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Effects of fuel cell material properties on water management were numerically investigated using Volume of Fluid (VOF) method in the FLUENT. The results show that the channel surface wettability is an important design variable for both serpentine and interdigitated flow channel configurations. In a serpentine air flow channel, hydrophilic surfaces could benefit the reactant transport to reaction sites by facilitating water transport along channel edges or on channel surfaces; however, the hydrophilic surfaces would also introduce significantly pressure drop as a penalty. For interdigitated air flow channel design, it is observable that liquid water exists only in the outlet channel; it is also observable that water distribution inside GDL is uneven due to the pressure distribution caused by interdigitated structure. An in-situ water measurement method, neutron imaging technique, was used to investigate the water behavior in a PEM fuel cell.

A zero-dimensional code is developed to simulate turbulent spray combustion and NOx and soot emission in direct injection diesel engines. The code consists of two major parts; mixing calculation for the probability density function (PDF) based on the multi-zone model by Hiroyasu et al., (1983) and the flame structure by the conditional moment closure (CMC) model (Klimenko & Bilger, 1999). The skeletal mechanism of n-heptane is employed with the elementary reaction steps for heat release and the NOx chemistry in GRI 3.0. The spray model accounts for evaporation and mixing based on momentum balance of the spray zones, while the CMC model incorporates the conditional flame structures with one fuel group or flame structure for each injection. The spatially integrated density-weighted PDF, F(η), is defined to represent inhomogeneous mixture distribution in the cylinder. The one-equation soot model is employed for prediction of the soot emission.

An experimental study was carried out to characterize the exhaust flow structure inside the closed-coupled catalytic converter, which is installed on a firing four-cylinder 12-valve passenger car gasoline engine. Simultaneous velocity and pressure measurements were taken using cycle-resolved Laser Doppler anemometer (LDA) technique and pressure transducer. A small fraction of titanium (IV) iso-propoxide was dissolved in gasoline to generate titanium dioxide during combustion as seeding particles for the LDA measurements. It was found that the velocity is highly fluctuating due to the pulsating nature of the engine exhaust flow, which strongly depends on the engine operating conditions and the measuring locations. The pressure oscillation is correlated with the transient exhaust flow characteristics. The main exhaust flow event from each cylinder can only be observed at the certain region in front of the monolith brick.

For the application of advanced clean combustion technologies, such as diesel HCCI/LTC, a compressor with high efficiency over a broad operation range is required to supply a high amount of EGR with minimum pumping loss. A compressor with high pitch of vaneless diffuser would substantially improve the flow range of the compressor, but it is at the cost of compressor efficiency, especially at low mass flow area where most of the city driving cycles resides. In present study, an ultra low solidity compressor vane diffuser was numerically investigated. It is well known that the flow leaving the impeller is highly distorted, unsteady and turbulent, especially at relative low mass flow rate and near the shroud side of the compressor. A conventional vaned diffuser with high stagger angle could help to improve the performance of the compressor at low end. However, adding diffuser vane to a compressor typically restricts the flow range at high end.

This study presents an extended Conditional Moment Closure (CMC) model [1] for turbulent spray combustion of a diesel engine. A spatially integrated CMC equation involves multiple flame structures, evaporation source terms for mixture fraction variance and scaled conditional scalar dissipation rates (CSDR) and probability density functions (PDF). An independent transport equation is solved for each flame group with equal mass of sequentially injected and evaporated fuel group. The implementation strategy in KIVA is to determine mean scalar variables instead of mean reaction rates in terms of conditional flame structures and local PDF's. Simulation is performed to test the suggested CMC model for a heavy duty diesel engine with early injection timings. NOx chemistry [2] is combined with skeletal chemistry of n-heptane [3] while soot is modeled by both one equation model [4] and two equation model [5].

The current study focused on the effects B20 fuel (20% soybean-based biodiesel) and SCR entrance shapes on a light-duty, high-speed, 2.8L common-rail 4-cylinder diesel engine, at different exhaust temperatures. The results indicate that B20 has less deNOX efficiency at low temperature than ULSD, and that N₂O emission need to be characterized as well as NH₃ slip. If a mixer and enough mixing length are used, longer divergence section does not improve the deNOX efficiency significantly under the speed ranges tested.

Experimental data is used in conjunction with multi-dimensional modeling in a modified version of the KIVA-3V code to characterize the emissions behavior of a high-speed, direct-injection diesel engine. Injection pressure and EGR are varied across a range of typical small-bore diesel operating conditions and the resulting soot-NOx tradeoff is analyzed. Good agreement is obtained between experimental and modeling trends; the HSDI engine shows increasing soot and decreasing NOx with higher EGR and lower injection pressure. The model also indicates that most of the NOx is formed in the region where the bulk of the initial heat release first takes place, both for zero and high EGR cases. The mechanism of NOx reduction with high EGR is shown to be primarily through a decrease in thermal NOx formation rate.

The emissions trade-off and combustion characteristics of a high speed, small-bore, direct injection, single cylinder, diesel engine are investigated at three different load conditions. The experiments covered a wide range of parameters including the injection pressure, exhaust gas recirculation (EGR) rate and swirl ratio (Sw). The effects of each parameter on the ignition delay (ID), apparent rate of energy release (ARER), NOx, Bosch smoke unit (BSU), CO and hydrocarbons are investigated. The results show that the NOx emission dropped continuously with the increase in EGR (up to 55%), but with increasing smoke emission in a classical trade-off relationship. The increase in injection pressure generally reduced smoke with NOx penalty; however, the NOx penalty decreased at higher EGR. There also appears to be an increase in the cool flame intensity at the high EGR rates. Applying swirl at high EGR rate and high injection pressure conditions further reduced smoke emissions.

A numerical simulation of shock wave generation by high-pressure and high-speed spray jet has been conducted to compare to the experimental results obtained by X-ray radiographic technique. Using the space-time conservation element solution element (CESE) method and the stochastic particle techniques to account for fuel injections and droplet collisions, supersonic-spray-induced shock waves are successfully simulated. Similar to the experimental condition, a non-evaporating diesel spray in a chamber filled with inert gas sulfur hexafluoride (SF6) at 1 atm pressure under room temperature (30° C) is simulated. To simulate the needle lift effect in the single-hole diesel injector, various injection-rate profiles were employed. In addition, the effects of discharge coefficients, with Cd ranging from 0.8 to 1.0, were also considered to simulate the shock generation processes in the leading spray front.

Analysis of flow field and charge distribution in a gasoline direct-injection (GDI) engine is performed by a modified version of the KIVA code. A particle-based spray model is proposed to simulate a swirl-type hollow-cone spray in a GDI engine. Spray droplets are assumed to be fully atomized and introduced at the sheet breakup locations as determined by experimental correlations and energy conservation. The effects of the fuel injection parameters such as spray cone angle and ambient pressure are examined for different injectors and injection conditions. Results show reasonable agreement with the measurements for penetration, dispersion, global shape, droplet velocity and size distribution by Phase Doppler Particle Anemometry(PDPA) in a constant-volume chamber. The test engine is a 4-stroke 4-valve optically accessible single-cylinder engine with a pent-roof head and tumble ports.

The performance of the Common Rail diesel injection system (CRS) is investigated experimentally in a single cylinder engine and a test rig to determine the cycle-to-cycle variation in the injection pressure and its effects on the needle opening and rate of fuel delivery. The engine used is a single cylinder, simulated-turbocharged diesel engine. Data for the different injection and performance parameters are collected under steady state conditions for 35 consecutive cycles. Furthermore, a mathematical model has been developed to calculate the instantaneous fuel delivery rate at various injection pressures. The experimental results supported with the model computations indicated the presence of cycle-to-cycle variations in the fuel injection pressure and needle lift. The variations in the peak-cylinder gas pressure, rate of heat release, cylinder gas temperature and IMEP are correlated with the variation in the injection rate.

A low temperature combustion (LTC) diesel engine has been under investigation for reduction of NOx and soot with acceptable compromise in the efficiency through modification of the combustion process. In this paper computational simulation is performed as a preliminary step for development of an LTC diesel engine for off-highway construction vehicles. Validation is performed for major physical models against measurements in LTC conditions. The conditional moment closure (CMC) is employed to address coupling between chemistry and turbulence in KIVA-CMC. The Kelvin-Helmholtz/Rayleigh-Taylor (KH-RT) model is employed for spray breakup and a skeletal n-heptane mechanism for both low and high temperature chemistry. Parametric evaluation is performed for design and operating conditions including EGR rate and injection timing. Results are obtained for efficiency, IMEP, CO, NOx and PM emissions at intake boost pressures of 1, 2 and 3 bar.

Requirements for reduced fuel consumption with simultaneous reductions in regulated emissions require more efficient operation of Spark Ignited (SI) engines. An advanced valvetrain coupled with Gasoline Direct injection (GDi) provide an opportunity to simultaneously reduce fuel consumption and emissions. Work on a flex fuel GDi engine has identified significant potential to reduce throttling by using Early Intake Valve Closing (EIVC) and Late Intake Valve Closing (LIVC) strategies to control knock and load. High loads were problematic when operating on gasoline for particulate emissions, and low loads were not able to fully minimize throttling due to poor charge motion for the EIVC strategy. The use of valve deactivation was successful at reducing high load particulate emissions without a significant airflow penalty below 3000 RPM. Valve deactivation did increase the knocking tendency for knock limited fuels, due to increased heat transfer that increased charge temperature.

Computation is performed to predict number density, volume fraction and size distribution of soot particles in typical operating conditions of a diesel engine. KIVA has been integrated with the CMC routine to consider turbulence/chemistry coupling and gas phase kinetics for heat release and soot precursors. The compositions of soot precursors are estimated by tracking Lagrangian particles to consider spatial inhomogeneity and differential diffusion in KIVA. The soot simulator SWEEP is employed as a postprocessing step to calculate conditional and integral quantities of soot particles. There are larger particles produced at a higher load or a lower rpm, but no consistent trend for injection timing in the conditional size distribution at the mixture fraction of 0.12. The integral results are obtained for number density, total mass and size distribution by summing up the histories of all tracked particles in the cylinder.

Low temperature combustion (LTC) may allow simultaneous reduction of nitrogen oxides (NOx) and soot with acceptable compromise in the efficiency of a diesel engine. Recently oxygenate biodiesel fuels were tested to resolve the problem of CO emission at higher exhaust gas recirculation (EGR) rates in LTC operation. In this paper 3-D simulation is performed by KIVA with soybean biodiesel blends of D100 and BD20 for a heavy duty test engine. The oxygen fraction in intake gas is controlled between 7% and 19% to simulate EGR in LTC operation. A surrogate mechanism is constructed by combining the skeletal mechanisms of methyl butanoate (MB) and n-heptane for low and high temperature chemistry. It consists of 76 species and 243 reaction steps with detailed NOx chemistry. The conditional moment closure (CMC) model is employed to address coupling between turbulence and chemistry.

Gasoline-direct-injection (GDI) engines have been adopted increasingly by the automotive industry in the recent years due to their performance, effects on the environment, and customers' demand on advanced technology. However, the knowledge of detailed combustion process in such engines is still not thoroughly analyzed and understood. With optically accessible engines (OAE) and advanced measuring techniques, such as high-speed digital imaging, the in-cylinder combustion process is made available directly to researchers. The present study primarily focuses on the effects of different parameters of engine control on the combustion process, such as fuel types, valve deactivation, ignition timing, spark energy, injection timing, air-fuel ratio, and exhaust gas recirculation. Three engine heads of a 2.0L GDI engine are used with modification to acquire different optical access.

Integrated control strategies for the O.P.E.R.A.S. (Optimization of injection Pressure, EGR ratio, injection Retard or Advance and Swirl ratio) are demonstrated. The strategies are based on an investigation of combustion and emissions in a small bore, high speed, direct injection diesel engine. The engine is equipped with a common rail injection system and is tested under simulated turbocharged engine conditions at two loads and speeds that represent two key operating points in a medium size HEV vehicle. A new phenomenological model is developed for the fuel distribution in the combustion chamber and the fractions that are injected prior to the development of the flame, injected in the flame or deposited on the walls. The investigation covered the effect of the different operating parameters on the fuel distribution, combustion and engine-out emissions.

Port fuel injection system in gasoline engines is receiving an increasing attention for its potential advantages in meeting the constrains of simultaneous reduction in fuel consumption and exhaust emission, and maintaining a good engine performance. The structure of port injector spray dominates the mixture preparation process and strongly affect the subsequent engine combustion characteristics over a wide range of operating conditions in port-injection gasoline engines. In this paper, an experimental and analytical study is made to characterize the breakup mechanism and atomization process of the non-air-assisted port injector sprays in gasoline engines. The liquid sprays resulted from various types of current and development-type automotive fuel injectors were visualized using planar laser-induced fluorescence imaging technique. A comparison was made on the spray structure of the single hole and multi-hole injectors.

A global characterization of the spray distribution of various current and development types of automotive fuel injectors was obtained. Axial and radial measurement of droplet sizes, velocities and volume fluxes were made with a phase Doppler particle analyzer (PDPA) for a transient port injector spray in quiescent atmospheric conditions. Time-resolved measurements involving the time-of-arrival of each droplet associated with its size and velocity components were also acquired. Additionally, the liquid sprays emanating from various types of port fuel injectors were visualized, through planar laser induced fluorescence (PLIF) technique, at different time instants. Such detailed study provides an improved understanding of the temporal or unsteady behavior of port injector spray.

The flow structure inside the catalytic converter of gasoline engines is very important for consideration of the catalyst light-off condition, converter durability and conversion efficiency. However, the available experimental data under actual engine exhaust conditions are quite limited due to its complicated configuration, critical operating conditions and difficult optical access. Therefore, an experimental study was performed, using laser Doppler velocimetry technique, to measure the velocity distributions inside two production dual-monolith catalytic converters fitted on a firing gasoline engine over several engine operating conditions. This paper reports the normal velocity characteristics measured in a plane 1 mm away from the front surface of first monolith. A small fraction of titanium (IV) isopropoxide was dissolved in gasoline for generating titanium dioxide seeding particles during the engine combustion.