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The paper reports on the outcome of a still on-going joint-research project with the objective of establishing a demonstrator high speed direct injection (HSDI) diesel engine in a Sport Utility Vehicle (SUV) which allows to exploit the effectiveness of new engine and aftertreatment technologies for reducing exhaust emissions to future levels of US/EPA Tier 2 and Euro 4. This objective should be accomplished in three major steps: (1) reduce NOx by advanced engine technologies (cooled EGR, flexible high pressure common rail fuel injection system, adapted combustion system), (2) reduce particulates by the Continuous Regeneration Trap (CRT), and (3) reduce NOx further by a DeNOx aftertreatment technology. The current paper presents engine and vehicle results on step (1) and (2), and gives an outlook to step (3).

During recent years several VVT devices have been developed, in order to improve either peak power and low end torque, or part load fuel consumption of SI engines. This paper describes an experimental activity, concerning the integration of a continuously variable cam phaser (CVCP), together with an intake port deactivation device, on a small 4 cylinder 16V engine. The target was to achieve significantly lower fuel consumption under normal driving conditions, compared to a standard MPFI application. A single hydraulic cam phaser is used to shift both the intake and the exhaust cams to retarded positions, at constant overlap. Thus, high EGR rates in the combustion chamber and late intake valve closure (“reverse Miller cycle”) are combined, in order to reduce pumping losses at part load.

Exhaust gas recirculation (EGR) can be used to mitigate knock in SI engines. However, experiments have shown that the effectiveness of various EGR constituents to suppress knock varies with fuel type and compression ratio (CR). To understand some of the underlying mechanisms by which fuel composition, octane sensitivity (S), and CR affect the knock-mitigation effectiveness of EGR constituents, the current paper presents results from a chemical-kinetics modeling study. The numerical study was conducted with CHEMKIN, imposing experimentally acquired pressure traces on a closed reactor model. Simulated conditions include combinations of three RON-98 (Research Octane Number) fuels with two octane sensitivities and distinctive compositions, three EGR diluents, and two CRs (12:1 and 10:1). The experimental results point to the important role of thermal stratification in the end-gas to smooth peak heat-release rate (HRR) and prevent acoustic noise.

In order to clarify future automobile technologies and fuel qualities to improve air quality, second phase of Japan Clean Air Program (JCAPII) had been conducted from 2002 to 2007. Predicting improvement in air quality that might be attained by introducing new emission control technologies and determining fuel qualities required for the technologies is one of the main issues of this program. Unregulated material WG of JCAPII had studied unregulated emissions from gasoline and diesel engines. Eight gaseous hydrocarbons (HC), four Aldehydes and three polycyclic aromatic hydrocarbons (PAHs) were evaluated as unregulated emissions. Specifically, emissions of the following components were measured: 1,3-Butadiene, Benzene, Toluene, Xylene, Ethylbenzene, 1,3,5-Trimethyl-benzene, n-Hexane, Styrene as gaseous HCs, Formaldehyde, Acetaldehyde, Acrolein, Benzaldehyde as Aldehydes, and Benzo(a)pyrene, Benzo(b)fluoranthene, Benzo(k)fluoranthene as PAHs.

We have developed a novel engine cycle simulation program (UniDES: universal diesel engine simulator) to reproduce the diesel combustion process over a wide range of engine operating parameters, such as the amount of injected fuel, the injection timing, and the EGR ratio. The approach described in this paper employs a zoning model, where the in-cylinder region is divided into up to five zones. We also applied a probability density function (PDF) concept to each zone to consider the effect of spatial non-homogeneities, such as local equivalence ratios and temperature, on the combustion characteristics. We linked this program to the commonly used commercial GT-Power® software (UniDES+GT). As a result, we were able to reproduce transient engine behavior very accurately.

The aim of this research is to develop the diesel combustion simulation (UniDES: Universal Diesel Engine Simulator) that incorporates multiple-injection strategies and in-cylinder composition changes due to exhaust gas recirculation (EGR), and that is capable of high speed calculation. The model is based on a zero-dimensional (0D) cycle simulation, and represents a multiple-injection strategy using a multi-zone model and inhomogeneity using a probability density function (PDF) model. Therefore, the 0D cycle simulation also enables both high accuracy and high speed. This research considers application to actual development. To expand the applicability of the simulation, a model that accurately estimates nozzle sac pressure with various injection quantities and common rail pressures, a model that accounts for the effects of adjacent spray interaction, and a model that considers the NOx reduction phenomenon under high load conditions were added.

The CBR (Controlled Burn Rate) technology for MPFI engines is known to enable the reduction of throttle losses of gasoline engines by high EGR (Exhaust Gas Recirculation) rates due to the dilution tolerance of the swirl charge motion system using port deactivation. Now a new aspect of CBR is being developed: extremely low emissions during and after cold start. This paper is focused on the combustion stability and low emission aspects of CBR technology. It is shown how engine out emissions and catalyst light off behavior of an engine can be significantly improved using port deactivation. The very stable combustion directly after engine start, extremely retarded ignition timings in combination with lean engine operation and open valve injection with minimized wall wetting lead to very low HC emissions and very high exhaust gas temperatures.

The paper describes a feasibility test program on a 2 liter, 4 cylinder DI/TCI passenger car engine operated on the new alternative fuel Dimethyl Ether (DME, CH3 - O - CH3) with the aim of demonstrating its potential of meeting ULEV emissions (0.2 g/mi NOx in the FTP 75 test cycle) when installed in a full size passenger car. Special attention is drawn to the fuel injection equipment (FIE) as well as combustion system requirements towards the reduction of NOx and combustion noise while keeping energetic fuel consumption at the level of the baseline DI/TCI diesel engine. FIE and combustion system parameters were optimized on the steady state dynamometer by variation of a number of parameters, such as rate of injection, number of nozzle holes, compression ratio, piston bowl shape and exhaust gas recirculation.

The introduction of more stringent standards for engine emissions requires a steady development of engine control strategies in combination with efforts to optimize in-cylinder combustion and exhaust gas aftertreatment. With the goal of optimizing the overall emission performance this study presents the comprehensive simulation approach of a virtual vehicle model. A well established 1D gas dynamics and engine simulation model is extended by four key features. These are models for combustion and pollutant production in the cylinder, a model for the conversion of pollutants in a catalyst and a model for the effect of manifold wall wetting and fuel evaporation. The general species transport feature is linking these model together as it allows to transport an arbitrary number of chemical species in the entire system. Finally this highly detailed engine model is integrated into a vehicle model.

The influence of fuel density on exhaust emissions from diesel engines has been investigated in a number of studies and these have generally concluded that particulate emissions rise with increasing density This paper reviews recent work in this area, including the European Programme on Emissions, Fuels and Engine Technologies (EPEFE) and reports on a complementary study conducted by CONCAWE, in cooperation with AVL List GmbH The project was carried out with a passenger car equipped with an advanced technology high speed direct injection turbocharged / intercooled diesel engine fitted with a complex engine management system which was referenced to a specific fuel density This production model featured electronic diesel control, closed loop exhaust gas recirculation and an exhaust oxidation catalyst Tests were carried out with two EPEFE fuels which excluded the influence of key fuel properties other than density (828 8 and 855 1 kg/m3) Engine operation was adjusted for changes in fuel density by resetting the electronic programmable, read-only memory to obtain the same energy output from the two test fuels In chassis dynamometer tests over the ECE15 + EUDC test cycle the major impact of fuel density on particulate emissions for advanced engine technology/engine management systems was established A large proportion of the density effect on particulate and NOx emissions was due to physical interaction between fuel density and the electronic engine management system Limited bench engine testing of the basic engine showed that nearly complete compensation of the density effect on smoke (particulate) emissions could be achieved when no advanced technology was applied

Diesel exhaust gas contains low molecular aliphatic carbonyl compounds and strongly smelling organic acids, which are known to have an irritant influence on eyes, nose and mucous membranes. Thus, diesel exhaust aftertreatment has to be considered more critically than that of gasoline engines, with respect to the formation of undesired by-products. The results presented here have been carried out as research work sponsored by the German Research Association for Internal Combustion Engines (FVV). The main objective of the three year project was to evaluate the behaviour of current and future catalyst technology on the one hand (oxidation catalyst, CRT system, SCR process), and regulated and certain selected non-regulated exhaust gas emission components and exhaust gas odour on the other hand.

Recently, deposition of ash derived from engine oil on the surface of a diesel particle filter (DPF) has been reported to worsen the performance of the DPF. It is generally known that phosphorus in engine oil is adsorbed on the surface of an automotive exhaust catalyst and reduces the performance of the catalyst. Thus, the amounts of ash and phosphorus in engine oil have been decreased. We have developed a non-phosphorus and non-ash engine oil (NPNA) that does not contain metal-based detergents and zinc dialkyldithiophosphate (ZnDTP). We performed a performance test for NPNA using an actual engine and reported that the piston detergency and anti-wear performance of NPNA were sufficiently high. However, the piston detergency of NPNA required further improvement when engine running conditions were more severe.

This paper describes the development of a 0-D-sulfur poisoning model for a NOx storage catalyst (NSC). The model was developed and calibrated using findings and data obtained from a passenger car diesel engine used on testbed. Based on an empirical approach, the developed model is able to predict not only the lower sulfur adsorption with increasing temperature and therefore the higher SOx (SO2 and SO3) slip after NSC, but also the sulfur saturation with increasing sulfur loading, resulting in a decrease of the sulfur adsorption rate with ongoing sulfation. Furthermore, the 0-D sulfur poisoning model was integrated into an existing 1-D NOx storage catalyst kinetic model. The combination of the two models results in an “EAS Model” (exhaust aftertreatment system) able to predict the deterioration of NOx-storage in a NSC with increasing sulfation level, exhibiting higher NOx-emissions after the NSC once it is poisoned.

Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.

Engine oils normally contain calcium detergents and ZnDTPs to have detergency and antiwear performance. However, it has been recently understood that these additives could deteriorate filter performance in catalyst and DPF. In this background this paper explains the study and the development about new type of engine oil excluding metal detergents and phosphorus compounds. The developed engine oil shows good durability in several JASO engine tests and a fleet test by formulating newly developed additives as substitute for calcium detergents and ZnDTPs.

Three-way catalyst shows high performance under stoichiometric atmosphere. The CeO2-ZrO2 based materials (CZ) are added as a buffer of O2 concentration. To improve the catalyst performance the larger O2 storage capacity (OSC) are needed. Theoretically, the sulfur oxidation-reduction reaction moves oxygen 8 times larger than cerium. We focused on this phenomenon and synthesized Ln2O2SO4 as a new OSC material. The experimental result under model gas shows that the OSC of Ln2O2SO4 is 5 times lager than CZ.

Performance improvements were studied for the diesel particulate and NOx reduction system (DPNR), a system that simultaneously reduces NOx and Particulate Matter (PM) from diesel engine exhaust gas. The experimental system (hereinafter called the “dual DPNR”) consists of two DPNR catalysts arranged in parallel, each provided with an exhaust throttle valve downstream to control the exhaust gas flow to the catalyst, plus a fuel injector that precisely controls the air-fuel ratio and the catalyst bed temperature. The fuel injector is used to supply a rich mixture to the DPNR catalyst, and the flow of exhaust gas is switched between the two catalysts by operating the exhaust throttle valves alternately. Tests were conducted with the engine running at steady state. The results indicated that the NOx reduction performance dramatically improved and the loss of fuel economy from the NOx reduction reduced.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

A new after-treatment system called DPNR (Diesel Particulate-NOx Reduction System) has been developed for simultaneous and continuous reduction of particulate matter (PM) and nitrogen oxides (NOx) in diesel exhaust gas. This system consists of both a new catalytic technology and a new diesel combustion technology which enables rich operating conditions in diesel engines. The catalytic converter for the DPNR has a newly developed porous ceramic structure coated with a NOx storage reduction catalyst. A fresh DPNR catalyst reduced more than 80 % of both PM and NOx. This paper describes the concept and performance of the system in detail. Especially, the details of the PM oxidation mechanism in DPNR are described.

Improving vehicle fuel economy is a central part of efforts toward achieving a sustainable society. An effective way for accomplishing this aim is to enhance the engine thermal efficiency. Measures to mitigate knocking and reduce engine cooling heat loss are important aspects of enhancing the engine thermal efficiency. Cooled exhaust gas recirculation (EGR) is regarded as a key technology because it is capable of achieving both of these objectives. For this reason, it has been adopted in a wide range of both hybrid and conventional vehicles in recent years. Toyota has been introducing these technologies as ESTEC (Economy with Superior Thermal Efficient Combustion). Improving cycle-to-cycle variations in combustion, in addition to fast combustion is essential for achieving high engine thermal efficiency.