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A key component of an Advanced Life Support (ALS) system is the solid waste handling system. One of the most important data sets for determining what solid waste handling technologies are needed is a solid waste model. A preliminary solid waste model based on a six-person crew was developed prior to the 2000 Solid Waste Processing and Resource Recovery (SWPRR) workshop. After the workshop, comments from the ALS community helped refine the model. Refinements included better estimates of both inedible plant biomass and packaging materials. Estimates for Extravehicular Mobility Unit (EMU) waste, water processor brine solution, as well as the water contents for various solid wastes were included in the model refinement efforts. The wastes were re-categorized and the dry wastes were separated from wet wastes. This paper details the revised model as of the end of 2001. The packaging materials, as well as the biomass wastes, vary significantly between different proposed Mars missions.

Biological wastewater processing has been under investigation by AlliedSignal Aerospace and NASA Johnson Space Center (JSC) for future use in space. Testing at JSC in the Hybrid Regenerative Water Recovery System (HRWRS) in preparation for future closed human testing has been performed. Computer models have been developed to aid in the design of a new four-person immobilized cell bioreactor. The design of the reactor and validation of the computer model is presented. In addition, the total organic carbon (TOC) computer model has been expanded to begin investigation of nitrification. This model is being developed to identify the key parameters of the nitrification process, and to improve the design and operating conditions of nitrifying bioreactors. In addition, the model can be used as a design tool to rapidly predict the effects of changes in operational conditions and reactor design, significantly reducing the number and duration of experiments required.

Two crops of lettuce (Lactuca sativa cv. Waldmann's Green) were grown in the Regenerative Life Support Systems (RLSS) Test Bed at NASA's Johnson Space Center. The RLSS Test Bed is an atmospherically closed, controlled environment facility for the evaluation of regenerative life support systems using higher plants. The chamber encloses 10.6 m2 of growth area under cool-white fluorescent lamps. Lettuce was double seeded in 480 pots, each containing about 250 cm3 of calcined-clay substrate. Each pot was irrigated with half-strength Hoagland's nutrient solution at an average total applied amount of 2.5 and 1.8 liters pot-1, respectively, over each of the two 30-day crop tests. Average environmental and cultural conditions during both tests were 23°C air temperature, 72% relative humidity, 1000 ppm carbon dioxide (CO2), 16h light/8h dark photoperiod, and 356 μmol m-2s-1 photosynthetic photon flux.

Iodine is the disinfectant used in U.S. spacecraft potable water systems. Recent long-term testing on human subjects has raised concerns about excessive iodine consumption. Efforts to reduce iodine consumption by Shuttle crews were initiated on STS-87, using hardware originally designed to deiodinate Shuttle water prior to transfer to the Mir Space Station. This hardware has several negative aspects when used for Shuttle galley operations, and efforts to develop a practical alternative were initiated under a compressed development schedule. The alternative Low Iodine Residual System (LIRS) was flown as a Detailed Test Objective on STS-95. On-orbit, the LIRS imparted an adverse taste to the water due to the presence of trialkylamines that had not been detected during development and certification testing. A post-flight investigation revealed that the trialkylamines were released during gamma sterilization of the LIRS resin materials.

A sorption-spectrophotometric platform for the concentration and subsequent quantification of biocides in spacecraft drinking water is described. This methodology, termed Colorimetric Solid Phase Extraction (C-SPE), is based on the extraction of analytes onto a membrane impregnated with a colorimetric reagent. Quantification of the extracted analytes is accomplished by interrogating the surface of the membrane with a commercially available diffuse reflectance spectrophotometer. Ground-based experiments have shown that C-SPE is a viable means to determine biocide concentrations in the range commonly found in water samples from the Space Shuttle and the International Space Station (ISS). This paper details efforts to advance C-SPE closer to space flight qualification and ISS implementation, starting with the modification of the ground based biocide detection platform to simplify operation in a microgravity environment.

The water supply for the International Space Station (ISS) consists partially of excess fuel-cell water that is treated on the Shuttle and stored on ISS in 44 L collapsible Contingency Water Containers (CWCs). Iodine is removed from the source water, and silver biocide and mineral concentrates are added by the crewmember while the CWCs are filled. Potable (mineralized) CWCs are earmarked for drinking and food hydration, and technical (non-mineralized) CWCs are reserved for waste system flushing and electrolytic oxygen generation. Representative samples are collected in Teflon® bags and returned to Earth for chemical analysis. The parameters typically measured include pH, conductivity, total organic carbon, iodine, silver, calcium, magnesium, fluoride, trace metals, formate and alcohols. The Nylon monomer caprolactam is also measured and tracked since it is known to leach slowly out of the plastic CWC bladder material.

The recovery of potable water from waste water produced by humans in regenerative life support systems is essential for success of long-duration space missions. The Lunar-Mars Life Support Test Project (LMLSTP) Phase II test was performed to validate candidate technologies to support these missions. The test was conducted in the Crew and Thermal Systems Division (CTSD) Life Support Systems Integration Facility (LSSIF) at Johnson Space Center (JSC). Discussed in this paper are the water recovery system (WRS) results of this test. A crew of 4-persons participated in the test and lived in the LSSIF chamber for a duration of 30-days from June 12 to July 12, 1996. The crew had accommodations for personal hygiene, the air was regenerated for reuse, and the waste water was processed to potable and hygiene quality for reuse by the crew during this period. The waste water consisted of shower, laundry, handwash, urine and humidity condensate.

Providing water necessary to maintain life support has been accomplished in spacecraft vehicles for over forty years. This paper will investigate how previous U.S. space vehicles provided potable water. The water source for the spacecraft, biocide used to preserve the water on-orbit, water stowage methodology, materials, pumping mechanisms, on-orbit water requirements, and water temperature requirements will be discussed. Where available, the hardware used to provide the water and the general function of that hardware will also be detailed. The Crew Exploration Vehicle (CEV or Orion) water systems will be generically discussed to provide a glimpse of how similar they are to water systems in previous vehicles. Conclusions, questions, and recommendations on strategies that could be applied to CEV based on previous spacecraft water system lessons learned will be made.

An integrated water recovery system was operated for 91 days in support of the Lunar Mars Life Support Test Project (LMLSTP) Phase III test. The system combined both biological and physical-chemical processes to treat a combined wastewater stream consisting of waste hygiene water, urine, and humidity condensate. Biological processes were used for primary degradation of organic material as well as for nitrification of ammonium in the wastewater. Physical-chemical systems removed inorganic salts from the water and provided post-treatment. The integrated system provided potable water to the crew throughout the test. This paper describes the water recovery system and reviews the performance of the system during the test.

Phase separation is one of the most significant obstacles encountered during the development of analytical methods for water quality monitoring in spacecraft environments. Removing air bubbles from water samples prior to analysis is a routine task on earth; however, in the absence of gravity, this routine task becomes extremely difficult. This paper details the development and initial ground testing of liquid metering centrifuge sticks (LMCS), devices designed to collect and meter a known volume of bubble-free water in microgravity. The LMCS uses centrifugal force to eliminate entrapped air and reproducibly meter liquid sample volumes for analysis with Colorimetric Solid Phase Extraction (C-SPE). Previous flight experiments conducted in microgravity conditions aboard the NASA KC-135 aircraft demonstrated that the inability to collect and meter a known volume of water using a syringe was a limiting factor in the accuracy of C-SPE measurements.

Regenerative-type subsystems are being tested at JSC to provide atmosphere revitalization functions of oxygen supply and carbon dioxide (CO2) removal for a future Space Station. Oxygen is supplied by an electrolysis subsystem, developed by General Electric, Wilmington, Mass., which uses the product water from either the CO2 reduction subsystem or a water reclamation process. CO2 is removed and concentrated by an electrochemical process, developed by Life Systems, Inc., Cleveland, Ohio. The concentrated CO2 is reduced in a Sabatier process with the hydrogen from the electrolysis process to water and methane. This subsystem is developed by Hamilton Standard, Windsor Locks, Conn. These subsystems are being integrated into an atmosphere revitalization group. This paper describes the integrated test configuration and the initial checkout test. The feasibility and design compatibility of these subsystems integrated into an air revitalization system is discussed.

This paper provides an overview of the IMMWPS Integrated Ground Test Program, completed at the NASA Johnson Space Center (JSC) during October and November 2001. The JSC Crew and Thermal Systems Division (CTSD) has developed the IMMWPS orbital flight experiment to test the feasibility of a microbe-based water purifier for use in zero-gravity conditions. The IMMWPS design utilizes a Microbial Processor Assembly (MPA) inoculated with facultative anaerobes to convert organic contaminants in wastewater to carbon dioxide and biomass. The primary purpose of the ground test program was to verify functional operations and procedures. A secondary objective was to provide initial ground data for later comparison to on-orbit performance. This paper provides a description of the overall test program, including the test article hardware and the test sequence performed to simulate the anticipated space flight test program. In addition, a summary of significant results from the testing is provided.

Collapsible bladder tanks called Contingency Water Containers (CWCs) have been used to transfer water from the Shuttle to the Mir and the International Space Station (ISS). Because their use as potable water storage on the ISS is planned for years, efforts are underway to improve the containers, including the evaluation of new materials. Combitherm®, a multi-layer plastic film, is a material under evaluation for use as the CWC bag material. It consists of layers of linear low density polyethylene, ethylene-vinyl alcohol copolymer, nylon, and a solvent- free adhesive layer. Long term studies of the quality of water stored in Combitherm bladders indicate a gradual but steady increase in the total organic carbon value. This suggests a leaching or breakdown of an organic component of the Combitherm.

The International Space Station (ISS) drinking water supply consists of water recovered from humidity condensate, water transferred from Shuttle, and groundwater supplied from Russia. The water is dispensed from both the stored water dispensing system (SVO-ZV) and the condensate recovery system (SRV-K) galley. Teflon bags are used periodically to collect potable water samples, which are then transferred to Shuttle for return to Earth. The results from analyses of these samples are used to monitor the potability of the drinking water on board and evaluate the efficiency of the water recovery system. This report provides results from detailed analyses of samples of ISS recovered potable water, Shuttle-supplied water, and ground-supplied water taken during ISS Expeditions 4 and 5. During Expedition 4, processing of U.S. Lab condensate through the Russian condensate recovery system was initiated. Results indicate water recovered from both Service Module and U.S.

On the International Space Station (ISS), humidity condensate will be collected from the atmosphere and treated by multifiltration to produce potable water for use by the crews. Ground-based development tests have demonstrated that multifiltration beds filled with a series of ion-exchange resins and activated carbons can remove many inorganic and organic contaminants effectively from wastewaters. As a precursor to the use of this technology on the ISS, a demonstration of multifiltration treatment under microgravity conditions was undertaken. On the Space Shuttle, humidity condensate from cabin air is recovered in the atmosphere revitalization system, then stored and periodically vented to space vacuum. A Shuttle Condensate Adsorption Device (SCAD) containing sorbent materials similar to those planned for use on the ISS was developed and flown on STS-68 as a continuation of DSO 317, which was flown initially on STS-45 and STS-47.

Controlling microbial growth and biofilm formation in spacecraft water-distribution systems is necessary to protect the health of the crew. Methods to decontaminate the water system in flight may be needed to support long-term missions. We evaluated the ability of iodine and ozone to kill attached bacteria and remove biofilms formed on stainless steel coupons. The biofilms were developed by placing the coupons in a manifold attached to the effluent line of a simulated spacecraft water-distribution system. After biofilms were established, the coupons were removed and placed in a treatment manifold in a separate water treatment system where they were exposed to the chemical treatments for various periods. Disinfection efficiency over time was measured by counting the bacteria that could be recovered from the coupons using a sonication and plate count technique. Scanning electron microscopy was also used to determine whether the treatments actually removed the biofilm.

The work presented in this paper summarizes the early results of an integrated advanced water recovery system test conducted by the Crew and Thermal Systems Division (CTSD) at NASA-Johnson Space Center (JSC). The system design and the results of the first two months of operation are presented. The overall objective of this test is to demonstrate the capability of an integrated advanced water recovery system to produce potable quality water for at least six months. Each subsystem is designed for operation in microgravity. The primary treatment system consists of a biological system for organic carbon and ammonia removal. Dissolved solids are removed by reverse osmosis and air evaporation systems. Finally, ion exchange technology in combination with photolysis or photocatalysis is used for polishing of the effluent water stream. The wastewater stream consists of urine and urine flush water, hygiene wastewater and a simulated humidity condensate.

Biological water processors are currently being developed for application in microgravity environments. Work has been performed to develop a single-phase, gravity independent anoxic denitrification reactor for organic carbon removal [1]. As a follow on to this work it was necessary to develop a gravity independent nitrification reactor in order to provide sufficient nitrite and nitrate to the organic carbon oxidation reactor for the complete removal of organic carbon. One approach for providing the significant amounts of dissolved oxygen required for nitrification is to require the biological reactor design to process two-phase gas and liquid in micro-gravity. This paper addresses the design and test results overview for development of a tubular, two-phase, gravity independent nitrification biological water processor.

The purification of waste water is a critical element of any long-duration space mission. The Vapor Phase Catalytic Ammonia Removal (VPCAR) system offers the promise of a technology requiring low quantities of expendable material that is suitable for exploration missions. NASA has funded an effort to produce an engineering development unit specifically targeted for integration into the NASA Johnson Space Center's Integrated Human Exploration Mission Simulation Facility (INTEGRITY) formally known in part as the Bioregenerative Planetary Life Support Test Complex (Bio-Plex) and the Advanced Water Recovery System Development Facility. The system includes a Wiped-Film Rotating-Disk (WFRD) evaporator redesigned with micro-gravity operation enhancements, which evaporates wastewater and produces water vapor with only volatile components as contaminants. Volatile contaminants, including organics and ammonia, are oxidized in a catalytic reactor while they are in the vapor phase.

Colorimetric-solid phase extraction (C-SPE) is being developed as a method for in-flight monitoring of spacecraft water quality. C-SPE is based on measuring the change in the diffuse reflectance spectrum of indicator disks following exposure to a water sample. Previous microgravity testing has shown that air bubbles suspended in water samples can cause uncertainty in the volume of liquid passed through the disks, leading to errors in the determination of water quality parameter concentrations. We report here the results of a recent series of C-9 microgravity experiments designed to evaluate manual manipulation as a means to collect bubble-free water samples of specified volumes from water sample bags containing up to 47% air. The effectiveness of manual manipulation was verified by comparing the results from C-SPE analyses of silver(I) and iodine performed in-flight using samples collected and debubbled in microgravity to those performed on-ground using bubble-free samples.