Search Results

Nitrites have long been added to heavy-duty coolant to inhibit iron cylinder liner corrosion initiated by cavitation. However, in heavy-duty use, nitrites deplete from the coolant, which then must be refortified using supplemental coolant additives (SCA's). Recently, carboxylates have also been found to provide excellent cylinder liner protection in heavy-duty application. Unlike nitrites, carboxylate inhibitors deplete slowly and thus do not require continual refortification with SCA's. In the present paper laboratory aging experiments shed light on the mechanism of cylinder liner protection by these inhibitors. The performance of carboxylates, nitrites and mixtures of the two inhibitors are compared. Results correlate well with previously published fleet data. Specifically, rapid nitrite and slow carboxylate depletion are observed. More importantly, when nitrite and carboxylates are used in combination, nitrite depletion is repressed while carboxylates deplete at a very slow rate.

Extensive vehicle fleet testing has demonstrated that use of MMT can reduce net tailpipe out emissions. The use of fuel containing the octane-enhancing, emission-reducing fuel additive leads to manganese oxide deposits in the vehicle exhaust system. Studies of the physical and chemical effects of manganese oxide deposits on the performance of catalytic converters conclusively demonstrated that MMT does not adversely affect catalytic converters and, in fact, protected the converters from phosphorus and zinc. Despite the overwhelming evidence that MMT is compatible with catalytic converters and vehicle emission control systems, concerns have recently been raised about the effect of manganese oxides on OBD-II catalytic converter monitoring.

There has been an ongoing interest in replacing mineral oil with more biodegradable and/or fire-resistant hydraulic fluids in many mobile equipment applications. Although many alternative fluids may be more biodegradable, or fire-resistant, or both than mineral oil, they often suffer from other limitations such as poorer wear, oxidative stability, and yellow metal corrosion which inhibit their performance in high-pressure hydraulic systems, particularly high pressure piston pump applications. From the fluid supplier's viewpoint, the development of a definitive test, or series of tests, that provides sufficient information to determine how a given fluid would perform with various hydraulic components would be of interest because it would minimize extensive testing. This is often too slow or prohibitively expensive. Furthermore, from OEM's (original equipment manufacturer's) point of view, it would be advantageous to develop a more effective, industry accepted fluid analysis screening.

A slipstream of exhaust from a Caterpillar 3126B engine was diverted into a plasma-catalytic NOx control system in the space velocity range of 7,000 to 100,000 hr-1. The stream was first fed through a non-thermal plasma that was formed in a coaxial cylinder dielectric barrier discharge reactor. Plasma treated gas was then passed over a catalyst bed held at constant temperature in the range of 573 to 773 K. Catalysts examined consisted of γ-alumina, indium-doped γ-alumina, and silver-doped γ-alumina. Road and rated load conditions resulted in engine out NOx levels of 250 - 600 ppm. The effects of hydrocarbon level, catalyst temperature, and space velocity are discussed where propene and in one case ultra-low sulfur diesel fuel (late cycle injection) were the reducing agents used for NOx reduction. Results showed NOx reduction in the range of 25 - 97% depending on engine operating conditions and management of the catalyst and slipstream conditions.

Various gold catalysts were prepared using commercial and in-house fabricated advanced catalyst supports that included mesoporous silica, mesoporous alumina, sol-gel alumina, and transition metal oxides. Gold nanoparticles were loaded on the supports by co-precipitation, deposition-precipitation, ion exchange and surface functionalization techniques. The average gold particle size was ∼20nm or less. The oxidation activity of the prepared catalysts was studied using carbon monoxide and light hydrocarbons (ethylene, propylene and propane) in presence of water and CO2 and the results are presented.

This paper describes two independent studies on γ-alumina as a plasma-activated catalyst. γ-alumina (2.5 - 4.3 wt%) was coated onto the surface of mesoporous silica to determine the importance of aluminum surface coordination on NOx conversion in conjunction with nonthermal plasma. Results indicate that the presence of 5- and 6- fold aluminum coordination sites in γ-alumina could be a significant factor in the NOx reduction process. A second study examined the effect of changing the reducing agent on NOx conversion. Several hydrocarbons were examined including propene, propane, isooctane, methanol, and acetaldehyde. It is demonstrated that methanol was the most effective reducing agent of those tested for a plasma-facilitated reaction over γ-alumina.

NOx reduction efficiency in simulated lean exhaust conditions has been examined for three proprietary catalyst materials using a non-thermal plasma discharge as a pretreatment stage to the catalyst. Using propene as the reducing agent for selective catalytic reduction, 74% reduction of NOx has been observed in the presence of 20 ppm SO2. For sulfur-free simulated exhaust, 84% NOx reduction has been obtained. Results show that the impact of sulfur on the samples examined can vary widely from virtually no effect (< 5%) to more than 20% loss in activity depending on the catalyst. Any loss due to sulfur poisoning appears to be irreversible according to limited measurements on poisoned catalysts exposed to sulfur-free exhaust streams. Catalysts were tested over a temperature range of 473-773K, with the highest activity observed at 773K. Examination of this large temperature window has shown that the optimum C1:NOx ratio changes with temperature.

The hybrid vehicle engines modified for high exhaust gas recirculation (EGR) is a good choice for high efficiency and low NOx emissions. However, high EGR will dilute the engine charge and may cause serious performance problems, such as incomplete combustion, torque fluctuation, and engine misfire. An efficient way to overcome these drawbacks is to intensify tumble leading to increased turbulent intensity at the time of ignition. The enhancement of turbulent intensity will increase flame velocity and improve combustion quality, therefore increasing engine tolerance to higher EGR. To achieve the goal of increasing tolerance to EGR, this work reports a CFD investigation of high tumble intake port design using STAR-CD. The validations had been performed through the comparison with PIV experimental tests.

A number of oxidation catalysts have been prepared using different types of advanced support materials such as ceria-zirconia, silica-titania, spinels and perovskites. Active metals such as Pd and Au-Pd were loaded by conventional impregnation techniques and/or deposition-precipitation methods. A liquid hydrocarbon delivery system was designed and implemented for the catalyst test benches in order to simulate the diesel engine exhaust environment. The activity of fresh (no degreening) catalysts was evaluated with traditional CO and light hydrocarbons (C2H4, C3H6) as well as with heavy hydrocarbons such as C10 H22.

A two-zone NOx model intended for 1-D engine simulations was developed and used to model NOx emissions from a 2.5 L single-cylinder engine. The intent of the present work is to understand key aspects of a simple NOx model that are needed for predictive accuracy, including NOx formation and destruction phenomena in a DI Diesel combustion system. The presented two-zone model is fundamentally based on the heat release rate and thermodynamic incylinder data, and uses the Extended Zeldovich mechanism to model NO. Results show that the model responded very well to changes in speed, load, injection timing, and EGR level. It matched measured tail pipe NOx levels within 20%, using a single tuning setup. When the model was applied to varied injection rate shapes, it showed correct sensitivity to speed, load, injection timing, and EGR level, but the absolute level was well outside the target accuracy. The same limitation was seen when applying the Plee NOx model.

It is estimated that operating continuously on a B20 fuel containing the current allowable ASTM specification limits for metal impurities in biodiesel could result in a doubling of ash exposure relative to lube-oil-derived ash. The purpose of this study was to determine if a fuel containing metals at the ASTM limits could cause adverse impacts on the performance and durability of diesel emission control systems. An accelerated durability test method was developed to determine the potential impact of these biodiesel impurities. The test program included engine testing with multiple DPF substrate types as well as DOC and SCR catalysts. The results showed no significant degradation in the thermo-mechanical properties of cordierite, aluminum titanate, or silicon carbide DPFs after exposure to 150,000 mile equivalent biodiesel ash and thermal aging. However, exposure of a cordierite DPF to 435,000 mile equivalent aging resulted in a 69% decrease in the thermal shock resistance parameter.

Field testing of an extended life coolant technology in Class 8 trucks, equipped with Caterpillar C-12 engines revealed excellent coolant life with negligible inhibitor depletion to 400,000 miles with no refortification and no coolant top-off. In separate evaluations in Caterpillar 3406E equipped trucks, extended corrosion protection and component durability were established out to 700,000 miles, without the need for refortification other than top-off.

This paper describes a method for accurately measuring sulfur oxides in automotive exhaust. In this method, the exhaust from a car is diluted with ambient air, then introduced into a large bag filled with clean dry air. The temperature, pressure, and humidity of the diluted exhaust are measured, along with the concentrations of hydrocarbons, carbon monoxide, carbon dioxide, SO2, and sulfates. Bag concentrations are related to the exhaust by using the sulfur/carbon ratio of the fuel. Established instrumental methods are used for the carbon compounds. The sulfur dioxide in the diluted exhaust gas is measured by the West-Gaeke method, which involves collecting a gaseous sample in a scrubber containing potassium tetrachloromecurate. The sulfates are collected on a particulate filter and measured by a new colorimetric method. The techniques we have developed have been applied to both non-catalyst and catalyst-equipped cars. These studies have shown that: 1.

The Clean Air Act of 1990 requires on-board diagnostics (OED) capabilities on all new vehicles. These diagnostic systems monitor the performance of engine and emission system components and inform the vehicle operator when component or system degradation could significantly impact emissions. Acceptable operation of the monitor requires proper treatment of system variables. Fuel composition is one of many possible variables that must be considered for monitoring components directly in the exhaust stream. Recently, the octane enhancing, emissions reducing additive methylcyclopentadienyl manganese tricarbonyl (MMT) was reintroduced into unleaded gasoline in the U.S. Prior to reintroduction, the additive underwent extensive testing to demonstrate that use of MMT does not adversely affect vehicle emissions or the operation of emission systems such as OBD. However, questions have been raised about the influence of the additive on OBD systems.

Emissions regulations for 2007 will likely require engine manufacturers to use a diesel particulate filter (DPF) to meet particulate matter (PM) emission requirements. With the lower operating temperatures of light-duty diesel engines, some form of catalyst will be required to facilitate oxidation of accumulated soot PM to regenerate the DPF. This catalyst can either be permanently applied to the filter substrate in the manufacturing process, or be continuously delivered via the diesel fuel. In this study we examined the impact of using both forms of catalyst. A recently published study of the fuel-borne catalyst additive MMT [1] (Methylcyclopentadienyl Manganese Tricarbonyl), reviewed the performance of MMT in conjunction with an uncatalyzed DPF [2].

Homogeneous charge compression ignition (HCCI) offers the potential for significant improvements in efficiency with a substantial reduction in emissions. However, achieving heavy-duty (HD) HCCI engine operation at practical loads and speeds presents numerous technical challenges. Successful expansion of the HCCI operating range to include the full range of load and speed must be accomplished while maintaining proper combustion phasing, control of maximum cylinder pressure and pressure rise rates, and low emissions of NOx and particulate matter (PM). Significant progress in this endeavour has been made through a collaborative research effort between Caterpillar and ExxonMobil. This paper evaluates fuel effects on HCCI engine operating range and emissions. Test fuels were developed in the gasoline and diesel boiling range covering a broad range of ignition quality, fuel chemistry, and volatility.

Ducted fuel injection (DFI) is a developing technology for reducing in-cylinder soot formed during mixing-controlled combustion in diesel compression ignition engines. Fuel injection through a small duct has the effect of extending the lift-off length (LOL) and reducing the equivalence ratio at ignition. In this work, the feasibility of DFI to reduce soot and to enable leaner lifted-flame combustion (LLFC) is investigated for a single diesel jet injected from a 138 μm orifice into engine-like (60-120 bar, 800-950 K) quiescent conditions. High-speed imaging and natural luminosity (NL) measurements of combusting sprays were used to quantify duct effects on jet penetration, ignition delay, LOL, and soot emission in a constant pressure high-temperature-pressure vessel (HTPV). At the highest ambient pressure and temperatures tested, soot luminosity was reduced by as much as 50%.

Automotive gear oil development has expanded beyond the historical requirements of emphasizing wear protection to encompass modern needs for fuel economy and limited slip frictional properties. This paper describes the development process of a new generation, fuel efficient gear lubricant for use in light duty vehicles. A systematic formulation approach was used, encompassing fluid viscometrics and additive optimization. Performance testing in both laboratory and vehicle tests is described. Though standard GL-5 tests were used to confirm oxidation, wear and corrosion performance, emphasis is given to those methods used for optimizing fuel economy.

Engine electrification is a critical technology in the promotion of engine fuel efficiency, among which the electrified turbocharger is regarded as the promising solution in engine downsizing. By installing electrical devices on the turbocharger, the excess energy can be captured, stored, and re-used. The electrified turbocharger consists of a variable geometry turbocharger (VGT) and an electric motor (EM) within the turbocharger bearing housing, where the EM is capable in bi-directional power transfer. The VGT, EM, and exhaust gas recirculation (EGR) valve all impact the dynamics of air path. In this paper, the dynamics in an electrified turbocharged diesel engine (ETDE), especially the couplings between different loops in the air path is analyzed. Furthermore, an explicit principle in selecting control variables is proposed. Based on the analysis, a model-based multi-input multi-output (MIMO) decoupling controller is designed to regulate the air path dynamics.

In designing fuel economy oils, two useful approaches are reduction of viscosity and incorporation of friction reducers. To achieve viscosity reduction without incurring problems of high oil consumption and possible interference with catalyst or oxygen sensor performance, the use of part-synthetic lubricants can be helpful. In this way, oil volatility (therefore oil consumption) is reduced and fuel economy is improved without incurring engine operating penalties. Friction reducers also can be used to improve fuel economy. The combination of these approaches furnishes the benefits of both. Laboratory and road testing of such combinations show important fuel economy benefits in normal vehicle operation, greater than those achievable from either approach alone. In addition, all other engine performance requirements are completely met. This advance in engine oil formulation technology, which opens up new possibilities to both vehicle manufacturers and consumers, is being further pursued.