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Dimethyl ether (DME) is an alternative to diesel fuel for use in compression-ignition engines with modified fuel systems and offers potential advantages of efficiency improvements and emission reductions. DME can be produced from natural gas (NG) or from renewable feedstocks such as landfill gas (LFG) or renewable natural gas from manure waste streams (MANR) or any other biomass. This study investigates the well-to-wheels (WTW) energy use and emissions of five DME production pathways as compared with those of petroleum gasoline and diesel using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model developed at Argonne National Laboratory (ANL).

Accounting for more than 90% of the molecules and more than 75% of the mass [1], hydrogen is the most abundant element in the universe. Due to the small molecule size and high buoyancy, it is not available in it’s free form on Earth. In recent years, hydrogen has gained the attention of the automotive industry [2–12] as an environmentally friendly alternative fuel. As a fuel, hydrogen is unique - it is odorless, colorless, tasteless, and burns invisibly in sunlight. Detection solutions such as the odorants used in natural gas are not yet feasible for automotive hydrogen because the available additives can poison the fuel cell catalyst. Additionally, the lower flammability limit of hydrogen is lower, and the flammability range wider, than fuels such as gasoline [13]. Hydrogen detection and its concentration measurement is usually done using hydrogen concentration sensors [13].

During the course of emissions and fuel economy (FE) testing, vehicles that are calibrated to meet Tier 3 emissions requirements currently must demonstrate compliance on Tier 3 E10 fuel while maintaining emissions capability with Tier 2 E0 fuel used for FE label determination. Tier 3 emissions regulations prescribe lower sulfur E10 gasoline blends for the U.S. market. Tier 3 emissions test fuels specified by EPA are required to contain 9.54 volume % ethanol and 8-11 ppm sulfur content. EPA Tier 2 E0 test fuel has no ethanol and has nominal 30 ppm sulfur content. Under Tier 3 rules, Tier 2 E0 test fuel is still used to determine FE. Tier 3 calibrations can have difficulty meeting low Tier 3 emissions targets while testing with Tier 2 E0 fuel. Research has revealed that the primary cause of the high emissions is deactivation of the aftertreatment system due to sulfur accumulation on the catalysts.

Historically, fuel cost conscious customers have tended to purchase diesel passenger cars. However, with increasing competition from alternative fuels and lean burn and direct injection gasoline fuelled engines, diesel engined vehicles currently face tough challenges from the point of fuel economy and emissions. In gasoline engines, low viscosity friction modified oils have demonstrated their potential for reducing internal engine friction and thus improving fuel economy, without adversely effecting engine durability. These fuel economy improvements have led to the introduction of such a low viscosity friction modified 5W-30 oil as the initial and service fill for the majority of Ford products sold in Europe. The trend towards even lower viscosities continues. To assess the potential benefits and issues of moving to 5W-20 in diesel engines, a short pilot study has been conducted using a Ford 1.8l direct injection diesel engine.

FTP emissions tests on a passenger vehicle equipped with a 1.8 L IDI turbo-charged diesel engine show that the mass emissions of particles decrease by (36±8)% when 16.6% dimethoxymethane (DMM) by volume is added to a diesel fuel. Particle size measurements reveal log-normal accumulation mode distributions with number weighted geometric mean diameters in the 80 - 100 nm range. The number density is comparable for both base fuel and the DMM/diesel blend; however, the distributions shift to smaller particle diameter for the blend. This shift to smaller size is consistent with the observed reduction in particulate mass. No change is observed in NOx emissions. Formaldehyde emissions increase by (50±25)%, while emissions of other hydrocarbons are unchanged to within the estimated experimental error.

The lack of electrical conductivity on materials, which are used in automotive fuel systems, can lead to electrostatic charges buildup in the components of such systems. This accumulation of energy can reach levels that exceed their capacity to withstand voltage surges, which considerably increases the risk of electrical discharges or sparks. Another important factor to consider is the conductivity of the commercially available fuels, such as biodiesel, which contributes to dissipate these charges to a proper grounding point in automobiles. From 2013, the diesel regulation in Brazil have changed and the levels of sulfur in the composition of diesel were reduced considerably, changing its natural characteristic of promoting electrostatic discharges, becoming more insulating.

This paper presents a study performed in 10 vehicles available in Brazilian market where the drivability with ethanol and gasoline, also referred as gasohol were compared. The motivation for this work came from the constant competition of the automotive industry, where engineers are searching for ways to improve the quality of the products aiming the “best in class” drivability with the best cost efficiency. For the Brazilian market, a further complexity is added to the development and verification process, which is the need to design and verify the controls and calibration considering the two fuels available in the market, the ethanol and the gasoline. In order to determine how the drivability is impacted by the ethanol, the paper presents a study where the drivability data were generated using the objective drivability measurement system AVL-DRIVE™.

An experimental study of the effects of partially-oxidized biodiesel fuel on the degradation of fresh fuel was performed. A blend of soybean oil fatty acid methyl esters (FAMEs) in petroleum diesel fuel (30% v:v biodiesel, B30) was aged under accelerated conditions (90°C with aeration). Aging conditions focused on three different degrees of initial oxidation: 1) reduced oxidation stability (Rancimat induction period, IP); 2) high peroxide values (PV); and 3) high total acid number (TAN). Aged B30 fuel was mixed with fresh B30 fuel at two concentrations (10% and 30% m:m) and degradation of the mixtures at the above aging conditions was monitored for IP, PV, TAN, and FAME composition. Greater content of aged fuel carryover (30% m:m) corresponded to stronger effects. Oxidation stability was most adversely affected by high peroxide concentration (Scenario 2), while peroxide content was most reduced for the high TAN scenario (Scenario 3).

In recent times, the development of alternate-fuel vehicles, including those fueled by hydrogen, has become relatively common. While there are potential safety related issues with any combustible fuel, these have been resolved over the last 100+ years. The comfort level with gasoline fuel has resulted from the widespread application of simple safety procedures followed at every stage of gasoline refinement and handling. It is important to have analogous procedures for handling hydrogen-fueled vehicles safely and with confidence. The characteristics of hydrogen, including: a) wide flammability range, b) very low ignition energy, c) odorless and difficult to detect, d) high diffusion rate, e) high buoyancy, f) invisible flame, etc., bolster the need for safe practices and procedures.

Greenhouse gas (GHG) emission targets are becoming more stringent for both automakers and electricity generators. With the introduction of plug-in hybrid and electric vehicles, transportation and electricity generation sectors become connected. This provides an opportunity for both sectors to work together to achieve the cost efficient reduction of CO2 emission. In addition, the abundant natural gas (NG) in USA is drawing increased attention from both policy makers and various industries due to its low cost and low carbon content. NG has the potential to ease the pressure from CO2 emission constraints for both the light duty vehicle (LDV) and the electricity generation sectors while simultaneously reducing their fuel costs. To quantify the benefit of this collaboration, an analytical model is developed to evaluate the total societal cost and CO2 emission for both sectors.

Interest in natural gas as a fuel for light-duty transportation has increased due to its domestic availability and lower cost relative to gasoline. Natural gas, comprised mainly of methane, has a higher knock resistance than gasoline making it advantageous for high load operation. However, the lower flame speeds of natural gas can cause ignitability issues at part-load operation leading to an increase in the initial flame development process. While port-fuel injection of natural gas can lead to a loss in power density due to the displacement of intake air, injecting natural gas directly into the cylinder can reduce such losses. A study was designed and performed to evaluate the potential of natural gas for use as a light-duty fuel. Steady-state baseline tests were performed on a single-cylinder research engine equipped for port-fuel injection of gasoline and natural gas, as well as centrally mounted direct injection of natural gas.

Future LEV-III tailpipe (TP) emission regulations pose an enormous challenge forcing the fleet average of light-duty vehicles produced in the 2025 model year to perform at the super ultralow emission vehicle (SULEV-30) certification levels (versus less than 20% produced today). To achieve SULEV-30, regulated TP emissions of non-methane organic gas (NMOG) hydrocarbons (HCs) and oxygenates plus oxides of nitrogen (NOx) must be below a combined 30 mg/mi (18.6 mg/km) standard as measured on the federal emissions certification cycle (FTP-75). However, when flex-fuel vehicles use E85 fuel instead of gasoline, NMOG emissions at cold start are nearly doubled, before the catalytic converter is active. Passive HC traps (HCTs) are a potential solution to reduce TP NMOG emissions. The conventional HCT design was modified by changing the zeolite chemistry so as to improve HC retention coupled with more efficient combustion during the desorption phase.

A fundamental thermodynamic model of the complete spark-ignited, homogeneous charge engine cycle has been used in several parametric analyses to predict the effects of engine design and operating alternatives on fuel consumption and emissions of NOx and unburned hydrocarbons (HC). The simulation includes sub-models for wall heat transfer, NOx and HC emissions, and the engine breathing processes. This work demonstrates the power and utility of a comprehensive engine simulation by presenting several independent parametric studies that were carried out in response to genuine engine design and/or operating strategy questions. Included in this compilation are the effects of cycle heat loss, exhaust port heat loss, combustion duration, and charge dilution (EGR and/or lean air-fuel ratio). In addition, the influence of the design variables associated with bore-stroke ratio, intake and exhaust valve lift, and cam timing are considered.

Ford Motor Company is introducing “EcoBoost” gasoline turbocharged direct injection (GTDI) engine technology in the 2010 Lincoln MKS. A logical enhancement of EcoBoost technology is the use of E85 for knock mitigation. The subject of this paper is the optimal use of E85 by using two fuel systems in the same EcoBoost engine: port fuel injection (PFI) of gasoline and direct injection (DI) of E85. Gasoline PFI is used for starting and light-medium load operation, while E85 DI is used only as required during high load operation to avoid knock. Direct injection of E85 (a commercially available blend of ∼85% ethanol and ∼15% gasoline) is extremely effective in suppressing knock, due to ethanol's high inherent octane and its high heat of vaporization, which results in substantial cooling of the charge. As a result, the compression ratio (CR) can be increased and higher boost levels can be used.

Fossil energy diversity and security along with environmental emission policies demand new energy carriers and associated technologies in the future. One of the major challenges of the automotive industry and research institutes worldwide currently is to develop and realize alternative fuel concepts for passenger cars. In line with Ford's global hydrogen vehicle program, different onboard hydrogen storage technologies are under investigation. In general, hydrogen storage methods can be categorized as either physical storage of hydrogen (i.e. compressed, liquid, or cryo-compressed) or material based hydrogen storage. Currently, automotive OEMs have only introduced hydrogen fleet vehicles that utilize physical-based hydrogen storage systems but they have recognized that hydrogen storage systems need to advance further to achieve the range associated with today's gasoline vehicle.

Ethanol has a high octane rating and can be added to gasoline to produce high octane fuel blends. Understanding the octane increase with ethanol blending is of great fundamental and practical importance. Potential issues with fuel flow rate and fuel vaporization have led to questions of the accuracy of octane measurements for ethanol-gasoline blends with moderate to high ethanol content (e.g., E20-E85) using the Cooperative Fuel Research (CFR™) engine. The nonlinearity of octane ratings with volumetric ethanol content makes it difficult to assess the accuracy of such measurements. In the present study, Research Octane Number (RON) and Motor Octane Number (MON) were measured for a matrix of ethanol-gasoline blends spanning a wide range of ethanol content (E0, E10, E20, E30, E50, E75) in a set of gasoline blendstocks spanning a range of RON values (82, 88, 92, and 95). Octane ratings for neat ethanol, denatured ethanol, and hydrous ethanol were also measured.

Engine performance and emission comparisons were made between the use of 100% soy, Canola and yellow grease derived biodiesel fuels and an ultra-low sulphur diesel fuel in the oxygen deficient regions, i.e. full or high load engine operations. Exhaust gas recirculation (EGR) was extensively applied to initiate low temperature combustion. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. The intake temperature, pressure, and EGR levels were modulated to improve the engine fuel efficiency and exhaust emissions. Furthermore, a preliminary ignition delay correlation under the influence of EGR was developed. Preliminary low temperature combustion modelling of the biodiesel and diesel fuels was also conducted. The research intends to achieve simultaneous reductions of nitrogen oxides and soot emissions in modern production diesel engines when biodiesel is applied.

Ford's H2RV (Hydrogen Hybrid Research Vehicle) uses a Hydrogen fueled Internal Combustion Engine. This engine has a higher compression ratio and a faster fuel-burning rate compared to a conventional gasoline engine. The conventional flywheel is replaced with an electric motor in the hybrid powertrain, which causes higher crankshaft torsionals and is a major NVH source. The engine has a centrifugal supercharger mounted on its front-end dress, which is a big source of NVH. Fans are used to cool the high voltage batteries and to provide ventilation of H2 in the case of a leakage. The body sheet metal has several holes for passive H2 ventilation, battery cooling, plumbing lines, and harness routing. Underhood hardware, due to the hybrid transmission and the H2 ICE, created major packaging challenges for the intake and FEAD NVH. The exhaust muffler volume was limited due to the installation of high voltage batteries and underbody H2 fuel tanks.

To help guide the design of homogeneous charge compression ignition (HCCI) engines, single and multi-zone models of the concept are developed by coupling the first law of thermodynamics with detailed chemistry of hydrocarbon fuel oxidation and NOx formation. These models are used in parametric studies to determine the effect of heat loss, crevice volume, temperature stratification, fuel-air equivalence ratio, engine speed, and boosting on HCCI engine operation. In the single-zone model, the cylinder is assumed to be adiabatic and its contents homogeneous. Start of combustion and bottom dead center temperatures required for ignition to occur at top dead center are reported for methane, n-heptane, isooctane, and a mixture of 87% isooctane and 13% n-heptane by volume (simulated gasoline) for a variety of operating conditions.

As regulations become more stringent, transient fuel control becomes extremely important for meeting emissions requirements in a cost-effective manner. Significant modeling work has been performed for a variety of conventional gasolines in port fuel injected (PFI) engines. This paper describes an extension of previous modeling work for alternative fuels. The paper first details the application of a distillation model to create the multi-component fuel models used in the simulations. The fuel models are then used in the transient Four Puddle Model to simulate the coupled liquid fuel and thermal/thermodynamic processes in the engine. Simulation results from the model are compared with dynamometer data over a transient, warm-up test.