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The increased severity and prevalence of insoluble deposits formed on fuel injectors in gasoline direct injection (GDI) engines precipitates negative environmental, economic and healthcare impacts. A necessary step in mitigating deposits is to unravel the molecular compositions of these complex layered materials. But very little molecular data has been acquired. Mass spectrometry shows promise but most techniques require the use of solvents, making them unsuited for analyzing insoluble deposits. Here, we apply the high mass-resolving power and in-situ analysis capabilities of 3D OrbitrapTM secondary ion mass spectrometry (3D OrbiSIMS) to characterize deposits formed on the external tip and internal needle from a GDI injector. This is the first application of the technique to study internal GDI deposits. Polycyclic aromatic hydrocarbons (PAHs) are present up to higher maximum masses in the external deposit.

Modelling the vibro-acoustic properties of mechanical built-up structures is a challenging task, especially in the mid to high frequency regime, even with the computational resources available today. Standard modelling tools for complex vehicle parts include finite and boundary element methods (FEM and BEM), as well as Multi-Body Simulations (MBS). These methods are, however, robust only in the low frequency regime. In particular, FEM is not scalable to higher frequencies due to the prohibitive increase in model size. We have recently developed a new method called Discrete Flow Mapping (DFM), which extends existing high frequency methods, such as Statistical Energy Analysis or the so-called Dynamical Energy Analysis (DEA), to work on meshed structures. It provides for the first time detailed spatial information about the vibrational energy of a whole built-up structure of arbitrary complexity in this frequency range.

Diesel engines have traditionally been favoured in heavy-duty applications for their fuel economy, robustness, reliability and relative lack of fuel sensitivity. Recently it has seen a growth in its popularity in light duty applications due particularly to its fuel efficiency. However, as the engine technology and particularly the fuel injection equipment has evolved to meet ever stricter emissions legislation the engines have become more sensitive to deposit formation resulting from changes in fuel quality. This paper reviews bouts of concern over diesel fuel injector deposits, possible causes for the phenomenon and test methods designed to screen fuels to eliminate problems.

Recent developments in diesel fuel injection equipment coupled with moves to using ULSD and biodiesel blends has seen an increase in the number of reports, from both engine manufacturers and fleet operators, regarding fuel system deposit issues. Preliminary work performed to characterise these deposits showed them to be complicated mixtures, predominantly carbon like but also containing other possible carbon precursor materials. This paper describes the application of the combination of hydropyrolysis, gas chromatography and mass spectrometry to the analysis of these deposits. It also discusses the insights that such analysis can bring to the constitution and origin of these deposits.