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Cavitation plays a significant role in high pressure diesel injectors. However, cavitation is difficult to measure under realistic conditions. X-ray phase contrast imaging has been used in the past to study the internal geometry of fuel injectors and the structure of diesel sprays. In this paper we extend the technique to make in-situ measurements of cavitation inside unmodified diesel injectors at pressures of up to 1200 bar through the steel nozzle wall. A cerium contrast agent was added to a diesel surrogate, and the changes in x-ray intensity caused by changes in the fluid density due to cavitation were measured. Without the need to modify the injector for optical access, realistic injection and ambient pressures can be obtained and the effects of realistic nozzle geometries can be investigated. A range of single and multi-hole injectors were studied, both sharp-edged and hydro-ground. Cavitation was observed to increase with higher rail pressures.

Wireless Power Transfer (WPT) promises automated and highly efficient charging of electric and plug-in-hybrid vehicles. As commercial development proceeds forward, the technical challenges of efficiency, interoperability, interference and safety are a primary focus for this industry. The SAE Vehicle Wireless Power and Alignment Taskforce published the Recommended Practice J2954 to help harmonize the first phase of high-power WPT technology development. SAE J2954 uses a performance-based approach to standardizing WPT by specifying ground and vehicle assembly coils to be used in a test stand (per Z-class) to validate performance, interoperability and safety. The main goal of this SAE J2954 bench testing campaign was to prove interoperability between WPT systems utilizing different coil magnetic topologies. This type of testing had not been done before on such a scale with real automaker and supplier systems.

Propagation-based and phase-enhanced x-ray imaging was developed as a unique metrology technique to visualize the internal structure of high-pressure fuel injection nozzles. We have visualized the microstructures inside 200-μm fuel injection nozzles in a 3-mm-thick steel housing using this novel technique. Furthermore, this new x-ray-based metrology technique has been used to directly study the highly transient needle motion in the nozzles in situ and in real-time, which is virtually impossible by any other means. The needle motion has been shown to have the most direct effect on the fuel jet structure and spray formation immediately outside of the nozzle. In addition, the spray cone-angle has been perfectly correlated with the numerically simulated fuel flow inside the nozzle due to the transient nature of the needle during the injection.

Using synchrotron x-radiography and mass deconvolution techniques, this work reveals strikingly interesting structural and dynamic characteristics of the direct injection (DI) gasoline hollow-cone sprays in the near-nozzle region. Employed to measure the sprays, x-radiography allows quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution of better than 1 μs, revealing the most detailed near-nozzle mass distribution of a DI gasoline fuel spray ever detected. Based on the x-radiographs of the spray collected from four different perspectives, enhanced mathematical and numerical analyses were developed to deconvolute the mass density of the gasoline hollow-cone spray. This leads to efficient and accurate regression curve fitting of the measured experimental data to obtain essential parameters of the density distribution that are then used in reconstructing the cross-sectional density distribution at various times and locations.

Most previous measurements of diesel sprays have yielded few details regarding the near-nozzle structure of the sprays. X-ray radiography measurements have provided quantitative, time-resolved measurements of spray behavior, but the radiography data are projections of the actual fuel distribution. In this study, diesel sprays from two axial, single-hole nozzles are measured using x-ray radiography from several viewing angles. A model-based reconstruction is used to determine the actual density distribution from the projected data. The spray from the hydroground nozzle is eccentric and relatively dense, while the spray from the non-hydroground nozzle is asymmetric and far less dense. Even several mm from the nozzles, the calculated density values are high enough to call into question the assumptions underlying many standard CFD spray models.

Recovering metals from obsolete automobiles, home appliances, and other metal-containing obsolete durables and other scrap involves shredding these objects and separating the reusable metals from the shredded material by using magnets, eddy current separators, and metal detectors. Over 12 million automobiles are shredded annually in the United States alone, and almost all of the 4.5 million metric tonnes (5 million short tons) of the shredder residue produced in the United States annually is disposed of in landfills. Over 13.6 million tonnes (15 million tons) of shredder residue is generated worldwide every year. The rise in disposal costs is further exacerbated in that the percentage of shredder residue that must be disposed of, in comparison with the percentage of marketable recovered metals, is increasing because of the increasing content of polymers in automobiles and in home appliances.

Disposal of automobile shredder residue (ASR), remaining from the reclamation of steel from junked automobiles, promises to be an increasing environmental and economic concern. Argonne National Laboratory (ANL) is investigating alternative technology for recovering value from ASR while also, it is hoped, lessening landfill disposal concerns. Of the ASR total, some 20% by weight consists of plastics. Preliminary work at ANL is being directed toward developing a protocol, both mechanical and chemical (solvent dissolution), to separate and recover polyurethane foam and the major thermoplastic fraction from ASR. Feasibility has been demonstrated in laboratory-size equipment.

Over 250 million vehicles are operating on United States roads and highways and over 12 million of them reach the end of their useful lives annually. These end-of-life vehicles (ELVs) contain over 24 million tons (21.8 million metric tonnes) of materials including ferrous and non-ferrous metals, polymers, glass, and automotive fluids. They also contain many parts and components that are still useable and some that could be economically rebuilt or remanufactured. Dismantlers acquire the ELVs and recover from them parts for resale “as-is” or after remanufacturing. The dismantler then sells what remains of the vehicle, the “hulk”, to a shredder who shreds it to recover and sell the metals. Presently, the remaining non-metallic materials, commonly known as shredder residue, are mostly landfilled. The vehicle manufacturers, now more than ever, are working hard to build more energy efficient and safer, more affordable vehicles.

Cavitation plays an important role in fuel injection systems. It alters the nozzle's internal flow structure and discharge coefficient, and also contributes to injector wear. Quantitatively measuring and mapping the cavitation vapor distribution in a fuel injector is difficult, as cavitation occurs on very short time and length scales. Optical measurements of transparent model nozzles can indicate the morphology of large-scale cavitation, but are generally limited by the substantial amount of scattering that occurs between vapor and liquid phases. These limitations can be overcome with x-ray diagnostics, as x-rays refract, scatter and absorb much more weakly from phase interfaces. Here, we present an overview of some recent developments in quantitative x-ray diagnostics for cavitating flows. Measurements were conducted at the Advanced Photon Source at Argonne National Laboratory, using a submerged plastic test nozzle.

Recent advancements in x-ray radiography diagnostics for direct injection sprays at Argonne's Advanced Photon Source have allowed absorption measurements of individual spray events, in addition to ensemble-averaged measurements. These measurements offer insight into the shot-to-shot variation of these sprays in the near-nozzle, spray formation region. Three single hole diesel injectors are studied across various injection and ambient pressures, spanning 14 different conditions. We calculated two dimensional maps of the standard deviation in line of sight mass distribution between individual spray events. These illuminated the spatial and temporal extent of variability between spray events. Regions of large fluctuations were observed to move downstream during the initial spray period and reached a steady state location after this initial transient.

Additive manufacturing was used to fabricate a head for an automotive-scale single-cylinder engine operating on natural gas. The head was consisted of a bimetallic composition of stainless steel and bronze. The engine performance using the bimetallic head was compared against the stock cast iron head. The heads were tested at two speeds (1200 and 1800 rpm), two brake mean effective pressures (6 and 10 bar), and two equivalence ratios (0.7 and 1.0). The bimetallic head showed good durability over the test and produced equivalent efficiencies, exhaust temperatures, and heat rejection to the coolant to the stock head. Higher combustion temperatures and advanced combustion phasing resulted from use with the bimetallic head. The implication is that with optimization of the valve timing, an efficiency benefit may be realized with the bimetallic head.

Limited battery power and poor engine efficiency at cold temperature results in low plug in hybrid vehicle (PHEV) fuel economy and high emissions. Quick rise of battery temperature is not only important to mitigate lithium plating and thus preserve battery life, but also to increase the battery power limits so as to fully achieve fuel economy savings expected from a PHEV. Likewise, it is also important to raise the engine temperature so as to improve engine efficiency (therefore vehicle fuel economy) and to reduce emissions. One method of increasing the temperature of either component is to maximize their usage at cold temperatures thus increasing cumulative heat generating losses. Since both components supply energy to meet road load demand, maximizing the usage of one component would necessarily mean low usage and slow temperature rise of the other component. Thus, a natural trade-off exists between battery and engine warm-up.

While sulfur in diesel fuels helps reduce friction and prevents wear and galling in fuel pump and injector systems, it also creates environmental pollution in the form of hazardous particulates and SO2 emissions. The environmental concern is the driving force behind industry's efforts to come up with new alternative approaches to this problem. One such approach is to replace sulfur in diesel fuels with other chemicals that would maintain the antifriction and antiwear properties provided by sulfur in diesel fuels while at the same time reducing particulate emissions. A second alternative might be to surface-treat fuel injection parts (i.e., nitriding, carburizing, or coating the surfaces) to reduce or eliminate failures associated with the use of low-sulfur diesel fuels. Our research explores the potential usefulness of a near-frictionless carbon (NFC) film developed at Argonne National Laboratory in alleviating the aforementioned problems.

In this paper the KH-RT and the CAB droplet breakup models are analyzed. The focus is on near nozzle spray simulation data that will be qualitatively compared with results obtained from x-ray experiments. Furthermore, the suitability of the x-ray method for spray studies is assessed and its importance for droplet breakup modeling is discussed. The simulations have been carried out with the Kiva3VRel2 CFD-code into which the KH-RT- and the CAB- droplet breakup models have been implemented. Since the x-ray method gives an integrated line-of-sight mass distribution of the spray, a suitable comparison of the experimental distributions and the simulated ones is made. Additionally, modeling aspects are discussed and the functioning of the models demonstrated by illustrating how the parcel Weber numbers and radii vary spatially. The transient nature of the phenomenon is highlighted and the influence of the breakup model parameters is discussed.

The addition of metal nanoparticles to standard coolant fluids dramatically increases the thermal conductivity of the liquid. The properties of the prepared nanofluids will allow for lighter, smaller, and higher efficiency spacecraft thermal control systems to be developed. Nanofluids with spherical or rod-shaped metal nanoparticles were investigated. At a volume concentration of 0.5%, the room temperature thermal conductivity of a 2 nm spherical gold nanoparticle-water solution was increased by more than 10% over water alone. Silver nanorods increased the thermal conductivity of ethylene glycol by 53% and water by 26%.

Applying nanotechnology to thermal engineering, ANL has addressed the interesting and timely topic of nanofluids. We have developed methods for producing both oxide and metal nanofluids, studied their thermal conductivity, and obtained promising results: (1) Stable suspensions of nanoparticles can be achieved. (2) Nanofluids have significantly higher thermal conductivities than their base liquids. (3) Measured thermal conductivities of nanofluids are much greater than predicted. For these reasons, nanofluids show promise for improving the design and performance of vehicle thermal management systems. However, critical barriers to further development and application of nanofluid technology are agglomeration of nanoparticles and oxidation of metallic nanoparticles. Therefore, methods to prevent particle agglomeration and degradation are required.

Microstructure level inhomogeneities between the harder martensite phase and the softer ferrite phase render the dual phase (DP) steels more complicated failure mechanisms and associated failure modes compared to the conventionally used low alloy homogenous steels. This paper examines the failure mode DP780 steel under different loading conditions using finite element analyses on the microstructure levels. Micro-mechanics analyses based on the actual microstructures of DP steel are performed. The two-dimensional microstructure of DP steel was recorded by scanning electron microscopy (SEM). The plastic work hardening properties of the ferrite phase was determined by the synchrotron-based high-energy X-ray diffraction technique. The work hardening properties of the martensite phase were calibrated and determined based on the uniaxial tensile test results. Under different loading conditions, different failure modes are predicted in the form of plastic strain localization.

The process of shredding end-of-life vehicles to recover metals results in a byproduct commonly referred to as shredder residue. The four and a half million metric tons of shredder residue produced annually in the United States is presently land filled. To meet the challenges of automotive materials recycling, the U.S. Department of Energy is supporting research at Argonne National Laboratory in cooperation with the Vehicle Recycling Partnership (VRP) of the United States Council for Automotive Research (USCAR) and the American Plastics Council. This paper presents the results of a study that was conducted by Argonne to determine variations in the composition of shredder residue from different shredders. Over 90 metric tons of shredder residues were processed through the Argonne pilot plant. The contents of the various separated streams were quantitatively analyzed to determine their composition and to identify materials that should be targeted for recovery.

Lignin by-products from biorefineries has the potential to provide a low-cost alternative to petroleum-based precursors to manufacture carbon fiber, which can be combined with a binding matrix to produce a structural material with much greater specific strength and specific stiffness than conventional materials such as steel and aluminum. The market for carbon fiber is universally projected to grow exponentially to fill the needs of clean energy technologies such as wind turbines and to improve the fuel economies in vehicles through lightweighting. In addition to cellulosic biofuel production, lignin-based carbon fiber production coupled with biorefineries may provide $2,400 to $3,600 added value dry Mg−1 of biomass for vehicle applications. Compared to producing ethanol alone, the addition of lignin-derived carbon fiber could increase biorefinery gross revenue by 30% to 300%.

Argonne National Laboratory (ANL), working with the FreedomCAR Partnership, maintains the hybrid vehicle simulation software, Powertrain System Analysis Toolkit (PSAT). The importance of component models and the complexity involved in setting up optimized control laws require validation of the models and control strategies. Using its Advanced Powertrain Research Facilities (APRF), ANL thoroughly tested the 2004 Toyota Prius to validate the PSAT drivetrain. In this paper, we will first describe the methodology used to quality check test data. Then, we will explain the validation process leading to the simulated vehicle control strategy tuning, which is based on the analysis of the differences between test and simulation. Finally, we will demonstrate the validation of PSAT Prius component models and control strategy, using APRF vehicle test data.