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Technical Paper

Unregulated Emissions Evaluation of Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI), State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), and Fuel Qualities Effects (EtOH, ETBE, Aromatics and FAME)

2007-10-29
2007-01-4082
In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.
Technical Paper

Total-NOx Sensor Based on Mixed-Potential for Detecting of Low NOx Concentrations

2005-04-11
2005-01-0451
We have been developing the mixed-potential type NOx sensor which can detect the total-NOX concentration directly in exhausts for automobiles. It has been confirmed that the sensor is capable of detecting wide concentrations of total-NOx from 20 to 1000 ppm under the condition from rich-burn (A/F=12) to lean-burn without any interference from reducing gases, such as HC and CO. In addition, it has been confirmed that the sensor output is correlated fairly well to NOx concentrations from the analyzer in the engine test at any rotations. The results obtained here indicate that the present sensor has great possibility of being utilized as an on-board NOx sensor for practical use.
Technical Paper

Three-Dimension Deposited Soot Distribution Measurement in Silicon Carbide Diesel Particulate Filters by Dynamic Neutron Radiography

2011-04-12
2011-01-0599
Exhaust emissions are well known to have adverse impacts on human health. Studies have demonstrated that there is an association between ambient particulate matter (PM) levels and various harmful cardiopulmonary conditions. Soot exhaust from diesel engines can be a significant contributor to airborne pollutants. A key component in PM level control for a diesel engine is a diesel particulate filter (DPF). This device traps soot while allowing other exhaust gases to pass unhindered. However, the performance of diesel particulate filters can change with increasing soot loadings and thus may require regeneration or replacement. Improved understanding of diesel particulate filters is dependent upon the knowledge of the actual soot loading and the soot distribution within the DPF. Neutron radiography (NR) has been identified as an effective means of non-destructively identifying hydrogen or carbon adsorbed in PM.
Technical Paper

The Influence of Inlet Port Design on the In-Cylinder Charge Mixing

1989-02-01
890842
A detailed investigation of the influence of intake port design on the in-cylinder flow structure during the intake and compression strokes, the mixing of the residual gas and a non-premixed intake charge, and the extent and pattern of charge inhomogenity near the time of combustion is described. The engine geometry is typical of the current lean-burn design and the study includes comparison of a helical (swirl) port and an idealized direct (no swirl) port designs. The results show marked dependence of the in-cylinder charge mixing characteristics on the intake port design. It is found that combinations of intake port design and manifold fuel injection timing produce favourably-stratified or irregularly-mixed charge distributions at the time of spark ignition. The consequences with respect to combustion characteristics are pointed out.
Technical Paper

Study of Mileage-Related Formaldehyde Emission from Methanol Fueled Vehicles

1990-02-01
900705
In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.
Technical Paper

Simulation of Exhaust Gas Aftertreatment Systems - Thermal Behavior During Different Operating Conditions

2008-04-14
2008-01-0865
The introduction of more stringent standards for engine emissions requires continuous improvement of exhaust gas aftertreatment systems. Modern systems require a combined design and application of different aftertreatment devices. Computer simulation helps to investigate the complexity of different system layouts. This study presents an overall aftertreatment modeling framework comprising dedicated models for pipes, oxidation catalysts, wall flow particulate filters and selective catalytic converters. The model equations of all components are discussed. The individual behavior of all components is compared to experimental data. With these well calibrated models a simulation study on a DOC-DPF-SCR exhaust system is performed. The impact of pipe wall insulation on the overall NOx conversion performance is investigated during four different engine operating conditions taken from a heavy-duty drive cycle.
Technical Paper

Research Results and Progress in LeaNOx II -A Co-operation for Lean NOx Abatement

2000-10-16
2000-01-2909
In a consortium of European industrial partners and research institutes, a combination of industrial development and scientific research was organised. The objective was to improve the catalytic NOx conversion for lean burn cars and heavy-duty trucks, taking into account boundary conditions for the fuel consumption. The project lasted for three years. During this period parallel research was conducted in research areas ranging from basic research based on a theoretical approach to full scale emission system development. NOx storage catalysts became a central part of the project. Catalysts were evaluated with respect to resistance towards sulphur poisoning. It was concluded that very low sulphur fuel is a necessity for efficient use of NOx trap technology. Additionally, attempts were made to develop methods for reactivating poisoned catalysts. Methods for short distance mixing were developed for the addition of reducing agent.
Technical Paper

Overview of the European “Particulates” Project on the Characterization of Exhaust Particulate Emissions from Road Vehicles: Results for Heavy Duty Engines

2004-06-08
2004-01-1986
This paper presents an overview of the results on heavy duty engines collected in the “PARTICULATES” project, which aimed at the characterization of exhaust particle emissions from road vehicles. The same exhaust gas sampling and measurement system as employed for the measurements on light duty vehicles [1] was used. Measurements were made in three labs to evaluate a wide range of particulate properties with a range of heavy duty engines and fuels. The measured properties included particle number, with focus separately on nucleation mode and solid particles, particle active surface and total mass. The sample consisted of 10 engines, ranging from Euro-I to prototype Euro-V technologies. The same core diesel fuels were used as in the light duty programme, mainly differentiated with respect to their sulphur content. Additional fuels were tested by some partners to extend the knowledge base.
Technical Paper

New Cordierite Diesel Particulate Filter Material for the Diesel Particulate - NOx Reduction System.

2004-03-08
2004-01-0953
The regulation of emissions discharged from diesel engines has become stricter worldwide. The regulatory values allowed for particulate matter (PM) as well as NOx will be lowered, especially in the Europe Euro 5, the U.S. EP 07, and the new Japanese long-term regulations. Since there is a tradeoff between the PM and NOx that are discharged from diesel engines, new emission reduction measures will be needed in order to greatly reduce both at the same time. By coating DPFs (Diesel Particulate Filters), which have been studied before, with NOx storage reduction catalysts, it has been found that simultaneous reduction of PM and NOx is possible, and so research was carried out in order to optimize a DPF for this type of system use. The DPF developed was used in the European DPNR (Diesel Particulate-NOx Reduction System) subject vehicles by Toyota Motor Corporation, and actual trial runs in Europe were performed.
Technical Paper

Nano Particle Emission Evaluation of State of the Art Diesel Aftertreatment Technologies (DPF, urea-SCR and DOC), Gasoline Combustion Systems (Lean Burn / Stoichiometric DISI and MPI) and Fuel Qualities Effects (EtOH, ETBE, FAME, Aromatics and Distillation)

2007-10-29
2007-01-4083
Newly designed laboratory measurement system, which reproduces particle number size distributions of both nuclei and accumulation mode particles in exhaust emissions, was developed. It enables continuous measurement of nano particle emissions in the size range between 5 and 1000 nm. Evaluations of particle number size distributions were conducted for diesel vehicles with a variety of emission aftertreatment devices and for gasoline vehicles with different combustion systems. For diesel vehicles, Diesel Oxidation Catalyst (DOC), urea-Selective Catalytic Reduction (urea-SCR) system and catalyzed Diesel Particulate Filter (DPF) were evaluated. For gasoline vehicles, Lean-burn Direct Injection Spark Ignition (DISI), Stoichiometric DISI and Multi Point Injection (MPI) were evaluated. Japanese latest transient test cycles were used for the evaluation: JE05 mode driving cycle for heavy duty vehicles and JC08 mode driving cycle for light duty vehicles.
Technical Paper

Model Based Development for Super Lean Burn Gasoline Engine Using Kolmogorov Microscales

2023-04-11
2023-01-0201
Combustion in a lean atmosphere diluted with a large amount of air can greatly improve fuel efficiency by reducing cooling loss [1, 2]. On the other hand, when air-fuel mixture in cylinder becomes lean, the turbulent combustion speed will decrease, resulting in problems such as the generation of unburned hydrocarbon (HC) and combustion instability [3, 4]. In order to solve these problems, it is important to increase the turbulence intensity and combustion speed [5, 6, 7, 8, 9, 10]. When designing combustion in cylinder by using Computational Fluid Dynamics (CFD), K-epsilon model is widely used for a turbulence model, and the calculated turbulence energy k or turbulence intensity u’ have been used as important indices of combustion velocity [11, 12].
Technical Paper

Investigation of Compressor Deposit in Turbocharger for Gasoline Engines (Part 2: Practical Application to Turbocharger)

2023-04-11
2023-01-0412
Contribution to carbon neutrality is one of the most important challenges for the automotive industry. Though CO2 emission has been reduced through electrification, internal combustion engines equipped in vehicles such as Hybrid Electric Vehicle (HEV) and Plug-in Hybrid Electric Vehicle (PHEV) are still necessary for the foreseeable future, and continuous efforts to improve fuel economy are demanded. To improve powertrain thermal efficiency, direct-injection turbocharged gasoline engines have been widely utilized in recent years. Super lean-burn combustion engine has been being researched as the next generation of turbocharged gasoline engines. It is known that an increase of the boost pressure causes deposit formation, which decrease the turbocharger efficiency, in the turbocharger compressor housing. To avoid the efficiency loss due to deposit, air temperature at compressor outlet has to be limited low.
Technical Paper

Integrated 1D to 3D Simulation Workflow of Exhaust Aftertreatment Devices

2004-03-08
2004-01-1132
Future limits on emissions for both gasoline and Diesel engines require adequate and advanced systems for the after-treatment of the exhaust gas. Computer models as a complementary tool to experimental investigations are an indispensable part to design reliable after-treatment devices such as catalytic converters and Diesel particulate filters including their influence on the power-train. Therefore, the objective of this contribution is to present an integrated 1D to 3D simulation workflow of of catalytic converters and Diesel particulate filters. The novelty of this approach is that parameters or set of parameters, obtained by a fast and efficient 1D-gas exchange and cycle simulation code for power-trains (AVL (2002a)), are readily transferable onto a 3D general purpose simulation code (AVL (2002b)). Thus, detailed aspects such as spatial distribution of temperatures or heat losses are investigated with only a single effort to estimate parameters.
Technical Paper

Improvement of PN Filtration Efficiency of Coated GPF – Study of Improvement of PN Filtration Efficiency and Reduction of Pressure Drop

2023-09-29
2023-32-0124
This research aimed to improve the PN filtration efficiency of a catalyst coated gasoline particulate filter (cGPF) to meet the next generation of emissions regulations for internal combustion engines. This paper proposes a concept that improves the PN filtration performance while maintaining low pressure drop by forming a thin PM trap layer on the surface of the cGPF substrate. The design guidelines for the coating particle size and coating amount of the PM trap layer were investigated, and actual manufacturing issues were also identified. The validity of this concept and guidelines was then verified on an actual vehicle.
Technical Paper

Impact Study of High Biodiesel Blends on Performance of Exhaust Aftertreatment Systems

2008-10-06
2008-01-2494
Biodiesel Fuel (BDF) Research Work Group works on identifying technological issues on the use of high biodiesel blends (over 5 mass%) in conventional diesel vehicles under the Japan Auto-Oil Program started in 2007. The Work Group conducts an analytical study on the issues to develop measures to be taken by fuel products and vehicle manufacturers, and to produce new technological findings that could contribute to the study of its introduction in Japan, including establishment of a national fuel quality standard covering high biodiesel blends. For evaluation of the impacts of high biodiesel blends on performance of diesel particulate filter system, a wide variety of biodiesel blendstocks were prepared, ranging from some kinds of fatty acid methyl esters (FAME) to another type of BDF such as hydrotreated biodiesel (HBD). Evaluation was mainly conducted on blend levels of 20% and 50%, but also conducted on 10% blends and neat FAME in some tests.
Journal Article

High Performance Cooling and EGR Systems as a Contribution to Meeting Future Emission Standards

2008-04-14
2008-01-1199
In relation to further tightening of the emissions legislation for on-road heavy duty Diesel engines, the future potential of cooled exhaust gas recirculation (EGR) as a result of developments in the cooling systems of such engines has been evaluated. Four basic engine concepts were investigated: an engine with SCR exhaust gas aftertreatment for control of the nitrogen oxides (NOx), an engine with cooled EGR and particulate (PM) filtration, an engine with low pressure EGR and PM filtration and an engine with two stage low temperature cooled EGR also with a particulate filter. A 10.5 litre engine was calibrated and tested under conditions representative for each concept, such that 1.7 g/kWh (1.3 g/bhp-hr) NOx could be achieved over the ESC and ETC. This corresponds to emissions 15% below the Euro 5 legislation level.
Technical Paper

Fuel Effects on SIDI Efficiency and Emissions

2003-10-27
2003-01-3186
Spark ignition direct injection (SIDI) engines have the potential to realize significant thermal efficiency improvements compared to conventional port fuel injection engines. The effects of fuel properties on efficiency and emissions have been investigated in a prototype of an Avensis Wagon equipped with a 2.0 liter, 4 cylinder spark ignition, direct injection (SIDI) engine designed to meet US 2000 emission standards. The vehicle employed a close coupled three-way catalyst and a NOx storage and reduction catalyst. Seven matrix fuels were blended to the same RON with varying levels of aromatics, olefins, ethanol, and volatility. Relative thermal efficiency, fuel economy, and tailpipe emissions were measured for the matrix fuels and a base fuel under the FTP LA4 driving cycle. The engine was operated in a lean burn mode in light load condition for approximately half of the driving cycle.
Technical Paper

Feasibility of Particulate Mass and Number Measurement with Portable Emission Measurement Systems (PEMS) for In-Use Testing

2011-09-11
2011-24-0199
Different particulate mass (PM) portable emission measurement systems (PEMS) were evaluated in the lab with three heavy-duty diesel engines which cover a wide range of particle emission levels. For the two engines without Diesel Particulate Filters (DPF) the proportional partial flow dilution systems SPC-472, OBS-TRPM, and micro-PSS measured 15% lower PM than the full dilution tunnel (CVS). The micro soot sensor (MSS), which measures soot in real time, measured 35% lower. For the DPF-equipped engine, where the emissions were in the order of 2 mg/kWh, the systems had differences from the CVS higher than 50%. For on-board testing a real-time sensor is necessary to convert the gravimetric (filter)-based PM to second-by-second mass emissions. The detection limit of the sensor, the particle property it measures (e.g., number, surface area or mass, volatiles or non-volatiles) and its calibration affect the estimated real-time mass emissions.
Technical Paper

Exhaust Gas Pressure Sensor

2008-04-14
2008-01-0907
As the whole world has been getting more concerned about the environmental protection, the emission regulations are getting stricter. The requirement to diesel engine is to develop the high-level engine management system to reduce both PM(Particulate Matter)and NOx. For PM reduction, post-treatment technology using a pressure sensor and a diesel particulate filter (hereinafter referred to as DPF) is necessary. This system burns out the clogged PM at the filter that the pressure sensor detects. The pressure sensor used in the DPF system has to be at an affordable price and to be reliable against corrosion, freezing, moisture and clogged soot in the harsh environment of exhaust gas with high humidity where highly-acid condensation water and the produced soot can intrude. This paper describes our newly developed pressure sensor that is suitable for the DPF system. The main features are as follows: a. Semiconductor type sensor with a simple structure and being less costly. b.
Technical Paper

Estimation of Diesel Soot Particles in Exhaust Gas Emission and Its Accumulation in Diesel Particulate Filter Using Graphical Calculation Model

2021-09-22
2021-26-0195
To avoid frequent regeneration intervals leading to expeditious ageing of the catalyst and substantial fuel penalty for the owner, it is always desired to estimate the soot coming from diesel exhaust emission, the soot accumulated and burnt in the Diesel Particulate Filter (DPF). Certain applications and vehicle duty cycles cannot make use of the differential pressure sensor for estimating the soot loading in the DPF because of the limitations of the sensor tolerance and measurement accuracy. The physical soot model is always active and hence a precise and more accurate model is preferred to calibrate & optimize the regeneration interval. This paper presents the approach to estimate the engine-out soot and the accumulated soot in the DPF using a graphical calculation tool (AVL Concerto CalcGraf™).
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