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Nitrites have long been added to heavy-duty coolant to inhibit iron cylinder liner corrosion initiated by cavitation. However, in heavy-duty use, nitrites deplete from the coolant, which then must be refortified using supplemental coolant additives (SCA's). Recently, carboxylates have also been found to provide excellent cylinder liner protection in heavy-duty application. Unlike nitrites, carboxylate inhibitors deplete slowly and thus do not require continual refortification with SCA's. In the present paper laboratory aging experiments shed light on the mechanism of cylinder liner protection by these inhibitors. The performance of carboxylates, nitrites and mixtures of the two inhibitors are compared. Results correlate well with previously published fleet data. Specifically, rapid nitrite and slow carboxylate depletion are observed. More importantly, when nitrite and carboxylates are used in combination, nitrite depletion is repressed while carboxylates deplete at a very slow rate.

It has been shown that the addition of a small amount of nanoparticles into a fluid results in anomalous increase in the thermal conductivity of the mixture, and the resulting nanofluid may provide better overall thermal management and better lubrication in many applications, such as heat transfer fluids, engine oils, transmission fluids, gear oils, coolants and other similar fluids and lubricants. The potential benefits of this technology to the automotive and related industries would be more efficient engines, reduced size and weight of the cooling and propulsion systems, lowered operating temperature of the mechanical systems, and increased life of the engine and other mechanical systems. The new mechanisms for this phenomenon of anomalous thermal conductivity increase have been proposed. The heat transfer properties of a series of graphite nanofluids were presented, and the experimental results were compared with the conventional heat transfer theory for pure liquids.

Silicate-free, carboxylate based technology as typified by Texaco Extended Life Coolant (TELC) and Caterpillar Extended Life Coolant (ELC), both meeting Caterpillar's EC-1 Coolant Specification, offer excellent corrosion protection for commercial lead solders commonly used in the fabrication of copper/brass radiators and heater cores throughout the trucking industry. Results of laboratory testing using solders from commercial radiators manufacturers and extensive field coolant analysis compare extended life technology with the popular conventional coolant technologies. In the laboratory, the effect of coolant concentration on solder protection is explored using the glassware corrosion test, ASTM D-1384. At concentrations ranging from 33% up to 75% the carboxylate technology offers comparable to superior protection when compared to the popular heavy-duty conventional coolant containing silicates and phosphates.

Coolant formulations based on organic acid corrosion inhibitor technology have been tested in over 180 heavy duty engines for a total of more than 50 million kilometers. This testing has been used to document long life coolant performance in various engine types from four major engine manufacturers. Inspections of engines using organic acid based coolant (with no supplemental coolant additive) for up to 610,000 kilometers showed excellent protection of metal engine components. Improved protection was observed against cylinder liner, water pump, and aluminum spacer deck corrosion. In addition, data accumulated from this testing were used to develop depletion rate curves for long life coolant corrosion inhibitors, including tolyltriazole and nitrite. Nitrite was observed to deplete less rapidly in long life coolants than in conventional formulations.

Field testing of an extended life coolant technology in Class 8 trucks, equipped with Caterpillar C-12 engines revealed excellent coolant life with negligible inhibitor depletion to 400,000 miles with no refortification and no coolant top-off. In separate evaluations in Caterpillar 3406E equipped trucks, extended corrosion protection and component durability were established out to 700,000 miles, without the need for refortification other than top-off.

The high temperature and high neutron flux environment of a thermionic space power reactor presents a challenge in the design of the sheath insulator within a thermionic fuel element. The present alumina insulator design is suspect to degradation due to the neutron flux. The alumina insulator also requires a barrier coating to isolate it from the liquid alkali metal coolant. Although the alumina sheath development is progressing, the alumina insulator remains a potential point of significant performance loss in the thermionic fuel element. The recent successes in depositing polycrystalline diamond film onto cylindrical refractory metal substrates has led to the consideration of diamond as a potentially ideal sheath insulator. Investigations have been conducted into the durability of diamond thin film under exposure to simulated thermionic reactor conditions.

Evaluations of the liner pitting protection performance provided by engine coolant corrosion inhibitors and supplemental coolant additives have presented many problems. Current practice involves the use of full scale engine tests to show that engine coolant inhibitors provide sufficient liner pitting protection. These are too time-consuming and expensive to use as the basis for industry-wide specifications. Ultrasonic vibratory test rigs have been used for screening purposes in individual labs, but these have suffered from poor reproducibility and insufficient additive differentiation. A new test procedure has been developed that reduces these problems. The new procedure compares candidate formulations against a good and bad reference fluid to reduce the concern for problems with calibration and equipment variability. Cast iron test coupons with well-defined microstructure and processing requirements significantly reduce test variability.