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Technical Paper

The Effects of Coating Composition, Substrate, and Welding Machine on the Resistance Spot Welding Behavior of Hot-Dip Galvanized and Galvannealed Sheet Steels

1999-09-28
1999-01-3213
This joint research study by Bethlehem Steel Corporation and the U. S. Steel Group of the USX Corporation reveals that several significant factors affect the welding performance (electrode life) of hot-dip galvanized and galvannealed sheet steels. The statistical analyses of the electrode life data reveal that coating aluminum content affects electrode wear behavior of both the hot-dip galvanized and the galvannealed coatings. Higher levels of aluminum content cause more rapid electrode wear and shorten electrode life. Iron content in the galvannealed coatings seems to have some positive effect on increasing electrode life, but its effect is not nearly as significant as the negative effect of aluminum content. As the Fe/Al coating content ratio of galvannealed coatings increases, electrode life increases. Substrate type also affects electrode life, with the IF grade consistently producing shorter electrode lives.
Technical Paper

The Effect of Chromium and Chromium-Free Post-Phosphating Rinses on the Corrosion Performance of Zinc and Zinc Alloy Coated Sheet Steels After Five Years Outdoor Scab Corrosion Exposure

1993-10-01
932358
A selection of commercially available chromium and chromium-free post phosphate rinses along with a deionized water rinse were evaluated over several zinc and zinc-alloy coated sheet steels. The test specimens were pretreated and electrocoated on-line in an automotive assembly plant. The effect of the rinse treatments on the cosmetic corrosion performance of the substrates, after 5 years of exposure in an outdoor scab corrosion test was determined. After this exposure none of the rinse treatments had performed better than deionized water rinse on zinc and zinc-iron coated sheet. The zinc-nickel coating showed improved scribe creepage when treated with the Cr+6/Cr+3 rinse. Data is provided comparing the concentration of the treatments used vs scribe creepage and chipping corrosion paint loss.
Technical Paper

Sheet Steel Surface Treatments for Enhanced Formability

1994-03-01
940945
Surface friction is an important characteristic which influences the formability of sheet steel products. Numerous friction tests have been developed, and many previous investigations have reported effects of surface characteristics, coatings, lubrication, etc., on formability. Recently, increased attention has been focussed on reducing friction via the application of solid film lubricants or special surface post-treatments such as phosphates, metallics/intermetallics, etc. This paper presents the results of selected laboratory evaluations conducted using a variety of steels and surface treatments. Formability was measured using Limiting Dome Height and Drawbead Simulator friction testing, along with Limiting Draw Ratio testing in one instance. The examples highlight some potential opportunities which may be considered for improving formability in industrial stamping operations.
Technical Paper

RTM Body Panels for Viper Sports Car

1993-03-01
930468
Resin transfer molding (RTM) is the process of choice for the Body Panels of the Viper Sports car. The objective of this paper is to outline the reasons for the choice of RTM, and discuss development of technology for Class A surfaces and the paint system. Accomplishments to date and finally the work yet to be completed will also be defined. Conclusions from the work to date indicate that the RTM process enables a reduction in vehicle development time through faster prototypes and tool build times and that high quality, Class A surfaces can be successfully achieved even with epoxy tools. Additional work is ongoing to reduce cycle times and finishing costs, and to improve the in-process dimensional stability.
Technical Paper

Performance of Coatings for Underbody Structural Components

2001-03-05
2001-01-0363
The Auto/Steel Partnership established the Light Truck Frame Project Group in 1996 with two objectives: (a) to develop materials, design and fabrication knowledge that would enable the frames on North American OEM (original equipment manufacturer) light trucks to be reduced in weight, and (b) to improve corrosion resistance of frames on these vehicles, thereby allowing a reduction in the thickness of the components and a reduction in frame weight. To address the issues relating to corrosion, a subgroup of the Light Truck Frame Project Group was formed. The group comprised representatives from the North American automotive companies, test laboratories, frame manufacturers, and steel producers. As part of a comprehensive test program, the Corrosion Subgroup has completed tests on frame coatings. Using coated panels of a low carbon hot rolled and pickled steel sheet and two types of accelerated cyclic corrosion tests, seven frame coatings were tested for corrosion performance.
Technical Paper

Optimizing Press Performance for Difficult Automotive Stampings

1986-02-01
860440
A method has been employed in the stamping facility to reduce scrap by correlating observations from the press shop with laboratory test results. This paper illustrates the successful use of this method for reducing formability failures. Correlation of observed coating behavior with laboratory adherence tests is also discussed.
Technical Paper

Nylon RIM Development for Automotive Body Panels

1985-02-01
850157
The performance and production requirements for future passenger vehicles has increased the efforts to replace metal body panels with plastic materials. This has been accomplished, to a large extent on some production vehicles that have been introduced recently. Unfortunately, these plastic body applications have necessitated special off-line handling or low temperature paint processing. However, the advantages of RIM nylon, offer the potential for uniquely new plastic body designs, that can be processed through existing assembly plants, much like the steel panels they are intended to replace. The intent of this paper is to discuss the rationale for future plastic body panel material selection and related nylon RIM development efforts.
Technical Paper

Metal Converter Technology Using Precoated Metal Foil

1996-10-01
962080
A novel process for coating and assembling metal converters utilizing precoated foil as building blocks has been developed which yields a converter capable of withstanding typical industry specified hot vibration protocols. The precoating process used here results in uniform catalyst coating distributions with coating adhesion to the foil on a par with the coatings' adhesion to ceramic substrates. FTP and MVEG vehicle emission performance of this unique precoated metal converter design versus a more conventional dip-coated metal monolith (parts with the same volume, cell density, and tri-metal catalyst coating), exhibited improved catalyst emission breakthrough efficiencies with respect to HC, CO, and NOx after two different engine-aging protocols. These advantages were observed on three different test vehicles across most phases of these driving cycles.
Technical Paper

Life Cycle Management in the Auto Manufacturing Industry - A Report from President Clinton's Council on Sustainable Development Auto Team

1995-10-01
951871
An assessment of automobile painting at General Motor's Lake Orion, Michigan, USA assembly facility from a life cycle perspective was conducted. The Orion Facility produces the new Oldsmobile Aurora and Buick Riviera models. Improvements in on-site pollution prevention, energy conservation and regulatory barriers to technology innovation were identified. The environmental implications of auto body substrate material choice were analyzed. A life cycle inventory framework was developed for paint suppliers and other parts of the auto painting life cycle. An Alternative Regulatory System was proposed for the entire U.S. auto industry that will, if implemented, facilitate the integration of environmental management into core business strategies and planning.
Technical Paper

Hydrogen Embrittlement in Automotive Fastener Applications

1996-02-01
960312
Fastener failure due to hydrogen embrittlement is of significant concern in the automotive industry. These types of failures occur unexpectedly. They may be very costly to the automotive company and fastener supplier, not only monetarily, but also in terms of customer satisfaction and safety. This paper is an overview of a program which one automotive company initiated to minimize hydrogen embrittlement in fasteners. The objectives of the program were two-fold. One was to obtain a better understanding of the hydrogen embrittlement phenomena as it relates to automotive fastener materials and processes. The second and most important objective, was to eliminate hydrogen embrittlement failures in vehicles. Early program efforts concentrated on a review of fastener applications and corrosion protection systems to optimize coated fasteners for hydrogen embrittlement resistance.
Technical Paper

Globalization of Automotive Specifications

1997-02-24
970992
The Paint Technology Globalization effort is recognized as an important step of accomplishing the leveraging of worldwide resources of both engineering and purchasing in order to improve General Motor's competitiveness. The process used, the benefits derived, the current status of the effort, and the expected results (deliverables) are discussed. These include common materials, processing, and equipment paint specifications to be included in purchasing bid packages.
Technical Paper

Five Year Outdoor Scab Corrosion Results on Zinc and Zinc Alloy Coated Sheet Steels

1993-10-01
932361
A comprehensive selection of automotive sheet steels were exposed in an outdoor scab corrosion test to provide a base-line of cosmetic corrosion performance. Eighteen different coated sheet steels along with CRS as a control were processed using two commercially available zinc phosphate chemistries. The phosphating was done using both immersion and spray phosphate processes in a laboratory and an automotive assembly plant. Scribe creepage results are reported for 5 years outdoor scab exposure. Comparisons of the scribe creepage behavior of CRS, zinc, and zinc alloy coatings and the effect of the phosphate treatment are provided. An estimate of 10 years field performance is made.
Technical Paper

Field Evaluation of Down-Gauged High Performance RIM Fascia Polymers

1993-03-01
930539
Reducing the wall thickness of automotive fascia offers cost and weight savings over those manufactured today. New high performance RIM polyurethane/urea and polyurea polymers with improved mechanical properties over conventional systems make down-gauging possible while maintaining specified performance.1 Adding low cost, high surface quality fillers to these polymers provides enhanced dimensional stability in fascia at reduced wall thickness, thus meeting ever increasing demands for lower cost and high quality. This paper describes validation studies of filled RIM fascia down-gauged 22% to 3.0 mm wall thickness and compares them to conventional fascia moulded at nominal 3.9 mm wall thickness. High performance polyurethane/urea, polyurea, and conventional polyurethane/urea each incorporating wollastonite, mica, or milled glass were tested. The data include “on-car position” moisture stability, painted impact at low temperature, and material processing.
Technical Paper

Evaluation of a Continuous Annealed Bake Hardenable Steel for Improved Dent Resistance

1989-02-01
890711
The potential of bake hardenable steel as a substitute for SAE 1008 steel to reduce gage and improve dent resistance is investigated in this report. Outer body panels in particular are susceptible to palm printing and other forms of denting. Conventional SAE 1008 steel and a developmental continuous annealed bake hardenable steel from Inland Steel Company are compared for dent performance properties. Bake hardenable (BH) steel is a medium strength (200-350 MPa) steel that receives an increase in yield strength during the heating of the paint bake cycle. An increase in yield strength would result in an increase in dent resistance. The increase in dent resistance is more quantitatively evaluated by comparing the BH steel with the current production material (SAE 1008) of a rear compartment lid outer.
Technical Paper

Effects of Substrate and Phosphate Type on the Painted Corrosion Performance of Galvanneal Coated Sheet

1995-02-01
950379
Galvannealed sheet steel is gaining acceptance by automotive manufacturers due to its combination of properties and cost. Galvanneal can be produced by several processes including the most common method termed the “hot” line hot dip coating process, but also using “flux” line hot dip coating application. Similarly, several types of phosphate coatings: Zn, Zn-Ni, and Zn-Ni-Mn phosphates can be applied to these materials prior to painting to enhance paint adhesion and painted corrosion resistance. This manuscript reports the affects of commercial phosphate type and galvanneal type (based on production method and properties) on the corrosion performance of galvanneal. In addition, painted corrosion performance of galvanneal is compared to painted corrosion performance of electroplated zinc. The manuscript also describes the use of electrochemical methods as one alternative to conventional test methods resulting in substantial time savings.
Technical Paper

Effects of Steel Surface Texture on Appearance After Painting

1993-03-01
930032
An extensive investigation was conducted to assess the influence of steel sheet surface finish (i.e. topography or “texture”) on painted surface appearance. Ten sets of steel panels representing a variety of shot blast, EDT, laser, and bright surface textures were painted simultaneously using advanced solvent-based luxury vehicle paint systems. Paint appearance was measured using a relatively new Autospect instrument and also in terms of conventional Distinctness of Reflected Image (DOI). The results are discussed in detail with respect to 1) the influence of different steel surface textures on paint appearance, 2) the evolution of surface topography during painting, and 3) the implications of this work.
Technical Paper

Effects of Pretreatment Variables on the Corrosion Performance of Galvanneal

1995-02-01
950381
Corrosion resistance has been the major impetus toward increased use of galvanneal and other coated sheet products by the automotive industry. Galvanneal has the additional advantages of good weldability, due to the iron in the coating, and a higher surface porosity which leads to better paint adhesion. The porosity of the galvanneal surface, however, could also lead to reduced cleanability. This paper reports the effects of pretreatment variables on galvanneal phosphatability and resulting painted corrosion performance. The studies showed that the rust preventative oil applied and the alkaline cleaner used to clean samples prior to phosphating had significant effects on carbon residuals after cleaning. The painted corrosion performance of galvanneal panels with various levels of residual carbon showed a much smaller effect within a given cyclic test. The studies also indicated significant differences in performance depending on the type of cyclic test performed.
Technical Paper

Effects of Coating Weight and Pretreatment on the Painted Corrosion Performance of Coated Steel Sheet

1997-02-24
970732
A program was initiated to determine corrosion performance of coated sheet products. The program examined the performance of galvannealed, hot-dip galvanized and electroplated zinc coated steel sheet in a variety of cyclic laboratory corrosion tests. Both perforation and cosmetic corrosion susceptibility were evaluated. Materials were pretreated using immersion and spray phosphate systems and were also prepared without a phosphate pretreatment. Results of these studies will be presented in this paper.
Technical Paper

Corrosion Performance and Fuel Compatibility of Prepainted Zinc-Nickel Coated Steel for Fuel Tank Applications

1997-02-24
971006
Automotive demands for increased service life and use of flexible fuel blends of alcohol and gasoline have propelled the development of new materials for automotive fuel systems. Traditional fuel system materials, i.e., bare or prepainted terne coated steel sheet, which do not meet the new requirements are being replaced with prepainted zinc-nickel coated steel sheet. Automotive fuel tanks and fuel system components made from the new prepainted zinc-nickel steel sheet offer increased service life and compatibility with the entire range of flexible fuel blends. This paper describes the results of several laboratory corrosion studies which examined the environmental corrosion performance and the fuel compatibility of prepainted zinc-nickel coated steel as a function of several system properties. Performance is compared to prepainted terne, prepainted hot dip tin, and prepainted galvanneal.
Technical Paper

Application of a Constrained Layer Damping Treatment to a Cast Aluminum V6 Engine Front Cover

2005-05-16
2005-01-2286
Constrained Layer Damping (CLD) treatments have long provided a means to effectively impart damping to a structure [1, 2 and 3]. Traditionally, CLD treatments are constructed of a very thin polymer layer constrained by a thicker metal layer. Because the adhesion of a thin polymer layer is very sensitive to surface finish, surfaces that a CLD treatment can be effectively applied to have historically been limited to those that are very flat and smooth. New developments in material technology have provided thicker materials that are very effective and less expensive to apply when used as the damping layer in a CLD treatment. This paper documents the effectiveness of such a treatment on a cast aluminum front cover for a V6 engine. Physical construction of the treatment, material properties and design criteria will be discussed. Candidate applications, the assembly process, methods for secondary mechanical fastening will be presented.
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