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Technical Paper

Variable Air Composition with Polymer Membrane - A New Low Emissions Tool

1998-02-01
980178
Air can be enriched with oxygen and/or nitrogen by selective permeation through a nonporous polymer membrane; this concept offers numerous potential benefits for piston engines. The use of oxygen-enriched intake air can significantly reduce exhaust emissions (except NOx), improve power density, lessen ignition delay, and allow the use of lower-grade fuels. The use of nitrogen-enriched air as a diluent can lessen NOx emissions and may be considered an alternative to exhaust gas recirculation (EGR). Nitrogen-enriched air can also be used to generate a monatomic-nitrogen stream, with nonthermal plasma, to treat exhaust NOx. With such synergistic use of variable air composition from an on-board polymer membrane, many emissions problems can be solved effectively. This paper presents an overview of different applications of air separation membranes for diesel and spark-ignition engines. Membrane characteristics and operating requirements are examined for use in automotive engines.
Technical Paper

Using a DNS Framework to Test a Splashed Mass Sub-Model for Lagrangian Spray Simulations

2018-04-03
2018-01-0297
Numerical modeling of fuel injection in internal combustion engines in a Lagrangian framework requires the use of a spray-wall interaction sub-model to correctly assess the effects associated with spray impingement. The spray impingement dynamics may influence the air-fuel mixing and result in increased hydrocarbon and particulate matter emissions. One component of a spray-wall interaction model is the splashed mass fraction, i.e. the amount of mass that is ejected upon impingement. Many existing models are based on relatively large droplets (mm size), while diesel and gasoline sprays are expected to be of micron size before splashing under high pressure conditions. It is challenging to experimentally distinguish pre- from post-impinged spray droplets, leading to difficulty in model validation.
Technical Paper

Transmission Shifting Analysis and Model Validation for Medium Duty Vehicles

2023-04-11
2023-01-0196
Over the past couple of years, Argonne National Laboratory has tested, analyzed, and validated automobile models for the light duty vehicle class, including several types of powertrains including conventional, hybrid electric, plug-in hybrid electric and battery electric vehicles. Argonne’s previous works focused on the light duty vehicle models, but no work has been done on medium and heavy-duty vehicles. This study focuses on the validation of shifting control in advanced automatic transmission technologies for medium duty vehicles by using Argonne’s model-based high-fidelity, forward-looking, vehicle simulation tool, Autonomie. Different medium duty vehicles, from Argonne’s own fleet, including the Ram 2500, Ford F-250 and Ford F-350, were tested with the equipment for OBD (on-board diagnostics) signal data record. For the medium duty vehicles, a workflow process was used to import test data.
Technical Paper

Transient Particulate Emission Measurements in Diesel Engine Exhausts

2003-10-27
2003-01-3155
This paper reports our efforts to develop an instrument, TG-1, to measure particulate emissions from diesel engines in real-time. TG-1 while based on laser-induced incandescence allows measurements at 10 Hz on typical engine exhausts. Using such an instrument, measurements were performed in the exhaust of a 1.7L Mercedes Benz engine coupled to a low-inertia dynamometer. Comparative measurements performed under engine steady state conditions showed the instrument to agree within ±12% of measurements performed with an SMPS. Moreover, the instrument had far better time response and time resolution than a TEOM® 1105. Also, TG-1 appears to surpass the shortcomings of the TEOM instrument, i.e., of yielding negative values under certain engine conditions and, being sensitive to external vibration.
Journal Article

Towards Developing an Unleaded High Octane Test Procedure (RON>100) Using Toluene Standardization Fuels (TSF)

2020-09-15
2020-01-2040
An increase in spark-ignition engine efficiency can be gained by increasing the engine compression ratio, which requires fuels with higher knock resistance. Oxygenated fuel components, such as methanol, ethanol, isopropanol, or iso-butanol, all have a Research Octane Number (RON) higher than 100. The octane numbers (ON) of fuels are rated on the CFR F1/F2 engine by comparing the knock intensity of a sample fuel relative to that of bracketing primary reference fuels (PRF). The PRFs are a binary blend of iso-octane, which is defined to an ON of 100, and n-heptane, which represents an ON of 0. Above 100 ON, the PRF scale continues by adding diluted tetraethyl lead (TEL) to iso-octane. However, TEL is banned from use in commercial gasoline because of its toxicity. The ASTM octane number test methods have a “Fit for Use” test that validate the CFR engine’s compliance with the octane testing method by verifying the defined ON of toluene standardization fuels (TSF).
Technical Paper

Thermal Loading in SiC Particle Filters

1995-02-01
950151
Silicon Carbide (SiC) has been shown to have a high melting/decomposition temperature, good mechanical strength, and high thermal conductivity, which make it well suited for use as a material for diesel particulate filters. The high thermal conductivity of the material tends to reduce the temperature gradients and maximum temperature which arise during regeneration. The purpose of this paper is to experimentally investigate the thermal loading which arise under regenerations of varying severity. An experimental study is presented, in which regenerations of varying severity are conducted for uncoated SiC and Cordierite filters. The severity is varied through changes in the particle loading on the filters and by changing the flow conditions during the regeneration process itself. Temperature distributions throughout the filters are measured during these regeneration.
Technical Paper

The New PNGV System Analysis Toolkit PSAT V4.1 - Evolution and Improvement

2001-08-20
2001-01-2536
Argonne National Laboratory (ANL), working with the Partnership for a New Generation of Vehicles (PNGV), maintains hybrid vehicle simulation software, the PNGV System Analysis Toolkit (PSAT). PSAT, originally proprietary, has been used by both DOE and the “Big Three” as a modeling tool. The number of PSAT users has increased recently because 15 universities participating in the 2001 FutureTruck competition were given the software for their use. PSAT allows companies to look at new types of vehicles (hybrids) and choose the best configuration according to customer expectations within a minimum of time. PSAT, a forward-looking model, allows the user to simulate a large number of different configurations (conventional, series, parallel, and power split). PSAT is well suited for development of control strategies; by using accurate dynamics component models as its code, PSAT can be implemented directly and tested at the bench scale or in a vehicle.
Journal Article

Test Procedure Development for “Blended Type” Plug-In Hybrid Vehicles

2008-04-14
2008-01-0457
Several plug-in hybrid electric vehicles (PHEVs) have recently been made available by conversion companies for laboratory testing. The viability of the technology must be evaluated by dynamometer benchmark testing, but because the technology is so new, existing and new test methods must first be investigated. Converted Gen 2 Toyota Prius vehicles from Hymotion, EnergyCS, and Hybrids Plus were tested at Argonne's dynamometer facility according to general testing concepts. These vehicles all share basic attributes - all are blended type PHEVs, all use Lithium battery technology, and all deplete charge in a similar fashion (although at different rates). In a time span of one year, lessons learned from one vehicle were carried over into the next test vehicle. A minimum test method was formulated that is well suited for all these vehicles. The method was validated with two vehicles of varying charge-depleting range.
Technical Paper

Study of Regulated and Non-Regulated Emissions from Combustion of Gasoline, Alcohol Fuels and their Blends in a DI-SI Engine

2010-05-05
2010-01-1571
Alternative fuels for internal combustion engines have been the subject of numerous studies. The new U.S. Renewable Fuel Standard has made it a requirement to increase the production of ethanol and advanced biofuels to 36 billion gallons by 2022. Because corn-based ethanol will be capped at 15 billion gallons, 21 billion gallons must come from the advanced biofuels category. A potential source to fill the gap may be butanol and its isomers as they possess fuel properties superior to ethanol. Recently, concerns have been raised about emission of currently non-regulated constituents, aldehydes in particular, from alcohol-based fuels. In an effort to assess the relative impact of the U.S. Renewable Fuel Standards on emissions from a modern gasoline engine, both regulated and non-regulated gas constituents were measured from the combustion of three different alcohol isomers in a modern direct-injected (DI) spark ignition (SI) gasoline engine.
Technical Paper

Strategies on Methane Slip Mitigation of Spark-Ignition Natural Gas Engine during Transient Motion

2021-06-02
2021-01-5062
The liquefied natural gas (LNG)-fueled ships were provisioned to meet the strict emission legislation in the marine application since 2000. However, the scientific approach of burning the low-emission natural gas in lean combustion uncovered that the engine suffers from high methane slip emission. Serious questions are raised about the quantity of methane slip during marine conditions when the load varies in multiple frequencies and amplitudes. Previous studies by these authors explained how methane slip increases during load oscillation. This paper examined several practical methods to reach stable combustion in transient conditions to reduce the methane slip. Employing Proportional-Integral-Derivative (PID) controllers in a closed loop, implementing open-loop lookup tables, model predictive controller (MPC), and an innovated solenoid method are performed in a high-fidelity medium-speed natural gas spark-ignition (SI) engine model.
Technical Paper

Steady State Investigations of DPF Soot Burn Rates and DPF Modeling

2011-09-11
2011-24-0181
This work presents the experimental investigation of Diesel Particulate Filter (DPF) regeneration and a calibration procedure of a 1D DPF simulation model based on the commercial software AVL BOOST v. 5.1. Model constants and parameters are fitted on the basis of a number of steady state DPF experiments where the DPF is exposed to real engine exhaust gas in a test bed. The DPF is a silicon carbide filter of the wall flow type without a catalytic coating. A key task concerning the DPF model calibration is to perform accurate DPF experiments because measured gas concentrations, temperatures and soot mass concentrations are used as model boundary conditions. An in-house-developed raw exhaust gas sampling technique is used to measure the soot concentration upstream the DPF which is also needed to find the DPF soot burn rate.
Technical Paper

Standard Driving Cycles Comparison (IEA) & Impacts on the Ownership Cost

2018-04-03
2018-01-0423
A new type of approval procedure for light-duty vehicles, the Worldwide harmonized Light vehicles Test Procedure (WLTP), developed by an initiative of the United Nations Economic Commission for Europe, will come into force by the end of 2017. The current European type-approval procedure for energy consumption and CO2 emissions of cars, the New European Driving Cycle (NEDC), includes a number of tolerances and flexibilities that no longer accurately reflect state-of-the-art technologies. Indeed, on the basis of an analysis of real-world driving data from the German website spritmonitor.de, the ICCT concluded that the differences between official laboratory and real-world fuel consumption and CO2 values were around 7% in 2001. This discrepancy has been increasing continuously since then to around 30% in 2013, with notable differences found between individual manufacturers and vehicle models.
Technical Paper

Soot Formation Modelling of Spray-A Using a Transported PDF Approach

2015-09-01
2015-01-1849
Numerical simulations of soot formation were performed for n-dodecane spray using the transported probability density function (TPDF) method. Liquid n-dodecane was injected with 1500 bar fuel pressure into a constant-volume vessel with an ambient temperature, oxygen volume fraction and density of 900 K, 15% and 22.8 kg/m3, respectively. The interaction by exchange with the mean (IEM) model was employed to close the micro-mixing term. The unsteady Reynolds-averaged Navier-Stokes (RANS) equations coupled with the realizable k-ε turbulence model were used to provide turbulence information to the TPDF solver. A 53-species reduced n-dodecane chemical mechanism was employed to evaluate the reaction rates. Soot formation was modelled with an acetylene-based two-equation model which accounts for simultaneous soot particle inception, surface growth, coagulation and oxidation by O2 and OH.
Technical Paper

Soot Formation Modeling of n-dodecane and Diesel Sprays under Engine-Like Conditions

2015-09-06
2015-24-2468
This work concerns the modelling of soot formation process in diesel spray combustion under engine-like conditions. The key aim is to investigate the soot formation characteristics at different ambient temperatures. Prior to simulating the diesel combustion, numerical models including a revised multi-step soot model is validated by comparing to the experimental data of n-dodecane fuel in which the associated chemistry is better understood. In the diesel spray simulations, a single component n-heptane mechanism and the multi-component Diesel Oil Surrogate (DOS) model are adopted. A newly developed C16-based model which comprises skeletal mechanisms of n-hexadecane, heptamethylnonane, cyclohexane and toluene is also implemented. Comparisons of the results show that the simulated liftoff lengths are reasonably well-matched to the experimental measurement, where the relative differences are retained to below 18%.
Technical Paper

SiC as a Substrate for Diesel Particulate Filters

1993-09-01
932495
Many of the materials which have been developed for use as particle filters in the exhaust of diesel engines have characteristics which give rise to significant problems in practical use. Due to its special characteristics, it is shown that SiC is very well suited for use as the base material for particulate filters. The physical and thermal properties of porous SiC substrate material as applied to diesel particulate filters have been determined and are presented. Experimental results from several types of filter regeneration processes in exhaust gas systems confirm the improvements in the area of thermal load and reduction in temperature level during regeneration. The reduction in temperature during regeneration is shown to be consistent with the high thermal conductivity of SiC.
Technical Paper

Reduction of UHC-emissions from Natural Gas Fired SI-engine - Production and Application of Steam Reformed Natural Gas

2000-10-16
2000-01-2823
Application of a known hydrogen containing fuel called reformed natural gas (RNG) has been realized in a stationary combustion engine with success. The aim for this is to reduce unburned hydrogen emissions (UHC) from the engine together with an increase in efficiency. The fuel contains mainly methane, hydrogen and minor amounts of carbon dioxide. A small-scale unit for onboard production of RNG has been built in order to avoid the dependence of artificial supplementation of hydrogen. The production is carried out through means of steam reforming of natural gas. The RNG-unit together with theoretical considerations for estimating fuel composition and issues of caution are described. Theoretical studies show a potential for varying the hydrogen content between 8 and 30 vol%. Studies also show potential for remarkable increases in the methane number relative to that of the natural gas. A test engine has been fueled with RNG.
Journal Article

Reducing Light Duty Vehicle Fuel Consumption and Greenhouse Gas Emissions: The Combined Potential of Hybrid Technology and Behavioral Adaptation

2013-04-08
2013-01-1282
When comparing the potential of advanced versus conventional powertrains, a traditional approach is to hold glider design constant and simulate “comparable performance” to a conventional vehicle (CV). However, manufacturers have developed hybrid electric vehicle (HEV), plug-in hybrid electric vehicle (PHEV), and all-electric vehicle (EV) powertrains in gliders designed to synergistically enhance fuel saving benefits of such powertrains by further reducing road load and engine output power (or continuous power for the EV) where no conventional powertrain option is provided. In the U.S. marketplace, there are now several examples of both hybrid and plug-in hybrid electric vehicles using gliders common to top selling CVs and a few using low load gliders to further reduce fuel consumption.
Journal Article

Recent Developments in X-ray Diagnostics for Cavitation

2015-04-14
2015-01-0918
Cavitation plays an important role in fuel injection systems. It alters the nozzle's internal flow structure and discharge coefficient, and also contributes to injector wear. Quantitatively measuring and mapping the cavitation vapor distribution in a fuel injector is difficult, as cavitation occurs on very short time and length scales. Optical measurements of transparent model nozzles can indicate the morphology of large-scale cavitation, but are generally limited by the substantial amount of scattering that occurs between vapor and liquid phases. These limitations can be overcome with x-ray diagnostics, as x-rays refract, scatter and absorb much more weakly from phase interfaces. Here, we present an overview of some recent developments in quantitative x-ray diagnostics for cavitating flows. Measurements were conducted at the Advanced Photon Source at Argonne National Laboratory, using a submerged plastic test nozzle.
Technical Paper

Proof-of-Concept Numerical Study for NOx Reduction in Diesel Engines Using Enriched Nitrogen and Enriched Oxygen

2016-09-27
2016-01-8082
The medium and heavy duty vehicle industry has fostered an increase in emissions research with the aim of reducing NOx while maintaining power output and thermal efficiency. This research describes a proof-of-concept numerical study conducted on a Caterpillar single-cylinder research engine. The target of the study is to reduce NOx by taking a unique approach to combustion air handling and utilizing enriched nitrogen and oxygen gas streams provided by Air Separation Membranes. A large set of test cases were initially carried out for closed-cycle situations to determine an appropriate set of operating conditions that are conducive for NOx reduction and gas diffusion properties. Several parameters - experimental and numerical, were considered. Experimental aspects, such as engine RPM, fuel injection pressure, start of injection, spray inclusion angle, and valve timings were considered for the parametric study.
Technical Paper

Predicting the Port Air Mass Flow of SI Engines in Air/Fuel Ratio Control Applications

2000-03-06
2000-01-0260
With the tightening of exhaust emission standards, wide bandwidth control of the air/fuel ratio (AFR) of spark ignition engines has attracted increased interest recently. Unfortunately, time delays associated with engine operation (mainly injection delays and transport delays from intake to exhaust) impose serious limitations to the achievable control bandwidth. With a proper choice of sensors and actuators, these limitations can be minimized provided the port air mass flow can be accurately predicted ahead in time. While the main objective of this work is to propose a complete AFR controller, the main focus is on the problems associated with port air mass flow prediction.
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