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In a 2-year program sponsored by SJAC, an aqueous electroplating process using alkaline Zn-Ni with trivalent chromium post treatment is under evaluation for high strength steel for aircraft application as an alternative to cadmium. Commercial Zn-15%Ni rack/barrel plating solutions are basis for plating aircraft parts or fasteners. Brightener was reduced from the original formula to form porous plating that enables bake-out of hydrogen to avoid hydrogen embrittlement condition. Properties of the deposit, such as appearance, adhesion, un-scribed corrosion resistance, and galvanic corrosion resistance in contact with Al alloy, were evaluated. Coefficient of friction was compared with Cd plating by torque-tension measurements. Evaluation of the plating for scribed corrosion resistance, primer adhesion, etc. will continue in FY2007.

In recent truck applications, single-piece large-diameter propshafts, in lieu of two-piece propshafts, have become more prevalent to reduce cost and mass. These large-diameter props, however, amplify driveline radiated noise. The challenge presented is to optimize prop shaft modal tuning to achieve acceptable radiated noise levels. Historically, CAE methods and capabilities have not been able to accurately predict propshaft airborne noise making it impossible to cascade subsystem noise requirements needed to achieve desired vehicle level performance. As a result, late and costly changes can be needed to make a given vehicle commercially acceptable for N&V performance prior to launch. This paper will cover the development of a two-step CAE method to predict modal characteristics and airborne noise sensitivities of large-diameter single piece aluminum propshafts fitted with different liner treatments.

We have developed a revolutionary automotive catalyst that maintains high activity by the suppression of grain growth of precious metals. This catalyst contains Pd-perovskite crystal which has shown a capacity for self-regeneration of Pd in a cycle of solid solution and segregation in perovskite crystals [1, 2, 3, 4, 5 and 6]. We named this catalyst the “Intelligent Catalyst” and first commercialized it in the Japanese market in October 2002 [7, 8]. In this study, we investigated the activity of Pd at various temperatures to confirm that the self-regenerative mechanism worked well at low temperatures like those right after engine starting. We also examined the durability of perovskite structure at high temperatures and tested its catalytic activity after engine aging at high temperatures above 1000 °C up to 1100 °C. It is proved that the intelligent catalyst has both excellent activity and durability under practical conditions.

In an evaluation of crashworthiness for the cars made of aluminum alloys, the evaluation considering fracture phenomenon comes to be needed because conventional aluminum alloys have low fracture strain (10-20%). In case of the development of a B-Pillar made by die cast, if crack occurrence, furthermore, separation of a part can be estimated by using CAE in crashworthiness evaluations, we can reduce the number of prototype makings and the cost of development using expensive dies. Therefore, we performed crashworthiness evaluations by CAE using some sort of a damage & fracture material model. It is known as “Orthotropic damage & fracture model”.

The so-called Modified Martempering discussed in this work differs from the standard martempering by that the temperature of the quenching bath is below the Ms point. In spite of the fact the lower temperature increases the severity of quenching, this also usually avoids the bainite formation, and by this reason, it is possible to make a fair comparison between different processes, which result in different microstructures. The present study shows the results in terms of mechanical properties, impact resistance in special of a cold work tool steel class, after being heat treated by the isothermal modified martempering process, as well as a comparison with the conventional quenching and tempering process and the austempering as well.

It has been reported that engine oils containing magnesium detergents gel under special conditions. The authors have previously reported on the mechanism by which magnesium detergents form needle crystals, which is the main cause of the gelation[1]. For this article, the authors conducted tests in actual vehicles using several types of engine oils containing magnesium detergents, including oils for which gelation problems have been reported in the market. The gelation was reproduced, and the test oils were ranked by their propensity to gel. In addition, a laboratory test method was used in which water and CO2 were mixed into engine oil under controlled conditions, then left stored in a bottle for twenty days, after which the kinematic viscosity and the quantity of insolubles of the mixture were measured. The study demonstrated the correlation between the laboratory test method and the actual vehicle tests.

Quasi-static tensile properties of TRIP590 steels from three different manufacturers were investigated using digital image correlation (DIC). The focus was on the post-uniform elongation behavior which can be very different for steels of the same grade owing to different manufacturing processes. Miniature tensile specimens, cut at 0°, 45°, and 90° relative to the rolling direction, were strained to failure in an instrumented tensile stage. True stress-true strain curves were computed from digital strain gages superimposed on digital images captured from one gage section surface during tensile deformation. Microstructural phases in undeformed and fracture specimens were identified with optical microscopy using the color tint etching process. Fracture surface analyses conducted with scanning electron microscopy and energy dispersive spectroscopy were used to investigate microvoids and inclusions in all materials.

In order to achieve good adhesive properties, typical decorative plastic plating technology uses a chromic acid process that creates an anchor effect. Due to environmental concerns with hexavalent chromium, there is a need to find alternative processes. Pretreatment using highly concentrated ozonized water was investigated as a novel approach to achieving this goal. In the conventional chromic acid process, strong adhesion between plating membranes is achieved by roughing the ABS (acrylonitrile-butadiene-styrene) resin surface by approximately 1 um. On the other hand, the highly concentrated ozonized water process achieves good adhesion with a smooth resin by changing the resin from ABS to ASA (acrylate-styrene-acrylonitrile). It was discovered that the difference in this strength of adhesion was the difference in resin surface strength (existence of deterioration or otherwise).

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.

The main objective of this paper is to simulate the springback using combined kinematic/isotropic hardening model. Material parameters in the hardening model are identified by an inverse method. Three-point bending test is conducted on 6022-T4 aluminum sheet. Punch stroke, punch load, bending strain and bending angle are measured directly during the tests. Bending moments are then computed from these measured data. Bending moments are also calculated based on a constitutive model. Material parameters are identified by minimizing the normalized error between two bending moments. Micro genetic algorithm is used in the optimization procedure. Stress-strain curves is generated with the material parameters found in this way, which can be used with other plastic models. ABAQUS/Standard 5.8, which has the combined isotropic/kinematic hardening model, is used to simulate draw-bend of 6022-T4 series aluminum sheet. Absolute springback angles are predicted very accurately.

Replacing the metal car roof with conventional solar modules results in the increase of total car weight and change of center of mass, which is not preferable for car designing. Therefore, weight reduction is required for solar modules to be equipped on vehicles. Exchanging glass to plastic for the cover plate of solar module is one of the major approaches to reduce weight; however, load bearing property, impact resistance, thermal deformation, and weatherability become new challenges. In this paper a new solar module structure that weighs as light as conventional steel car roofs, resolving these challenges is proposed.

As the automobile industry is moving towards Electrical vehicles, it becomes very important to have low cost and robust solution to seal all the internal Battery sub systems. It’s a known fact that various IC engine Vehicles are already using Room temperature vulcanized rubber (RTV) for many metal and composite sealing interfaces. Nevertheless, it always needs a good structural design to have good sealing performance. For designing a robust RTV joint for composite structures, it becomes important to have standard RTV chamfers. Sometimes even with these standards, it becomes very costly in having warranty issues when we have weak structure around RTV chamfers. Any joint structure involves multiple design parameters which might impact the sealing performance. Some of the joint structural parameters should be well designed at the early phase of product development cycle, which otherwise will later add lot of cost in modifying the product with its integrated components.

We have tried to improve damping capacity of an aluminum alloy by means of dispersing ceramic particles (low damping SiC and high damping NdNbO4) of different sizes and volume fractions in the aluminum alloy by powder metallurgy. It is shown that the damping capacity is increased in every case accompanying an increase of Young's modulus. It is also shown that the intrinsic damping capacity of dispersed particles does not play a role in improving the damping capacity. The increase of the damping capacity seems to be attributed to dislocations breakaway, interaction of fine particles and dislocations, and relaxation of interface between ceramic particles and aluminum matrix.

In June 1997, the Vehicle Recycling Partnership (VRP) and the American Plastics Council (APC) asked MBA Polymers to conduct a study to determine the technical and economic feasibility of recovering metals and plastics from end-of-life radiator end caps (RECs). The VRP worked with the Institute of Scrap Recycling Industries (ISRI) to obtain samples of RECs from two metal recycling companies, SimsMetal America and Aaron Metals. MBA performed its standard Recyclability Assessment on the materials, which included a detailed density and material characterization study and an actual processing study using its pilot processing line. It was found that the polyamide from RECs could be recovered in reasonably high yield and purity using tight density separations. The recycling of the REC samples used for this study generated about 40% nonferrous metal, 19% mixed ferrous and nonferrous metal and about 20% polyamide flakes.

The details of Di-Air, a new NOx reduction system using continuous short pulse injections of hydrocarbons (HC) in front of a NOx storage and reduction (NSR) catalyst, have already been reported. This paper describes further studies into the deNOx mechanism, mainly from the standpoint of the contribution of HC and intermediates. In the process of a preliminary survey regarding HC oxidation behavior at the moment of injection, it was found that HC have unique advantages as a reductant. The addition of HC lead to the reduction or metallization of platinum group metals (PGM) while keeping the overall gas atmosphere in a lean state due to adsorbed HC. This causes local O₂ inhibition and generates reductive intermediate species such as R-NCO. Therefore, the specific benefits of HC were analyzed from the viewpoints of 1) the impact on the PGM state, 2) the characterization of intermediate species, and 3) Di-Air performance compared to other reductants.

The Auto/Steel Partnership Corrosion Project Team has completed a perforation corrosion test program consisting of on-vehicle field exposures and various accelerated tests. Steel sheet products with eight combinations of metallic and organic coatings were tested, utilizing a simple crevice coupon design. On-vehicle exposures were conducted in St. John's and Detroit for up to seven years to establish a real-world performance standard. Identical test specimens were exposed to the various accelerated tests, and the results were compared to the real-world standard. This report documents the results of these tests, and compares the accelerated test results (including SAE J2334, GM9540P, Ford APGE, CCT-I, ASTM B117, South Florida Modified Volvo, and Kure Beach (25-meter) exposures) to the on-vehicle tests. The results are compared in terms of five criteria: extent of corrosion, rank order of material performance, degree of correlation, acceleration factor, and control of test environment.

The International Lubricant Standardization and Approval Committee (ILSAC) ATF subcommittee members have compared the two oxidation bench test methods, Aluminum Beaker Oxidation Test (ABOT) and Indiana Stirring Oxidation Stability Test (ISOT), using a number of factory-fill and service-fill ATFs obtained in Japan and in the US. In many cases, the ATFs were more severely oxidized after the ABOT procedure than after the same duration of the ISOT procedure. The relative severity of these two tests was influenced by the composition of the ATFs. The bench test oxidation data were compared with the transmission and the vehicle oxidation test data.

This paper discusses the recent growth in aluminum wheel popularity and the problems associated with maintaining the wheel's appearance and corrosion protection. The various options in wheel coatings are then described as well as the adverse wheel environment. Finally, the variables affecting wheel corrosion resistance are explained and the testing that is undertaken to evaluate the performance characteristics of the wheel coating.

In an effort to reduce mass, future automotive bodies will feature lower gage steel or lighter weight materials such as aluminum. An unfortunate side effect of lighter weight bodies is a reduction in sound transmission loss (TL). For barrier based systems, as the total system mass (including the sheet metal, decoupler, and barrier) goes down the transmission loss is reduced. If the reduced surface density from the sheet metal is added to the barrier, however, performance can be restored (though, of course, this eliminates the mass savings). In fact, if all of the saved mass from the sheet metal is added to the barrier, the TL performance may be improved over the original system. This is because the optimum performance for a barrier based system is achieved when the sheet metal and the barrier have equal surface densities. That is not the case for standard steel constructions where the surface density of the sheet metal is higher than the barrier.