizing the potential for large, damaging impacts from climate change, California enacted Executive Order S-03-05, requiring a reduction in statewide greenhouse gas (GHG) emissions to 80% below 1990 levels by 2050. Given that the transportation light-duty vehicle (LDV) segment accounts for 28% of the state's GHG emissions today, it will be difficult to meet the 2050 goal unless a portfolio of near-zero carbon transportation solutions is pursued. Because it takes decades for a new propulsion system to capture a large fraction of the passenger vehicle market due to vehicle fleet turn-over rates, it is important to accelerate the introduction of these alternatives to ensure markets enter into early commercial volumes (10,000s) between 2015 and 2020. This report summarizes the results and conclusions of a modeling exercise that simulated GHG emissions from the LDV sector to 2050 in California.
Journal Article

Simultaneous Measurements of Aromatic Hydrocarbons in Exhaust using a Laser Ionization Method

2009-11-02
2009-01-2742
A simultaneous multi-composition analyzing (SMCA) resonance enhanced multi-photon ionization (REMPI) system was used to investigate gasoline engine exhaust. Observed peaks for exhaust were smaller mass numbers than those from diesel exhaust. However, large species up to three ring aromatics were observed suggesting that soot precursor forms even in the gasoline engine. At low catalyst temperature condition, the reduction efficiencies of a three-way catalyst were higher for higher mass numbers. This result indicates that the larger species accumulate in the catalyst or elsewhere due to their lower vapor pressures. To evaluate the emission of low volatility species, the accumulation should be taken into account. In the hot mode, reduction efficiencies for aromatic species of three-way catalyst were almost 99.5% however, they fall to 70% in the cold start condition.
Journal Article

Experimental-Numerical Analysis of Nitric Oxide Formation in Partially Stratified Charge (PSC) Natural Gas Engines

2009-11-02
2009-01-2783
Lean burn natural gas engines have high potential in terms of efficiency and NOx emissions in comparison with stoichiometric natural gas engines, and much lower particulate emissions than diesel engines. They are a promising solution to meet the increasingly stringent exhaust emission targets for both light and heavy-duty engines. Partially Stratified-Charge (PSC) is a novel concept which was conceived by prof. Evans (University of British Columbia, Vancouver). This technique allows to further limit pollutant emissions and improve efficiency of an otherwise standard spark-ignition engine fuelled by natural gas, operating with lean air-fuel ratio. The potential of the PSC technique lies in the control of load without throttling by further extending the lean flammability limit.
Journal Article

Review of Diesel Emissions and Control

2010-04-12
2010-01-0301
This review summarizes the latest developments in diesel emissions regarding regulations, engines, NOx (nitrogen oxides) control, particulate matter (PM) reductions, and hydrocarbon (HC) and CO oxidation. Regulations are advancing with proposals for PN (particle number) regulations that require diesel particulate filters (DPFs) for Euro VI in 2013-14, and SULEV (super ultra low emission vehicle) fleet average light-duty (LD) emissions likely to be proposed in California for ~2017. CO₂ regulations will also impact diesel engines and emissions, probably long into the future. Engine technology is addressing these needs. Heavy-duty (HD) research engines show 90% lower NOx at the same PM or fuel consumption levels as a reference 2007 production engine. Work is starting on HD gasoline engines with promising results. In light duty (LD), engine downsizing is progressing and deNOx is emerging as a fuel savings strategy.
Journal Article

High Efficiency, Low Feedgas NOx, and Improved Cold Start Enabled by Low-Temperature Ethanol Reforming

2010-04-12
2010-01-0621
Two major barriers to wider use of ethanol as an engine fuel are ethanol's low heating value per volume relative to gasoline and higher hydrocarbon emissions at startup. Ethanol provides about one-third lower fuel economy than gasoline on a volumetric basis if the two fuels are utilized with equal efficiency, making ethanol less attractive to consumers. In addition, it is difficult to meet emissions standards such as SULEV when using E85 or hydrous ethanol, because ethanol's low volatility and high heat of vaporization compared to gasoline result in incomplete combustion when the engine is cold. A catalyst consisting of a copper-plated nickel sponge has recently been developed that enables ethanol to be reformed at around 300°C to a mixture of hydrogen (H₂), carbon monoxide (CO), and methane (CH₄). This low reforming temperature enables heat to be supplied from the engine exhaust.
Journal Article

Development of Exhaust and Evaporative Emissions Systems for Toyota THS II Plug-in Hybrid Electric Vehicle

2010-04-12
2010-01-0831
Exhaust and evaporative emissions systems have been developed to match the characteristics and usage of the Toyota THS II plug-in hybrid electric vehicle (PHEV). Based on the commercially available Prius, the Toyota PHEV features an additional external charging function, which allows it to be driven as an electric vehicle (EV) in urban areas, and as an hybrid electric vehicle (HEV) in high-speed/high-load and long-distance driving situations. To reduce exhaust emissions, the conventional catalyst warm up control has been enhanced to achieve emissions performance that satisfies California's Super Ultra Low Emissions Vehicle (SULEV) standards in every state of battery charge. In addition, a heat insulating fuel vapor containment system (FVS) has been developed using a plastic fuel tank based on the assumption that such a system can reduce the diffusion of vapor inside the fuel tank and the release of fuel vapor in to the atmosphere to the maximum possible extent.
Journal Article

Development of the Combustion System for a Flexible Fuel Turbocharged Direct Injection Engine

2010-04-12
2010-01-0585
Gasoline turbocharged direct injection (GTDI) engines, such as EcoBoost™ from Ford, are becoming established as a high value technology solution to improve passenger car and light truck fuel economy. Due to their high specific performance and excellent low-speed torque, improved fuel economy can be realized due to downsizing and downspeeding without sacrificing performance and driveability while meeting the most stringent future emissions standards with an inexpensive three-way catalyst. A logical and synergistic extension of the EcoBoost™ strategy is the use of E85 (approximately 85% ethanol and 15% gasoline) for knock mitigation. Direct injection of E85 is very effective in suppressing knock due to ethanol's high heat of vaporization - which increases the charge cooling benefit of direct injection - and inherently high octane rating. As a result, higher boost levels can be achieved while maintaining optimal combustion phasing giving high thermal efficiency.
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