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Since the mid 1980s, NASA has developed advanced waste management technologies that collect and process waste. These technologies include incineration, hydrothermal oxidation, pyrolysis, electrochemical oxidation, activated carbon production, brine dewatering, slurry bioreactor oxidation, composting, NOx control, compaction, and waste collection. Some of these technologies recover resources such as water, oxygen, nitrogen, carbon dioxide, carbon, fuels, and nutrients. Other technologies such as the Waste Collection System (WCS - the commode) collect waste for storage or processing. The need for waste processing varies greatly depending upon the mission scenario. This paper reviews the waste management technology development activities conducted by NASA since the mid 1980s and explores the drivers that determine the application of these technologies to future missions.

Activated carbons have a unique capability of strongly absorbing a great variety of species, ranging from SO2 and NOx, to trace organics, mercury, and other heavy metals. Activated carbons can also be used for gas storage and gas separations, including systems of practical interest to NASA (e.g., CO2/N2/O2), and even for the purification of liquids. No single activated carbon is suitable for all applications, but appreciable control over sorbent properties can be exercised in the process of carbon preparation. Since activated carbons can be produced from a wide range of organic materials, including waste streams, the preparation of activated carbons on board spacecraft should involve a limited amount of additional resources, help manage on-board waste, and reduce the weight of materials to be launched from earth. The feasibility of producing waste-derived activated carbons suitable for SO2 and NO control was the subject of the current study.

Previous research has shown that the homogeneous charge compression ignition (HCCI) combustion concept holds promise for reducing pollutants (i.e. NOx, soot) while maintaining high thermal efficiency. However, it can be difficult to control the operation of the HCCI engines even under steady state running conditions. Power density may also be limited if high inlet air temperatures are used for achieving ignition. A methodology using a small pilot quantity of diesel fuel injected during the compression stroke to improve the power density and operation control is considered in this paper. Multidimensional computations were carried out for an HCCI engine based on a CAT3401 engine. The computations show that the required initial temperature for ignition is reduced by about 70 K for the cases of the diesel pilot charge and a 25∼35% percent increase in power density was found for those cases without adversely impacting the NOx emissions.

Fundamental understanding of the sources of fuel-derived Unburned Hydrocarbon (UHC) emissions in heavy duty diesel engines is a key piece of knowledge that impacts engine combustion system development. Current emissions regulations for hydrocarbons can be difficult to meet in-cylinder and thus after treatment technologies such as oxidation catalysts are typically used, which can be costly. In this work, Computational Fluid Dynamics (CFD) simulations are combined with engine experiments in an effort to build an understanding of hydrocarbon sources. In the experiments, the combustion system design was varied through injector style, injector rate shape, combustion chamber geometry, and calibration, to study the impact on UHC emissions from mixing-controlled diesel combustion.

We have developed top-level crop models for analysis of Advanced Life Support (ALS) systems that use plants to grow food. The crops modeled are candidates for ALS use: bean (dry), lettuce, peanut, potato (white), rice, soybean, sweet potato, tomato, and wheat. The crop models are modified versions of the energy cascade crop growth model originally developed for wheat by Volk, Bugbee, and Wheeler. The models now simulate the effects of temperature, carbon dioxide level, planting density, and relative humidity on canopy gas exchange, in addition to the effects of light level and photoperiod included in the original model. The energy cascade model has also been extended to predict the times of canopy closure, grain setting (senescence), and maturity (harvest) as functions of the environmental conditions.

The effects of thermal and chemical aging on the performance of cordierite-based and high-porosity mullite-based diesel particulate filters (DPFs), were quantified, particularly their filtration efficiency, pressure drop, and regeneration capability. Both catalyzed and uncatalyzed core-size samples were tested in the lab using a diesel fuel burner and a chemical reactor. The diesel fuel burner generated carbonaceous particulate matter with a pre-specified particle-size distribution, which was loaded in the DPF cores. As the particulate loading evolved, measurements were made for the filtration efficiency and pressure drop across the filter using, respectively, a Scanning Mobility Particle Sizer (SMPS) and a pressure transducer. In a subsequent process and on a different bench system, the regeneration capability was tested by measuring the concentration of CO plus CO2 evolved during the controlled oxidation of the carbonaceous species previously deposited on the DPF samples.

Although soot-formation processes in diesel engines have been well characterized during the mixing-controlled burn, little is known about the distribution of soot throughout the combustion chamber after the end of appreciable heat release during the expansion and exhaust strokes. Hence, the laser-induced incandescence (LII) diagnostic was developed to visualize the distribution of soot within an optically accessible single-cylinder direct-injection diesel engine during this period. The developed LII diagnostic is semi-quantitative; i.e., if certain conditions (listed in the Appendix) are true, it accurately captures spatial and temporal trends in the in-cylinder soot field. The diagnostic features a vertically oriented and vertically propagating laser sheet that can be translated across the combustion chamber, where “vertical” refers to a direction parallel to the axis of the cylinder bore.

Mandated pollutant emission levels are shifting light-duty vehicles towards hybrid and electric powertrains. Heavy-duty applications, on the other hand, will continue to rely on internal combustion engines for the foreseeable future. Hence there remain clear environmental and economic reasons to further decrease IC engine emissions. Turbocharged diesels are the mainstay prime mover for heavy-duty vehicles and industrial machines, and transient performance is integral to maximizing productivity, while minimizing work cycle fuel consumption and CO2 emissions. 1D engine simulation tools are commonplace for “virtual” performance development, saving time and cost, and enabling product and emissions legislation cycles to be met. A known limitation however, is the predictive capability of the turbocharger turbine sub-model in these tools.

China has become the world’s largest vehicle market in terms of sales volume. Automobiles sales keep growing in recent years despite the declining economic growth rate. Due to the increasing attention given to the environmental impact, more stringent emission regulations are being drafted to control traditional internal combustion engine emissions. In order to reduce vehicle emissions, environmentally-friendly new-energy vehicles, such as electric vehicles and plug-in hybrid vehicles, are being promoted by government policies. The Chinese government plans to boost sales of new-energy cars to account for about five percent of China’s total vehicle sales. It is well known that more electric and electronic components will be integrated into a vehicle platform during vehicle electrification.

Fuel properties impact the engine-out emission directly. For some geographic regions where diesel engines can meet emission regulations without aftertreatment, the change of fuel properties will lead to final tailpipe emission variation. Aftertreatment systems such as Diesel Particulate Filter (DPF) and Selective Catalytic Reduction (SCR) are required for diesel engines to meet stringent regulations. These regulations include off-road Tier 4 Final emission regulations in the USA or the corresponding Stage IV emission regulations in Europe. As an engine with an aftertreatment system, the change of fuel properties will also affect the system conversion efficiency and regeneration cycle. Previous research works focus on prediction of engine-out emission, and many are based on chemical reactions. Due to the complex mixing, pyrolysis and reaction process in heterogeneous combustion, it is not cost-effective to find a general model to predict emission shifting due to fuel variation.

The General Purpose Work Station (GPWS) is a laboratory multi-use facility, as demonstrated during the Spacelab Life Sciences 1 (SLS-1) flight. The unit provided particulate containment under varying conditions, served as an effective work space for manipulating live animals, e.g., rats, served as a containment facility for fixatives, and was proposed for use to conduct in-flight maintenance during connector pin repair. The cabinet has a front door large enough to allow installation of a full-size microscope in-flight and is outfitted with a side window to allow delivery of items into the cabinet without exposure to the spacelab atmosphere. Additional support subsystems include inside cabinet mounting, surgical glove fine manipulations capability, and alternating or direct current power supply for experiment equipment, as will be demonstrated during Spacelab J.

To ensure that adequate water resources are available during a mission, any net water loss from the habitat must be balanced with an equivalent amount of makeup water. For a Mars transit mission, the primary sources of makeup water will likely involve water contained in shipped tanks and in prepackaged food. As mission length increases, it becomes more cost effective to increase system water closure (recovery and generation) than to launch adequate amounts of contained water. This trend may encourage designers to specify increased water recovery in lieu of higher food moisture content. However, food palatability requirements will likely declare that prepackaged foods have a minimum hydration (averaged over all food types). The food hydration requirement may even increase with mission duration. However, availability requirements for specific emergency scenarios may declare that determined quantities of water be provided in tanks, rather than as moisture in food.

NASA and the FAA conducted two flight campaigns to quantify onboard weather radar measurements with in-situ measurements of high concentrations of ice crystals found in deep convective storms. The ultimate goal of this research was to improve the understanding of high ice water content (HIWC) and develop onboard weather radar processing techniques to detect regions of HIWC ahead of an aircraft to enable tactical avoidance of the potentially hazardous conditions. Both HIWC RADAR campaigns utilized the NASA DC-8 Airborne Science Laboratory equipped with a Honeywell RDR-4000 weather radar and in-situ microphysical instruments to characterize the ice crystal clouds. The purpose of this paper is to summarize how these campaigns were conducted and highlight key results. The first campaign was conducted in August 2015 with a base of operations in Ft. Lauderdale, Florida.

A steady-state system mass balance calculation was performed to investigate design issues regarding the storage and/or processing of solid waste. In the initial stages of BIO-Plex, only a certain percentage of the food requirement will be satisfied through crop growth. Since some food will be supplied to the system, an equivalent amount of waste will accumulate somewhere in the system. It is a system design choice as to where the mass should accumulate in the system. Here we consider two approaches. One is to let solid waste accumulate in order to reduce the amount of material processing that is needed. The second is to process all of the solid waste to reduce solid waste storage and then either resupply oxygen or add physical/chemical (P/C) processors to recover oxygen from the excess carbon dioxide and water that is produced by the solid waste processor.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

Gasoline particulate filters (GPFs) are devices used to filter soot emitted by gasoline direct injection (GDI) engines. A numerical model for a ceria-coated GPF presented in a previous paper by H. Arunachalam et al. in 2017 was developed to predict internal temperature and soot amount combusted during regeneration events. Being that both the internal temperature and the accumulated soot cannot be directly measured during real-time operation and owing to their critical importance for GPF health monitoring as well as regeneration scheduling, the above model turns out to be a valuable tool for OBD applications. In this paper, we first conduct a stochastic analysis to understand the relation between the model parameters and the initial value of the ceria (IV) oxide volume fraction, as a deterministic value for such a state is not known.

For high-load applications, natural gas represents a clean burning, readily available, and relatively inexpensive alternative to number 2 Diesel fuel. However, the fuel’s poor ignitability has previously limited implementation to spark ignited and dual-fueled engines. These approaches suffer from reduced peak load and high engine-out particulate emissions, respectively, requiring lean operation and expensive aftertreatment to meet regulatory standards. A high-temperature combustion strategy can overcome the difficult ignitibility, allowing for true Diesel-style combustion of pure methane-the least ignitable and least sooting component of natural gas. In order to achieve this result, a compression system was designed to supply fuel at pressures suitably high to achieve good mixing and short injection durations, and a solenoid-actuated Diesel fuel injector was modified to function at these pressures with a gaseous fuel.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

Diesel engine downsizing aimed at reducing fuel consumption while meeting stringent exhaust emissions regulations is currently in high demand. The boost system architecture plays an essential role in providing adequate air flow rate for diesel fuel combustion while avoiding impaired transient response of the downsized engine. Electric Turbocharger Assist (ETA) technology integrates an electric motor/generator with the turbocharger to provide electrical power to assist compressor work or to electrically recover excess turbine power. Additionally, a variable geometry turbine (VGT) is able to bring an extra degree of freedom for the boost system optimization. The electrically-assisted turbocharger, coupled with VGT, provides an illuminating opportunity to increase the diesel engine power density and enhance the downsized engine transient response. This paper assesses the potential benefits of the electrically-assisted turbocharger with VGT to enable heavy-duty diesel engine downsizing.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.