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Ignition delay in diesel engine combustion comprehends both a chemical and a physical amount, the first depending on fuel composition and charge temperature and pressure, the last resulting of time needed for the fuel to atomize, vaporize and mix with air. Control of this parameter, which is mandatory to weight the relative amount of premixed to diffusive stage of the hydrocarbon combustion, is here considered. Experimental measurements of flame intensity spectra obtained by in situ measurements on an optically accessible test device show the presence of peaks corresponding to radicals as OH and CH appearing at the pressure start of combustion. Since OH radicals result from chain branching reactions, a numerical simulation is performed based on a reduced kinetic scheme which allows to measure the branching agent concentration, and whose approximate nature is adequate to the proportion chemical aspects contribute to the overall delay.

Actual emission legislation limits strongly the amount of pollutant in the atmosphere from internal combustion engine. In particular diesel engines widely emit NOx and particulate matter (PM). The last one has principally a carbonaceous nature and presents micronic and submicronic particles extremely dangerous for human health since it could deposit in the lung. In this work, a technique based on broadband ultraviolet (UV) visible scattering and extinction is applied inside a transparent DI CR diesel engine in order to analyze the soot evolution and oxidation. The study is carried out with particular detail for different injection strategies characterized of two and three injections per cycle, Pre+Main and Pre+Main+Post, considering the late combustion before the exhaust stroke. The analysis is performed in terms of size, mass concentration, and chemical and physical nature.

The influence of fuel composition on mixture formation and first stage of combustion, occurring in a small high swirl combustion chamber of an IDI Diesel engine, was analyzed from measurements of spectral extinction and flame emissivity. Measurements were carried out in an optically accessible combustion chamber in which an air swirling flow is forced from the main chamber through a tangential passage. A conventional injection system was used to inject Tetradecane, N-heptane and Diesel fuel. The distribution of liquid and vapor and the interaction of the jet with air swirl were detected by UV-visible extinction measurements. The autoignition phase was characterized by UV-visible chemiluminescence measurements. For all fuels examined, it was observed that initially the liquid fuel penetrates almost linearly with time until reaching a maximum characteristic length, slightly dependent on the fuel.

The characterization of a turbulent diesel spray combustion process has been carried out in a divided chamber diesel system with optical accesses. Laser Doppler Anemometry, spectral extinction and flame intensity measurements have been performed from U.V., to visible from the start of injection to the end of combustion, at fixed air/fuel ratio and different engine speeds. Spatial distribution of fuel and vapor as well as the ignition location and soot distribution have been derived in order to study the mechanism of the air-fuel interaction and the combustion process. The analysis of results has shown that the high swirling motion transports the fuel towards the left part of the chamber and breaks up the jet into small droplets of different sizes and accelerates the fuel vaporization. Then, chemical and physical overlapped phases were observed during the ignition delay, contributing both to autoignition.

Proton Exchange Membrane (PEM) Fuel Cell (FC) presents itself as a promising technology in view of zero-tailpipe emission vehicles. In addition, the constant development of renewable energy sources will lead to an increase in green hydrogen availability, and thus completely eliminate emissions for devices that use H2 as an energy vector. However, PEM FCs are still far from being fully developed as a technology: thermal and water management are the main issues that researchers are studying through experiments and Computational Fluid Dynamics (CFD) simulations. For the numerical approach, H2O removal models often consider a simplified flat surface, but the microgeometry of the Gas Diffusion Layer (GDL) has a leading role in determining the critical dimension for droplet detachment and how much resistance the surface poses to water sliding. The aim of this paper is to investigate the influence of droplets number on a GDL.