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When increasing EGR from low levels to a level that corresponds to low temperature combustion, soot emissions initially increase due to lower soot oxidation before decreasing to almost zero due to very low soot formation. At the EGR level where soot emissions start to increase, the NOx emissions are low, but not sufficiently low to comply with future emission standards and at the EGR level where low temperature combustion occurs CO and HC emissions are too high. The purpose of this study was to investigate the possibilities for shifting the so-called soot bump (where soot levels are increased) to higher EGR levels, or to reduce the magnitude of the soot bump using very high injection pressures (up to 240 MPa) while reducing the NOx emissions using EGR. The possibility of reducing the CO and HC emissions at high EGR levels due to the increased mixing caused by higher injection pressure was also investigated and the flame was visualized using an endoscope at chosen EGR values.

Studies have shown that premixed combustion concepts such as PCCI and RCCI can achieve high efficiencies while maintaining low NOx and soot emissions. The RCCI (Reactivity Controlled Compression Ignition) concept use blending port-injected high-octane fuel with early direct injected high-cetane fuel to control auto-ignition. This paper describes studies on RCCI combustion using CNG and diesel as the high-octane and high-cetane fuels, respectively. The test was conducted on a heavy-duty single cylinder engine. The influence of injection timing and duration of the diesel injections was examined at 9 bar BMEP and1200 rpm. In addition, experiments were conducted using two different compression ratios, (14 and 17) with different loads and engine speeds. Results show both low NOx and almost zero soot emissions can be achieved but at the expense of increasing of unburned hydrocarbon emissions which could potentially be removed by catalytic after-treatment.

Catalysts that have been extensively investigated for direct soot oxidation in Catalyzed Diesel Particulate Filters (CDPFs) are very often based on mixed oxides of ceria with zirconia, materials known to assist soot oxidation by providing oxygen to the soot through an oxidation-reduction catalytic cycle. Besides the catalyst composition that significantly affects soot oxidation, other parameters such as morphological characteristics of the catalyst largely determined by the synthesis technique followed, as well as the reagents used in the synthesis may also contribute to the activity of the catalysts. In the present work, two ceria-zirconia catalyst samples with different zirconia content were subjected to different milling protocols with the aim to shift the catalyst particle size distribution to lower values. The produced catalysts were then evaluated with respect to their soot oxidation activity following established protocols from previous works.

Evolving marine diesel emission regulations drive significant reductions of nitrogen oxide (NOx) emissions. There is, therefore, considerable interest to develop and validate Selective Catalytic Reduction (SCR) converters for marine diesel NOx emission control. Substrates in marine applications need to be robust to survive the high sulfur content of marine fuels and must offer cost and pressure drop benefits. In principle, extruded honeycomb substrates of higher cell density offer benefits on system volume and provide increased catalyst area (in direct trade-off with increased pressure drop). However higher cell densities may become more easily plugged by deposition of soot and/or sulfate particulates, on the inlet face of the monolithic converter, as well as on the channel walls and catalyst coating, eventually leading to unacceptable flow restriction or suppression of catalytic function.

Gasoline and gasoline-ethanol sprays from an outward-opening piezo-injector were studied in a constant volume/pressure chamber using high-speed imaging and phase doppler anemometry (PDA) under stratified cold start conditions corresponding to a vehicle ambient temperature of 243 K (−30°C/−22°F); in-cylinder air pressure of 5 bar, air temperature of 350 K (−30°C/−22°F) and fuel temperature of 243 K. The effects of varying in-cylinder pressure and temperature, fuel injection pressure and fuel temperature on the formation of gasoline, E75 and pure ethanol sprays were investigated. The results indicate that fuel composition affects spray behaviour, but less than expected. Furthermore, varying the temperature of the fuel or the air surrounding the spray also had minor effects. As expected, the fuel injection pressure was found to have the strongest influence on spray formation under stratified conditions.

Catalyzed Diesel Particulate Filters (CDPFs) continue to be an important emission control solution and are now also expanding to include additional functionalities such as gas species oxidation (such as CO, hydrocarbons and NO) and even storage phenomena (such as NOx and NH3 storage). Therefore an in depth understanding of the coupled transport - reaction phenomena occurring inside a CDPF wall can provide useful guidance for catalyst placement and improved accuracy over idealized effective medium 1-D and 0-D models for CDPF operation. In the present work a previously developed 3-D simulation framework for porous materials is applied to the case of NO-NO2 turnover in a granular silicon carbide CDPF. The detailed geometry of the CDPF wall is digitally reconstructed and micro-simulation methods are used to obtain detailed descriptions of the concentration and transport of the NO and NO2 species in the reacting environment of the soot cake and the catalyst coated pores of the CDPF wall.

The increasing need for controlled diesel engine emissions and the strict regulations in the abatement of diesel exhaust products lead to an ever increasing use of Diesel Particulate Filters (DPFs) in OEM applications. The periodic regeneration of DPFs (oxidation of soot particles) demands temperatures that rarely appear during engine operation. It is therefore necessary to employ direct or indirect catalytic measures. In the present work, the development and synthesis via aerosol-based routes, of nanostructured base metal oxides for direct soot oxidation, along with their characterization and their evaluation in engine exhaust is described. The synthesized powders were characterized with respect to their phase composition and morphology. XRD, SEM and TEM analysis have shown the nanostructured character of the powders, while Raman spectroscopy was employed for the preliminary characterization of the materials surface chemistry.

Future pressures to reduce the fuel consumption of passenger cars may require the exploitation of alternative combustion strategies for gasoline engines to replace, or use in combination with the conventional stoichiometric spark ignition (SSI) strategy. Possible options include homogeneous lean charge spark ignition (HLCSI), stratified charge spark ignition (SCSI) and homogeneous charge compression ignition (HCCI), all of which are intended to reduce pumping and thermal losses. In the work presented here four different combustion strategies were evaluated using the same engine: SSI, HLCSI, SCSI and HCCI. HLCSI was achieved by early injection and operating the engine lean, close to its stability limits. SCSI was achieved using the spray-guided technique with a centrally placed multi-hole injector and spark-plug. HCCI was achieved using a negative valve overlap to trap hot residuals and thus generate auto-ignition temperatures at the end of the compression stroke.

In this paper, a methodology is presented to study the influence of thermal aging on catalytic DPF performance using small scale coated filter samples and side-stream reactor technology. Different mixed oxide catalytic coating families are examined under realistic engine exhaust conditions and under fresh and thermally aged state. This methodology involves the determination of filter physical (flow resistance under clean and soot loaded conditions and filtration efficiency) and chemical properties (reactivity of catalytic coating towards direct soot oxidation). Thermal aging led to sintering of catalytic nanoparticles and to changes in the structure of the catalytic layer affecting negatively the filter wall permeability, the clean filtration efficiency and the pressure drop behavior during soot loading. It also affected negatively the catalytic soot oxidation activity of the catalyzed samples.

The development of high efficiency powertrains is a key objective for car manufacturers. One approach for improving the efficiency of gasoline engines is based on homogeneous charge compression ignition, HCCI, which provides higher efficiency than conventional strategies. However, HCCI is only currently viable at relatively low loads, primarily because at high loads it involves rapid combustion that generates pressure oscillations in the cylinder (ringing), and partly because it gives rise to relatively high NOX emissions. This paper describes studies aimed at increasing the viability of HCCI combustion at higher loads by using fully flexible valve trains, direct injection with charge stratification (SCCI), and intake air boosting. These approaches were complemented by using EGR to control NOX emissions by stoichiometric operation, which enables the use of a three-way catalyst.

During 1991 Volvo Car Corporation has introduced the new Volvo 850 GLT model featuring front wheel drive with transverse installation of the engine and gearbox. The powertrain; consists of a new in-line five-cylinder engine in combination with a four speed electronically controlled automatic gearbox or a five speed manual gearbox. The engine features DOHC 20 valves, V-VIS (Volvo Variable Induction System), well tuned exhaust system and microprocessor controlled engine management systems. The engine was designed and developed as a new member of Volvo's modular engine family. The first member was the in-line six-cylinder engine B6304F [1] introduced in 1990. The modular engines have a large number of identical components and the major components are machined in common transfer lines which makes the manufacturing process highly rational and cost-effective.

In order to investigate the effects of split injection on emission formation and engine performance, experiments were carried out using a heavy duty single cylinder diesel engine. Split injections with varied dwell time and start of injection were investigated and compared with single injection cases. In order to isolate the effect of the selected parameters, other variables were kept constant. In this investigation no EGR was used. The engine was equipped with a common rail injection system with a piezo-electric injector. To interpret the observed phenomena, engine CFD simulations using the KIVA-3V code were also made. The results show that reductions in NOx emissions and brake specific fuel consumption were achieved for short dwell times whereas they both were increased when the dwell time was prolonged. No EGR was used so the soot levels were already very low in the cases of single injections.

Asymmetric and Variable Cell (AVC) geometry Diesel Particulate Filters (DPF) occupy an increasing portion of the DPFs currently offered by various DPF manufacturers, aiming at providing higher filtration area in the same filter volume to meet demanding emission control applications for passenger cars but also for heavy duty vehicles. In the present work we present an approach for designing and optimizing such DPFs by providing a quantitative description of the flow and deposition of soot in these structures. Soot deposit growth dynamics in AVC DPFs is studied computationally, primary and secondary flows over the inlet channels cross-sectional perimeters are analyzed and their interactions are elucidated. The result is a rational description of the observed growth of soot deposits, as the flow readjusts to transport the soot particles along the path of least resistance (which is not necessarily the shortest geometric path between the inlet and outlet channel, i.e. the wall thickness).

Eight different cylinder pressure trace based knock detection methods are compared using two reference cycles of different time-frequency content, reflecting single blast and developing blast, and a test population of 300 knocking cycles. It is shown that the choice of the pass window used for the pressure data has no significant effect on the results of the different methods, except for the KI20. In contrast to other authors, no sudden step in the knock characteristics is expected; first, because the data investigated contain only knocking cycles, and second, because a smooth transition between normal combustion and knock is expected, according to recent knock theory. It is not only the correlation coefficient, but also the Kendall coefficient of concordance, that is used to investigate the differences between the knock classification methods.

Combustion characteristics of dimethyl ether, DME, have been investigated experimentally, in a heavy duty single cylinder engine equipped with an adapted common rail fuel injection system, and the effects of varying injection timing, rail pressure and exhaust gas recirculation on the combustion and emission parameters. The results show that DME combustion does not produce soot and with the use of exhaust gas recirculation NOX emissions can also be reduced to very low levels. However, high injection pressure and/or a DME adopted combustion system is required to improve the mixing process and thus reduce the combustion duration and carbon monoxide emissions.

The effects of using an SI stratified charge in combination with HCCI combustion on combustion phasing, rate of heat release and emissions were investigated in engine experiments to identify ways to extend the operational range of HCCI combustion to lower loads. In the experiments an optical single-cylinder engine equipped with a piezo electric outward-opening injector and operated with negative valve overlap (NVO) and low lift, short duration, camshaft profiles, was used to initiate HCCI combustion by increasing the exhaust gas recirculation (EGR) and thus retaining sufficient thermal energy to reach auto-ignition temperatures. Two series of experiments with full factorial designs were performed, to investigate how the tested parameters (amounts of fuel injected in pilot injections and main injections, stratification injection timing and spark-assistance) influenced the combustion.

Experiments were performed using a Light-Duty, single-cylinder, research engine in which the emissions, fuel consumption and combustion characteristics of two Fischer-Tropsch (F-T) Diesel fuels derived from natural gas and two conventional Diesel fuels (Swedish low sulfur Diesel and European EN 590 Diesel) were compared. Due to their low aromatic contents combustion with the F-T Diesel fuels resulted in lower soot emissions than combustion with the conventional Diesel fuels. The hydrocarbon emissions were also significantly lower with F-T fuel combustion. Moreover the F-T fuels tended to yield lower CO emissions than the conventional Diesel fuels. The low emissions from the F-T Diesel fuels, and the potential for producing such fuels from biomass, are powerful reason for future interest and research in this field.

This work evaluates the effect of charge stratification on combustion phasing, rate of heat release and emissions for HCCI combustion. Engine experiments in both optical and traditional single cylinder engines were carried out with PRF50 as fuel. The amount of stratification as well as injection timing of the stratified charge was varied. It was found that a stratified charge can influence combustion phasing, increasing the stratification amount or late injection timing of the stratified charge leads to an advanced CA50 timing. The NOx emissions follows the CA50 advancement, advanced CA50 timing leads to higher NOx emissions. Correlation between CA50 can also be seen for HC and CO emissions when the injection timing was varied, late injection and thereby advanced CA50 timing leads to both lower HC and CO emissions.

As different Diesel Particulate Filter (DPF) designs and media are becoming widely adopted, research efforts in the characterization of their influence on particle emissions intensify. In the present work the influence of a Diesel Oxidation Catalyst (DOC) and five different Diesel Particulate Filters (DPFs) under steady state and transient engine operating conditions on the particulate and gaseous emissions of a common-rail diesel engine are studied. An array of particle measuring instrumentation is employed, in which all instruments simultaneously measure from the engine exhaust. Each instrument measures a different characteristic/metric of the diesel particles (mobility size distribution, aerodynamic size distribution, total number, total surface, active surface, etc.) and their combination assists in building a complete characterization of the particle emissions at various measurement locations: engine-out, DOC-out and DPF-out.

It is a big challenge how to satisfy both the purification of exhaust gas and the decrease of fuel penalty, that is, carbon-dioxide emission. Regarding the Diesel Particulate Filter (DPF) applied in the diesel after-treatment system, it must be effective for lowering the fuel penalty to prolong the interval and reduce the frequency of the DPF regeneration operation. This can be achieved by a DPF that has high Particulate Matter (PM) mass limit and high PM oxidation performance that is enough to regenerate the DPF continuously during the normal running operation. In this study, the examination of the pore structure of the wall of a DPF that could expand the continuous regeneration region in the engine operation map was carried out. Several porous materials with a wide range of pore structure were prepared and coated with a Mixed Oxide Catalyst (MOC). The continuous regeneration performance was evaluated under realistic conditions in the exhaust of a diesel engine.