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Ethanol for use in automotive fuels can be made from renewable feedstocks, which contributes to its increased use in recent years. There are many differences in physical and chemical properties between ethanol and petrochemicals refined from fossil oil. One of the differences is its energy content. The energy content, or heating value, is an important property of motor fuel, since it directly affects vehicle fuel economy. While the energy content can be measured by combustion of the fuel in a bomb, the test is time-consuming and expensive. It is generally satisfactory and more convenient to estimate that property from other commonly-measured fuel properties. Several standardized empirical methods have been developed in the past for estimating the energy content of hydrocarbon fuels such as gasoline, diesel fuel, and jet fuel.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries and to buffer the potential organic acids present in an ethanol blended fuel to enhance storage stability. The impact of these inhibitors on spark-ignition engine fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the corrosion inhibitors to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a second market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel, specifically E85 (Ethanol Fuel Blends); and, to show how the variation in the concentrations of the components of the CIs impacts the operation and performance of vehicles, specifically, the effects on intake valve deposit formation.

Carbon, hydrogen and oxygen are major elements in modern fuels. Varying combinations of these elements in motor fuel alter the stoichiometric air-fuel ratio (A/F). Stoichiometric A/F ratio is an important parameter in engine calibration affecting vehicle performance, emissions and fuel economy. With increasing use of ethanol in automotive fuels in recent years, since it can be made from renewable feedstocks, oxygen contents in fuel are increasing. Oxygen contents can be around 1.7 mass % in European E5 gasoline or 3.5 mass % in U.S. E10 gasoline and up to 29 mass % in E85 fuel. The increase in oxygen content of fuel has resulted in changes in other physical and chemical properties due to the differences between ethanol and hydrocarbons refined from fossil oil. A previous paper (SAE 2010-01-1517) discussed the change in energy content of automotive fuel and the estimation of net heating values from common fuel properties.

Dimethyl Ether (DME) is a potential ultra-clean diesel fuel. Its unique characteristics require special handling and accommodation of its low viscosity and low lubricity. In this project, DME was blended with diesel fuel to provide sufficient viscosity and lubricity to permit operation of a 7.3 liter turbodiesel engine in a campus shuttle bus with minimal modification of the fuel injection system. A pressurized fuel delivery system was added to the existing common rail injection system on the engine, allowing the DME-diesel fuel blend to be circulated through the rail at pressures above 200 psig keeping the DME in the liquid state. Fuel exiting the rail is cooled by finned tubed heat exchangers and recirculated to the rail using a gear pump. A modified LPG tank (for use on recreational vehicles) stores the DME- diesel fuel blend onboard the shuttle bus.

The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline range fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, with good correlation agreement to PMI. In addition, the paper will cover a global assessment of a gasoline range fuel’s sooting tendency based on the PMI number and the proposed method. Areas around the globe where market gasoline range fuels are of concern will be highlighted, in coordination with the new emissions regulations. Vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.

The Honda Particulate Matter Index (PMI) is a very helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and vehicle OEMs as a metric to understand a fuels impact on automotive engine sooting, in preparation for new global emissions regulations. The calculation of the index involves generating detailed hydrocarbon analysis (hydrocarbon molecular speciation) using gas chromatography laboratory equipment and the PMI calculation requires the exact list of compounds and correct naming conventions to work properly. The analytical methodology can be cumbersome, when the gas chromatography methodology has to be adjusted for new compounds that are not in the method, or if the compounds are not matching the list for quantification. Also, the method itself is relatively expensive, and not easily transferrable between labs.

In this work, an experimental and analysis methodology was developed to evaluate the preignition propensity of fuels and engine operating conditions in an SI engine. A heated glow plug was introduced into the combustion chamber to induce early propagating flames. As the temperature of the glowplug varied, both the fraction of cycles experiencing these early flames and the phasing of this combustion in the engine cycle varied. A statistical methodology for assigning a single-value to this complex behavior was developed and found to have very good repeatability. The effects of engine operating conditions and fuels were evaluated using this methodology. While this study is not directly studying the so-called stochastic preignition or low-speed preignition problem, it studies one aspect of that problem in a very controlled manner.

The impact of gasoline composition on vehicle particulate emissions response has been widely investigated and documented. Correlation equations between fuel composition and particulate emissions have also been documented, e.g. Particulate Matter Index (PMI) and Particulate Evaluation Index (PEI). Vehicle PM/PN emissions correlate very well with these indices. In a previous paper, global assessment with PEI on fuel sooting tendency was presented [1]. This paper will continue the previous theme by the authors, and cover China gasoline in more detail. With air pollution an increasing concern, along with more stringent emission requirements in China, both OEMs and oil industries are facing new challenges. Emissions controls require a systematic approach on both fuels and vehicles. Chinese production vehicle particulate emissions for a range of PEI fuels are also presented.

The effects of aromatic content and octane rating of gasoline fuels on stochastic pre-ignition (SPI) behaviors were investigated at typical operating conditions using a modern 2.0 L turbocharged engine. In-cylinder pressure time history measurements made during a speed-load test sequence designed to stimulate SPI were used to determine both the frequency of SPI occurrence and the in-cylinder peak pressure during such events. Six fuels were tested with varying levels of aromatic content (15 - 35% by vol.) and two octane rating levels (∼88 & 94 anti-knock index). The engine was operated using a production-intent calibration with equivalence ratio near one. Pressure and temperature in the intake manifold were held constant near two bar and 35°C respectively. Significant SPI activity was observed, with abnormal event frequencies up to ∼1 SPI event per 1,000 engine cycles and in-cylinder peak pressures up to ∼200 bar.

A series of experiments were performed using a Yanmar TS180, single cylinder, indirect injection (IDI) diesel engine, a natural gas fueled, Olympian G25F1S, spark-ignited, 25 kilowatt generator, and a two-stroke, multi-fuel, spark ignited engine to provide a diverse research platform for the study of in-cylinder NOx destruction (Conversion of NO). For each type of engine, the NOx recirculation step of the selective NOx recirculation (SNR) cycle was simulated by injecting pure nitric oxide (NO) into the intake air at various concentrations, depending on engine type and operating conditions. Previous researchers have attempted to characterize NOx destruction behavior by simulating the NOx recirculation step in both diesel and gasoline engines. Some prior work has suggested that NOx destruction behavior in diesel engines is not dependent on the amount of NO present in the intake air, and that the NOx destruction efficiency was greatly enhanced by increasing engine load.

Corrosion inhibitors (CIs) have been used for years to protect the supply and distribution hardware used for transportation of fuel from refineries. The impact of these inhibitors on spark ignited fuel systems, specifically intake valve deposits, is known and presented in open literature. However, the relationship of the additive concentrations to the powertrain intake valve deposit performance is not understood. This paper has two purposes: to present and discuss a market place survey of corrosion inhibitors and how they vary in concentration in the final blended fuel; and, to show how the variation in the concentrations of the CIs impact the operation and performance of vehicles, specifically, the effects on intake valve deposit formation. Commercially available corrosion inhibitor packages for both gasoline and ethanol blended fuels, specifically E85 fuels, were studied for their chemical compositions, and their impact on valves for a port fuel injection (PFI) engine.

With increasing use of ethanol in automotive fuel in recent years, which can be made from renewable feedstocks, the chemical composition of gasoline is changed. The compositional change results in many changes in fuel properties. One key property is the octane rating of gasoline. Market data has shown the shifts of octane rating (antiknock index or AKI) upward due to more penetration of E10 gasoline in the US market. However, the increase in research octane is more pronounced as compared to motor octane, therefore the increase in octane sensitivity in gasoline. Refineries have used the change in octane due to ethanol contribution by sending so called sub-grade gasoline to terminals expecting the final blend after mixing with ethanol to meet the market requirement in octane. Thus the octane rating of the final blend will largely depend on the sub-grade gasoline composition and ethanol.

Stochastic Preignition (SPI) is an abnormal combustion phenomenon for internal combustion engines (ICE), which has been a significant impact to automotive companies developing high efficiency, turbocharged, direct fuel injection, spark ignited engines. It is becoming clearer what fuel properties are related to the cause of SPI, whether directly with fuel preparation in the cylinder, or mechanisms related to the deposit build-up which contributes to initial and follow-on SPI events. The purpose of this paper is to provide a summary of global market gasoline fuel properties with special attention given to properties and specific compounds from the fuel and fuel additives that can contribute to SPI and the deposit build-up in engines. Based on a review of the global fuel quality, it appears that the fuel quality has not caught up to meet the technology requirements for fuel economy from modern technology engines.

Gasoline Direct Injection (GDI) has become the preferred technology for spark-ignition engines resulting in greater specific power output and lower fuel consumption, and consequently reduction in CO2 emission. However, GDI engines face a substantial challenge in meeting new and future emission limits, especially the stringent particle number (PN) emissions recently introduced in Europe and China. Studies have shown that the fuel used by a vehicle has a significant impact on engine out emissions. In this study, nine fuels with varying chemical composition and physical properties were tested on a modern turbo-charged side-mounted GDI engine with design changes to reduce particulate emissions. The fuels tested included four fuels meeting US certification requirements; two fuels meeting European certification requirements; and one fuel meeting China 6 certification requirements being proposed at the time of this work.

Two of the goals of the Penn State FutureTruck project were to reduce the emissions of the hybrid electric Ford Explorer to ULEV or lower, and improve the fuel economy by 25% over the stock vehicle. The hybrid electric vehicle system is powered with a 103kW 2.5L Detroit Diesel engine which operates with a fuel blend consisting of ultra-low-sulfur diesel and biodiesel (35%). Lower emissions are inherently achieved by the use of biodiesel. Additionally, the engine was fitted with a series of aftertreatment devices in an effort to achieve the low emissions standards. Vehicle testing has shown a gasoline-equivalent fuel economy improvement of approximately 22%, a reduction in greenhouse gas emissions by approximately 38%, and meeting or exceeding stock emissions numbers in all other categories through the use of an advanced catalyst and control strategy.

Stochastic Preignition (SPI) is an abnormal combustion event that occurs in a turbocharged engine and can lead to the loss in fuel economy and engine hardware damage, and in turn result in customer dissatisfaction. It is a significant limiting factor on the use and continued downsizing of turbocharged spark ignited direct injection (SIDI) gasoline engines. Understanding and mitigating all the factors that cause and influence the rate and severity of SPI occurrence are of critical importance to the engine’s continued use and fuel economy improvements for future designs. Previous studies have shown that the heavy molecular weight components of the fuel formulations are one factor that influences the rate of SPI from a turbocharged SIDI gasoline engine. All the previous studies have involved analyzing the fuel’s petroleum hydrocarbon chemistry, but not specifically the additives that are put in the fuel to protect and clean the internal components over the life of the engine.

Fuel chemistry plays a crucial role in the continued reduction of particulate emissions (PE) and cleaner air quality from vehicles and equipment powered by internal combustion engines (ICE). Over the past ten years, there have been great improvements in predictive particulate emissions indices (correlative mathematical models) based on the fuel’s composition. Examples of these particulate indices (PI) are the Honda Particulate Matter Index (PMI) and the General Motors Particulate Evaluation Index (PEI). However, the analytical chemistry lab methods used to generate data for these two PI indices are very time-consuming. Because gasoline can be mixtures of hundreds of hydrocarbon compounds, these lab methods typically include the use of the high resolution chromatographic separation techniques such as detailed hydrocarbon analysis (DHA), with 100m chromatography columns and long (3 - 4 hours) analysis times per sample.

The Particulate Matter Index (PMI) is a helpful tool which provides an indication of a fuel’s sooting tendency. Currently, the index is being used by various laboratories and OEMs as a metric to understand the gasoline fuels impact on both sooting found on engine hardware and vehicle out emissions. This paper will explore a new method that could be used to give indication of the sooting tendency of the gasoline range fuels, called the Particulate Evaluation Index (PEI), and provide the detailed equation in its initial form. In addition, the PEI will be shown to have a good correlation agreement to PMI. The paper will then give a detailed explanation of the data used to develop it. Initial vehicle PM/PN data will also be presented that shows correlations of the indices to the vehicle response.

With the implementation of the China VI gasoline standards, the use of ethanol is expanding and is intended to further reduce vehicle criteria gaseous and particulate emissions. However, due to the constraints of biomass ethanol production, petroleum derived Methyl tert-Butyl Ether (MTBE) is being used in addition to ethanol to improve fuel octane and maintain oxygen content. The impact of these mixed oxygenates on vehicle emissions are studied in this paper. The correlation of fuel characteristics to vehicle particulate emissions and their predictive indices has been investigated. The results from this study suggest some alternatives to existing fuel indices due to oxygenate contribution. Additionally, this paper studies, the emissions of three direct-injection turbocharged vehicle models focusing on particulate emissions from the Worldwide Harmonized Light Vehicles Test Cycle (WLTC). The test fuels were China VIb gasoline, blended with different ratios of ethanol and MTBE.

Biodiesel is a domestic, renewable fuel for diesel engines and is made from agricultural co-products such as soybean oil, rapeseed oil, palm oil and other natural oils. Biodiesel is a cleaner burning fuel that is biodegradable and non-toxic compared to petroleum diesel. Biodiesel has become a major alternative fuel for automotive applications and is critical for lowering US dependence on foreign oil and attain energy security. Vehicle manufacturers have developed new vehicle and diesel engine technologies compatible with B6-B20 biodiesel blends meeting ASTM D7467 specifications. Field warranty and validation tests have shown significant concerns with use of poor quality biodiesel fuels including fuel system deposits, engine oil deterioration, and efficiency loss of the after treatment system. Maintaining good quality of biodiesel is critical for success as a commercial fuel.