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For controlling oxides of nitrogen (NOx) and particular matter (PM) emissions from diesel engines, various fuel and combustion mode modification strategies are investigated in the past. Low temperature combustion (LTC) is an alternative combustion strategy that reduces NOx and PM emissions through premixed lean combustion. Dual fuel reactivity-controlled compression ignition (RCCI) is a promising LTC strategy with better control over the start and end of combustion because of reactivity and equivalence ratio stratification. However, the unburned hydrocarbon (HC) and carbon monoxide (CO) emissions are significantly higher in RCCI, especially at part-load conditions. The present work intends to address this shortcoming by utilizing oxygenated alternative fuels. Considering the limited availability and higher cost, replacing conventional fuels completely with alternative fuels is not feasible.

The presence of unsaturated methyl esters in biodiesel makes it susceptible to oxidation and fuel quality degradation upon long-term storage. In the present work, the effects of oxidation of Karanja biodiesel upon long-term storage on the combustion and emission characteristics of a heavy-duty truck diesel engine are studied. The Karanja biodiesel is stored for one year in a 200 litres steel barrel at room conditions to mimic commercial storage conditions. The results obtained show that compared to diesel, the start of injection of fresh and aged biodiesels are advanced by ~2-degree crank angle, and the ignition delay time is reduced. Aged biodiesel showed a slightly smaller ignition delay compares to fresh biodiesel. The fuel injection and combustion characteristics of fresh and aged biodiesels were similar at all the load conditions. Both fresh and aged biodiesels produced higher oxides of nitrogen (NOx) and lower smoke emissions compared to diesel.

In-cylinder emission control methods for simultaneous reduction of oxides of nitrogen (NOx) and particulate matter (PM) are gaining attention due to stringent emission targets and the higher cost of after-treatment systems. In addition, there is a renewed interest in using carbon-neutral biodiesel due to global warming concerns with fossil diesel. The bi-directional NOx-PM trade-off is reduced to a unidirectional higher NOx emission problem with biodiesel. The effect of water injection with biodiesel with low water quantities is relatively unexplored and is attempted in this investigation to mitigate higher NOx emissions. The water concentrations are maintained at 3, 6, and 9% relative to fuel mass by varying the pulse width of a low-pressure port fuel injector. Considering the corrosive effects of water at higher concentrations, they are maintained below 10% in the present work.

The research on reducing emissions from automotive engines through modifications in the combustion mode and the fuel type is gaining momentum because of the increasing contribution to global warming by the transportation sector. The combustion and emission formation in the advanced low temperature combustion (LTC) engine strategies are susceptible to fuel molecular composition and properties. Ignition timing in LTC strategies is primarily controlled by fuel composition and associated chemical kinetics. Thus, tailoring of fuel properties is required to address the limitations of LTC in terms of lack of control on ignition timing and narrow engine operating load range. Utilizing fuel blends and additives such as nanoparticles is a promising approach to achieving targeted fuel property. An improved understanding of fundamental processes, including fuel evaporation, is required due to its role in fuel-air mixing and emission formation in LTC.

The upcoming Bharat Stage VI (BS VI) emission legislation has put enormous pressure on the future of small diesel engines which are widely used in the Indian market. The present work investigates the emission reduction potential of a common rail direct injection single cylinder diesel engine by adopting a holistic approach of lowering the compression ratio, boosting the intake air and down-speeding the engine. Experimental investigations were conducted across the entire operating map of a mass-production, light-duty diesel engine to examine the benefits of the proposed approach and the results are quantified for the modified Indian drive cycle (MIDC). By reducing the compression ratio from 18:1 to 14:1, the oxides of nitrogen (NOx) and soot emissions are reduced by 40% and 75% respectively. However, a significant penalty in fuel economy, unburned hydrocarbon (HC) and carbon monoxide (CO) emissions are observed with the reduced compression ratio.

Extensive experimental investigations done over a decade in different engine types demonstrated the capability of achieving high efficiency along with low levels of oxides of nitrogen (NOx) and soot emissions with low temperature combustion (LTC) modes. However, the commercial application of LTC strategies requires several challenges to be addressed, including precise ignition timing control, reducing higher unburned hydrocarbon (UHC) and carbon monoxide (CO) emissions. The lower exhaust gas temperatures with LTC operation pose severe challenges for after-treatment control systems. Among the available LTC strategies, Reactivity Controlled Compression Ignition (RCCI) has emerged as the most promising strategy due to better ignition timing control with higher thermal efficiency. Nevertheless, the complexity of engine system hardware due to the dual fuel injection system and associated controls, high HC and CO emissions are the major limiting factors in RCCI.

Adopting a low compression ratio (LCR) is a viable approach to meet the stringent emission regulations since it can simultaneously reduce the oxides of nitrogen (NOx) and particulate matter (PM) emissions. However, significant shortcomings with the LCR approach include higher unburned hydrocarbon (HC) and carbon monoxide (CO) emissions and fuel economy penalties. Further, poor combustion stability of LCR engines at cold ambient and part load conditions may worsen the transient emission characteristics, which are least explored in the literature. In the present work, the effects of implementing the low compression ratio (LCR) approach in a mass-production light-duty vehicle powered by a single-cylinder diesel engine are investigated with a major focus on transient emission characteristics.

The ignition quality of a fuel is described by its cetane number. Experimental methods used to determine cetane number employ Co-operative fuel research (CFR) engine and Ignition quality tester (IQT) which are expensive, have less repeatability and require skilled operation, and hence least preferred. There are many prediction models reported, which involve number of double bonds and number of carbon atoms whose determination is not direct. Using models that relate biodiesel composition to its cetane number is limited by the range of esters involved. Hence, a model to predict cetane number of biodiesels that addresses the limitations of the existing models, without ignoring the influence of factors such as degree of unsaturation and number of carbon atoms, is needed. Fourier transform infrared spectroscopy (FTIR) could be one such method.

Biodiesel is a renewable, carbon neutral alternative fuel to diesel for compression ignition engine applications. Biodiesel could be produced from a large variety of feedstocks including vegetable oils, animal fats, algae, etc. and thus, vary significantly in their composition, fuel properties and thereby, engine characteristics. In the present work, the effects of biodiesel compositional variations on engine characteristics are captured using a multi-linear regression model incorporated with two new biodiesel composition based parameters, viz. straight chain saturation factor (SCSF) and modified degree of unsaturation (DUm). For this purpose, biodiesel produced from seven vegetable oils having significantly different compositions are tested in a single cylinder diesel engine at varying loads and injection timings. The regression model is formulated using 35 measured data points and is validated with 15 other data points which are not used for formulation.

Advanced low temperature combustion (LTC) modes are most promising to reduce green house gas emissions owing to fuel economy benefits apart from simultaneously reducing oxides of nitrogen (NOx) and particulate matter (PM) emissions from diesel engines. Various LTC strategies have been proposed so far and each of these LTC strategies have their own advantages and limitations interms of precise ignition control, achievable load range and higher unburned emissions. In the present work, a small single cylinder diesel engine is initially operated under conventional combustion mode at rated speed, varying load conditions to establish the base line reference data. Then, the engine is modified to operate under different LTC strategies including Homogenous Charge Compression Ignition (HCCI), Premixed Charge Compression Ignition (PCCI) and Reactivity Controlled Compression Ignition (RCCI).

Reactivity controlled compression ignition (RCCI) is one of the most promising low temperature combustion (LTC) strategies to achieve higher thermal efficiencies along with ultra low oxides of nitrogen (NOx) and particulate matter emissions. Small single cylinder diesel engines of air-cooled type are finding increasing applications in the agriculture pump-set and small utility power generation owing to their lower cost and fuel economy advantages. In the present work, a small single cylinder diesel engine is initially operated under conventional combustion mode at rated speed, varying load conditions to establish the base line reference data. Then, the engine is modified to operate under RCCI combustion mode with a newly designed cylinder head to accommodate a high pressure, fully flexible electronically controlled direct diesel fuel injection system, a low pressure gasoline port fuel injection system and an intake air pre heater.

Diesel fuels are complex mixtures of thousands of hydrocarbons. Since modeling their combustion characteristics with the inclusion of all hydrocarbon species is not feasible, a hybrid surrogate model approach is used in the present work to represent the physical and chemical properties of three different diesel fuels by using up to 13 and 4 separate hydrocarbon species, respectively. The surrogates are arrived at by matching their distillation profiles and important properties with the real fuel, while the chemistry surrogates are arrived at by using a Group Chemistry Representation (GCR) method wherein the hydrocarbon species in the physical property surrogates are grouped based on their chemical classes, and the chemistry of each class is represented by using up to two hydrocarbon species.

Unsaturated methyl esters in biodiesel make it susceptible to oxidation and fuel quality degradation upon long-term storage. It is almost impossible to use biodiesel for commercial applications immediately after production. The lead time between biodiesel production and usage is generally high, causing auto-oxidation and fuel quality degradation. Hence any onsite improvement in fuel quality should be tested with aged biodiesel. To avoid the food versus fuel debate, non-edible oil feedstocks are preferable for producing biodiesel. However, biodiesel from non-edible oil sources has more unsaturated methyl ester constituents. The traditional trade-off between oxides of nitrogen (NOx) and soot emissions in conventional diesel combustion is reduced to a more severe NOx problem with biodiesel. In the present study, NOx mitigation through fuel modifications is studied for oxidized biodiesel produced from a non-edible oil, Karanja.

Emulsification of biodiesel with water aids in reducing oxides of nitrogen (NOx) and smoke emissions simultaneously whilst improving the engine performance. However, widespread commercial applications of biodiesel-water emulsions require cost-effective surfactants that result in stable emulsions to avoid the corrosive effects of water at high temperatures prevailing in the engine combustion systems. The current investigation explored the effect of adding water to biodiesel at 6 and 12% by weight. A novel, cost-effective surfactant Polyglycerol Polyricinoleate (PGPR), was used to stabilize the emulsions. A magnetic stirrer with a heating facility was utilized to prepare biodiesel-water emulsions that were stable for over five months. The experiments were carried out on a light-duty diesel engine at a constant rated speed and varying load conditions. The results obtained with the emulsions were compared with neat biodiesel as the reference fuel.

Currently, alternative fuels produced from waste resources are gaining much attention to replace depleting fossil fuels. The disposal of waste plastic poses severe environmental problems across the globe. The energy embodied in waste plastics can be converted into liquid fuel by pyrolysis. The present work explores the possibility of utilizing waste plastic oil (WPO) produced from municipal plastic wastes and waste cooking oil (WCO) biodiesel produced from used cooking oil in a dual fuel reactivity-controlled compression ignition (RCCI) mode. A single-cylinder light-duty diesel engine used for agricultural water pumping applications is modified to run in RCCI through suitable intake and fuel injection systems modifications. Alternative fuel blends, viz. WPO and WCO biodiesel with 20 vol. % in gasoline and diesel is used as a port and direct-injected fuels in RCCI. The premixed ratio and direct-injected fuel timings are optimized to achieve maximum thermal efficiency.

Over the years, much progress has been made in automotive vehicle technology to achieve high efficiency and clean combustion. Reactivity controlled compression ignition (RCCI) is one of the most widely studied high-efficiency, clean combustion strategies. However, complex dual-fuel injection systems and associated controls, high unburned hydrocarbon (UHC), and carbon monoxide (CO) emissions limit RCCI use in practical applications. Recently, single fuel RCCI strategies are gaining more attention as the above shortcomings are effectively addressed. Homogeneous charge with direct injection (HCDI) is a single fuel RCCI strategy that results in high thermal efficiency and lower UHC and CO emissions. In HCDI, the port-injected diesel fuel vapour and air are inducted during the intake stroke and ignited with direct-injected diesel fuel near the end of the compression stroke. However, high oxides of nitrogen (NOx) make HCDI less viable for practical applications.

The carbon-neutral biodiesel is a promising renewable substitute for fossil diesel that renders the traditional oxides of nitrogen-particulate matter (NOx-PM) trade-off into a unidirectional NOx control problem. Low-temperature combustion (LTC) modes such as homogenous charge compression ignition (HCCI) are attractive for obtaining ultra-low NOx and PM emissions. Studies on utilizing biodiesel fuel for HCCI combustion mode are sparsely available. Moreover, biodiesel emulsions in the HCCI combustion mode have not been attempted so far. Based on this premise, the present work explored the potential to utilize biodiesel and its emulsions having 20% and 25% water by volume under HCCI operating conditions. Biodiesel was prepared from a non-edible Karanja oil. The biodiesel emulsions were prepared using a heated magnetic stirrer apparatus with 3% by volume of the raw Karanja oil as a surfactant.

The present work investigates the effects of lowering the compression ratio (LCR) from 18:1 to 14:1 and optimizing the fuel injection parameters across the operating range of a mass production light-duty diesel engine. The results were quantified for a regulatory Indian drive cycle using a one-dimensional simulation tool. The results show that the LCR approach can simultaneously reduce the oxides of nitrogen (NOx) and soot emissions by 28% and 64%, respectively. However, the unburned hydrocarbon (HC) and carbon monoxide (CO) emissions increased significantly by 305% and 119%, respectively, with a 4.5% penalty in brake specific fuel consumption (BSFC). Hence, optimization of fuel injection parameters specific to LCR operation was attempted. It was evident that advancing the main injection timing and reducing the injection pressure at low-load operating points can significantly help to reduce BSFC, HC and CO emissions with a slight increase in the NOx emissions.

Biodiesel makes an attractive option to replace fossil diesel owing to its applicability in diesel engines without major modifications. An increase in NO emissions with biodiesel compared to diesel is a major concern for its wider use. Blending alcohols, such as methanol, with biodiesel is a potential remedy to mitigate NO formation, as suggested by experiments. However, computational investigations studying the effect of biodiesel-methanol blends on NO formation are scarce. A combined experimental and computational approach is adopted here to investigate the NO formation mechanism with neat biodiesel and biodiesel-methanol blend fueled light duty diesel engine. Firstly, a new compact kinetic model is utilized consisting of oxidation reactions for methyl butanoate and n-dodecane as a surrogate for biodiesel. A surrogate is defined to represent biodiesel based on a combined property and functional group based approach.

In the present work, a relative comparison of addition of water to diesel through emulsion and fumigation methods is explored for reducing oxides of nitrogen (NOx) and smoke emissions in a production small bore diesel engine. The ratio of water to diesel was kept the same in both the methods at a lower concentration of 3% by mass to avoid any adverse effects on the engine system components. The experiments were conducted at a rated engine speed of 1500 rpm under varying load conditions. For engine studies using emulsion fuels, kinetically stable water-in-diesel nanoemulsions were prepared with 3% water concentration by mass of the total sample. The emulsion fuels formulated using commercial surfactants were transparent in appearance. The droplet size of the nanoemulsions was characterized using dynamic light scattering technique.