Search Results

From the viewpoint of primary energy diversification and CO2 reduction, interests of using Biomass Fuel are rising. Some kinds of FAME (Fatty Acid Methyl Ester), which are obtained from oil fats like vegetable oil using transesterification reaction with methanol, are getting Palm Oilpular for bio-diesel recently. In this study, we have conducted many experiments of palm oil hydrogenations using our pilot plants, and checked the reactivity and the pattern of product yields. As a result, we figured out that the hydrocarbon oil equivalent to the conventional diesel fuel can be obtained from vegetable oils in good yield under mild hydrogenation conditions. Moreover, as a result of various evaluations for the hydrogenated palm oil (oxidation stability, lowtemperature flow property, LCA, etc.), we found that the hydrogenated palm oil by our technology has performances almost equivalent to conventional diesel fuel.

High fuel efficiency and low emission technologies, such as Direct Injection (DI) gasoline and diesel engines and hybrid powertrains, have been developed to resolve environmental and energy resource issues. The hybrid powertrain system has achieved superior power performance as well as higher system efficiency and is expected to be a core powertrain technology because it is compatible with various power sources including fuel cells. It becomes important to control complicated hybrid systems that consist of not only a powertrain but also vehicle systems such as regenerative braking. Model-based control and calibration enables both control strategy optimization and control system development efficiency improvement.

Recently, global warming and energy security have received significant attention. Thus an improvement of the vehicle fuel economy is strongly required. For engines, one effective way is to improve the engine thermal efficiency. Raising compression ratio [1] or turbo charging technologies have potential to achieve high thermal efficiency. However knock does not allow the high thermal efficiency. Knock depends on the fuel composition and the pressure and temperature history of unburnt end-gas [2-3]. For fuels, RON is well known for describing the anti knock quality. High RON fuels have high anti knock quality and result in higher thermal efficiency. This paper investigates the impact of high RON fuels on the thermal efficiency by using high compression ratio engine, turbo charged engine, and lean boosted engine [4]. Finally, it is shown that the high thermal efficiency can be approached with high RON gasoline and ethanol.

In an effort to reduce CO2 emissions, governments are increasingly mandating the use of various levels of biofuels. While this is strongly supported in principle within the energy and transportation industries, the impact of these mandates on the transport stock’s CO2 emissions and overall operating efficiency has yet to be fully explored. This paper provides information on studies to assess biodiesel influences and effects on engine performance, driveability, emissions and fuel consumption on state-of-the-art Euro IV compliant Toyota Avensis D4-D vehicles with DPNR aftertreatment systems. Two fuel matrices (Phases 1 & 2) were designed to look at the impact of fuel composition on vehicle operation using a wide range of critical parameters such as cetane number, density, distillation and biofuel (FAME) level and type, which can be found within the current global range of Diesel fuel qualities.

Since ethanol is a renewable source of energy and it contributes to lower CO2 emissions, ethanol produced from biomass is expected to increase in use as an alternative fuel. It is recognized that for spark ignition (SI) engines ethanol has advantages of high octane number and high combustion speed and has a disadvantage of difficult startability at low temperature. This paper investigates the influence of ethanol fuel on SI engine performance, thermal efficiency, and emissions. The combustion characteristics under cold engine conditions are also examined. Ethanol has high anti-knock quality due to its high octane number, and high latent heat of evaporation, which decreases the compressed gas temperature during the compression stroke. In addition to the effect of latent heat of evaporation, the difference of combustion products compared with gasoline further decreases combustion temperature, thereby reducing cooling heat loss.

For viscous couplings(VCs) as a driving force transmission system of vehicles, requirement of torque characteristics has been getting very stringent. Because the torque characteristics significantly affect four wheel drive vehicles' abilities such as traction performance and driving stability. Furthermore, the recent concerns on high fuel economy, low pollution and low cost require that design of VCs should be increasingly compact, light weighted and excellent in transmitted torque's stability. It is an easy way to increase viscosity of viscous coupling fluids(VCFs) for the compact design of the VC. But it might cause increase in heat load and wear of plates which resulted in degradation of the VCF. The degradation affects VCF's viscosity and impairs stability in torque transmission. Therefore it is indispensable to develop high viscosity VCF which is excellent in long-term viscosity's stability.

In recent years, automakers have been developing various types of environmentally friendly vehicles such as hybrid (HV), plug-in hybrid (PHV), electric (EV), and fuel cell (FCV) vehicles to help reduce greenhouse gas (GHG) emissions. However, there are few commercial solar vehicles on the market. One of the reasons why automakers have not focused attention on this area is because the benefits of installing solar modules on vehicles under real conditions are unclear. There are two difficulties in measuring the benefits of installing solar modules on vehicles: (1) vehicles travel under various conditions of sunlight exposure and (2) sunlight exposure conditions differ in each region. To address these problems, an analysis was performed based on an internet survey of 5,000 people and publically available meteorological data from 48 observation stations in Japan.

The key challenge in designing a high power density fuel cell is to reduce oxygen transport loss due to liquid water. However, liquid water transport from catalyst layers to channels under operating conditions is not completely understood. Toyota developed a high resolution space and time liquid water visualization technique using synchrotron x-ray (Spring-8) radiography. In addition, a simulation method was created based on computational fluid dynamics (CFD) to identify the cell performance relationship to water distribution. The relationship among gas diffusion layer (GDL) parameters, water distribution, and fuel cell performance was clarified by combining the techniques Toyota developed.

Polymer electrolyte membrane fuel cell (PEFC) systems for fuel cell vehicles (FCVs) require both performance and durability. Carbon is the typical support material used for PEFC catalysts. However, hydrogen starvation at the anode causes high electrode potential states (e.g., 1.3 V with respect to the reversible hydrogen electrode) that result in severe carbon support corrosion. Serious damage to the carbon support due to hydrogen starvation can lead to irreversible performance loss in PEFC systems. To avoid such high electrode potentials, FCV PEFC systems often utilize cell voltage monitor systems (CVMs) that are expensive to use and install. Simplifying PEFC systems by removing these CVMs would help reduce costs, which is a vital part of popularizing FCVs. However, one precondition for removing CVMs is the adoption of a durable support material to replace carbon.

In order to determine the main factors causing the mileage-related increase in formaldehyde emission from methanol-fueled vehicles, mileage was accumulated on three types of vehicle, each of which had a different air-fuel calibration system. From exhaust emission data obtained during and after the mileage accumulation, it was found that lean burn operation resulted in by far the highest formaldehyde emission increase. An investigation into the reason for the rise in engine-out formaldehyde emission revealed that deposits in the combustion chamber emanating from the lubricating oil promotes formaldehyde formation. Furthermore it was learnt that an increase in engine-out NOx emissions promotes partial oxidation of unburned methanol in the catalyst, leading to a significant increase in catalyst-out formaldehyde emission.

The development of an alternative oxygen reduction electrocatalyst to platinum based electrocatalysts is critical for practical use of the polymer electrolyte membrane fuel cell (PEMFC). Transition metal sulfide chalcogenides have recently been reported as a possible candidate for Pt replacement. Our work focused on chalcogenides composed of ruthenium, molybdenum, and sulfur (RuMoS). We elucidate the factors affecting electrocatalytic activity of carbon supported RuXMoY SZ catalyst. This was demonstrated through a correlation of oxygen reduction reaction (ORR) activity of the catalysts with structural changes resulting from designed changes in sulfur composition in the catalysts.

In the 1st generation Toyota "MIRAI" fuel cell stack, carbon protective surface coating is deposited after individual Ti bipolar plate being press-formed into the desired shape. Such a process has relatively low production speed, not ideal for large scale manufacturing. A new coating concept, consisting of a nanostructured composite layer of titanium oxide and carbon particles, was devised to enable the incorporation of both the surface treatment and the press processes into the roll-to-roll production line. The initial coating showed higher than expected contact resistance, of which the root cause was identified as nitrogen contamination during the annealing step that inhibited the formation of the composite film structure. Upon the implementation of a vacuum furnace chamber as the countermeasure, the issue was resolved, and the improved coating could meet all the requirements of productivity, conductivity, and durability for use in the newer generation of fuel cell stacks.

For over a decade and a half, Toyota Motor Corporation has been developing fuel cell vehicles (FCVs) and is continuing various approaches to enable mass production. This study used new methods to quantitatively observe some of the mass transfer phenomena in the reaction field, such as oxygen transport, water drainage, and electronic conductivity. The obtained results are applicable to the design requirements of ideal reaction fields, and have the potential to assist to reduce the size of the fuel cell.

Current and future engine technologies and fuels are mutually dependent. The increased use of alternative fuels has been linked to deterioration in performance of injectors, fuel filters and engines as a result of insoluble deposit formation. The present work aimed to study the impact of Diesel/biodiesel blends formulation (biodiesel feedstock and content) and temperature on the oxidation stability based on total acid number (TAN). The biofuels used in the fuel matrix were: rapeseed, soy and palm methyl esters (RME, SME and PME respectively). The Diesel/biodiesel blends were made with 0%v/v, 5%v/v, 10% v/v and 20%v/v of biodiesel blended with additive-free new Diesel. The oxidation stability of Diesel/biodiesel blends was to evaluate during 6 months fuels storage, under 20°C and 40°C, and fuels severe oxidation into a reactor vessel to better understand the parameters leading to fuel oxidation on-board.

Two types of new conceptual lead free overlays are developed for automotive internal combustion(IC) engine bearings. The overlays are consisted of molybdenum disulfide(MoS2) and polyamideimide(PAI) resin for binding. One of the overlays is suitable for diesel engines with higher unit load and the other overlay is suitable for gasoline engines with higher sliding velocity. Both overlays indicate good corrosion resistance and wear resistance comparing with conventional lead base overlay. Moreover, higher fatigue resistance is obtained in combination with high performance lead free bearing alloy. These new bearings have the potential to become alternative materials to conventional copper lead bearings with lead base overlay.

Torque loss reduction at differential gear unit is important to improve the fuel economy of automobiles. One effective way is to decrease the viscosity of lubricants as it results in less churning loss. However, this option creates a higher potential for thin oil films, which could damage the mechanical parts. At tapered roller bearings, in particular, wear at the large end face of rollers and its counterpart, known as bearing bottom wear is one of major failure modes. To understand the wear mechanism, wear at the rolling contact surface of rollers and its counterpart, known as bearing side wear, was also observed to confirm the wear impact on the tapered roller bearings. Because gear oils are also required to avoid seizure under extreme pressure, the combination of a phosphorus anti-wear agent and a sulfurous extreme pressure agent are formulated.

Fluoroelastmers are well known for their resistance to heat and fluids, and have become major material for crankcase oil seals. On the other hand, new additive formulations are developed for engine lubricants used for fuel economic gasoline engines. In this paper, the effects of those additives on properties of fluoroelastmers are investigated. The results of the immersion tests of both test plaques and oil seal products indicate that dithiocarbamates, friction modifier, have hardening effects on fluoroelastmers. The fluoroelastmer deterioration mechanism is determined by analysis of elastmer samples after immersion in oil.

To evaluate the influence of FAME, which has poor oxidation stability, on engine oil performance, an engine test was conducted under large volumes of fuel dilution by post-injection. The test showed that detergent consumption and polymerization of FAME were accelerated in engine oil, causing a severe deterioration in piston cleanliness and sludge protection performance of engine oil.

Electrode catalyst (platinum) degradation represents a major challenge to the performance and durability of polymer electrolyte membrane fuel cells (PEMFCs) in Fuel Cell Vehicles (FCVs). While various mechanisms have been proposed and investigated previously, there is still a need to develop in situ imaging techniques that can characterize and provide direct evidence to confirm the degradation process. In the present study, we report an in situ transmission electron microscopy (TEM) method that enables real time, high-resolution observation of carbon-supported platinum nanoparticles in liquid electrolyte under working conditions. By improving the design of the Micro Electro Mechanical Systems (MEMS) sample holder, the migration and aggregation of neighboring platinum nanoparticles could be visualized consistently and correlated to applied electrode potentials during aging process (i.e., cyclic voltammetry cycles).

In this report, adhesion mechanism between epoxy resin and primer and between primer and Ni platting in Hybrid vehicle (HV) was investigated. Adhesion forces are thought to be a combination of mechanical bond forces (such as anchor effect), chemical bond forces and physical bond forces (such as hydrogen bonding and Van der Waals force). Currently there is insufficient understanding of the adhesion mechanism. In particular, the extent to which the three bond forces contribute to adhesion strength. So the adhesion mechanism of polyimide primers was analyzed using a number of different methods, including transmission electron microscope (TEM) and atomic force microscope (AFM) observation, to determine the contributions of the three bonding forces. Molecular simulation was also used to investigate the relationship between adhesion strength and the molecular structure of the primer.