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There are many sources of air pollution that can threaten air quality during space missions. The International Space Station (ISS) is an extremely complex platform that depends on a multi-tiered strategy to control the risk of excessive air pollution. During the seven missions surveyed by this report, the ISS atmosphere was in a safe, steady-state condition; however, there were minor loads added as new modules were attached. There was a series of leaks of octafluoropropane, which is not directly toxic to humans, but did cause changes in air purification operations that disrupted the steady state condition. In addition, off-nominal regeneration of metal oxide canisters used during extravehicular activity caused a serious pollution incident.

Hamilton Sundstrand has developed a scalable evaporative heat rejection system called the Multi-Fluid Evaporator (MFE). It was designed to support the Orion Crew Module and to support future Constellation missions. The MFE would be used from Earth sea level conditions to the vacuum of space. This system combines the functions of the Space Shuttle flash evaporator and ammonia boiler into a single compact package with improved freeze-up protection. The heat exchanger core is designed so that radial flow of the evaporant provides increasing surface area to keep the back pressure low. The multiple layer construction of the core allows for efficient scale up to the desired heat rejection rate. A full-scale unit uses multiple core sections that, combined with a novel control scheme, manage the risk of freezing the heat exchanger cores. A four-core MFE prototype was built in 2007.

Hamilton Sundstrand is under contract with the NASA Johnson Space Center to develop a scalable, evaporative heat rejection system called the Multi-Fluid Evaporator (MFE). It is being designed to support the Orion Crew Module and to support future Constellation missions. A MFE would be used from Earth sea level conditions to the vacuum of space. The current Space Shuttle configuration utilizes an ammonia boiler and flash evaporator system to achieve cooling at all altitudes. With the MFE system, both functions are combined into a single compact package with significant weight reduction and improved freeze-up protection. The heat exchanger core is designed so that radial flow of the evaporant provides increasing cross-sectional area to keep the back pressure low. Its multiple layer construction allows for efficient scale up to the desired heat rejection rate.

During an ExtraVehicular Activity (EVA), both the heat generated by the astronaut's metabolism and that produced by the Portable Life Support System (PLSS) must be rejected to space. The heat sources include the heat of adsorption of metabolic CO2, the heat of condensation of water, the heat removed from the body by the liquid cooling garment and the load from the electrical components. Although the sublimator hardware to reject this load weighs only 1.58 kg (3.48 lbm), an additional 3.6 kg (8 lbm) of water are loaded into the unit, most of which is sublimated and lost to space, thus becoming the single largest expendable during an eight-hour EVA. Using a radiator to reject heat from the astronaut during an EVA can reduce the amount of expendable water consumed in the sublimator. Last year we reported on the design and initial operational assessment tests of a novel radiator designated the Radiator And Freeze Tolerant heat eXchanger (RAFT-X).

During extravehicular activities (EVAs) it is crucial to keep the astronaut comfortable. Currently, a sublimator rejects to space both the astronaut's metabolic heat and that produced by the Portable Life Support System. In doing so, it consumes up to 3.6 kg (8 lbm) of water; the single largest expendable during an eight-hour EVA. While acceptable for low earth orbit, resupply for moon and interplanetary missions will be too costly. Fortunately, the amount of water consumed can be greatly reduced if most of the heat load is radiated to space. However, the radiator must reject heat at the same rate that it is generated to prevent heat stroke or frostbite. Herein, we report on a freezable radiator and heat exchanger to proportionally control the heat rejection rate.

We have conducted experiments on 16 lunar soils and 3 lunar volcanic glass samples to study the extraction of oxygen, an important resource for future lunar bases. The samples were chosen to span the range of composition and mineralogy represented in the Apollo collection. Each sample was reduced in flowing hydrogen for 3 hours at 1050°C. The dominant effect was reduction of Fe2+ (as FeO) in minerals and glass to iron metal, with concomitant release of oxygen. Oxygen extraction was strongly correlated with initial Fe2+ abundance but varied among mineral and glass phases. The experimental reduction of lunar soil and glass provides a method for assessing the oxygen production potential for sites on the lunar surface from lunar orbit. Our results show that oxygen yield from lunar soils can be predicted from knowledge of only one parameter, total iron content. This parameter can be measured from orbit by gamma ray spectrometry or multispectral imaging.

NASA's Constellation Program includes the Orion, Altair, and Lunar Surface Systems (LSS) project offices. The first two elements, Orion and Altair, are manned space vehicles while the third element is broader and includes several subelements including Rovers and a Lunar Habitat. The upcoming planned missions involving these systems and vehicles include several risks and design challenges. Due to the unique thermal environment, many of these risks and challenges are associated with the vehicles' thermal control system. NASA's Exploration Systems Mission Directorate (ESMD) includes the Exploration Technology Development Program (ETDP). ETDP consists of several technology development projects. The project chartered with mitigating the aforementioned risks and design challenges is the Thermal Control System Development for Exploration Project.

A system performance study on a portable life support system being developed for use in the Weightless Environment Training Facility (WETF) and the Neutral Buoyancy Laboratory (NBL) has been completed. The Neutral Buoyancy Portable Life Support System (NBPLSS) will provide life support to suited astronauts training for extravehicular activity (EVA) under water without the use of umbilicals. The basic configuration is characterized by the use of medium pressure (200 - 300 psi) cryogen (liquid nitrogen/oxygen mixture) which provides cooling within the Extravehicular Mobility Unit (EMU), the momentum which enables flow in the vent loop, and oxygen for breathing. NBPLSS performance was analyzed by using a modified Metabolic Man program to compare competing configurations. Maximum sustainable steady state metabolic rates and transient performance based on a typical WETF metabolic rate profile were determined and compared.

Shortly after installation of the service and performance heat exchanger (SPCU HX) in 2001, samples collected from the coolant fluid indicated the presence of nickel accompanied by a subsequent decrease in phosphate concentration along with a high microbial load. When the SPCU HX was replaced and evaluated post-flight, it was expected that the heat exchanger would have significant biofilm and corrosion present given the composition of the coolant fluid; however, there was no evidence of either. Early results from two experiments imply that the heat exchanger materials themselves are inhibiting biofilm formation. This paper discusses the results of one set of experiments and puts forward the inhibition of quorum sensing as a possible mechanism for the lack of biofilm formation.

Controlling microbial growth and biofilm formation in spacecraft water-distribution systems is necessary to protect the health of the crew. Methods to decontaminate the water system in flight may be needed to support long-term missions. We evaluated the ability of iodine and ozone to kill attached bacteria and remove biofilms formed on stainless steel coupons. The biofilms were developed by placing the coupons in a manifold attached to the effluent line of a simulated spacecraft water-distribution system. After biofilms were established, the coupons were removed and placed in a treatment manifold in a separate water treatment system where they were exposed to the chemical treatments for various periods. Disinfection efficiency over time was measured by counting the bacteria that could be recovered from the coupons using a sonication and plate count technique. Scanning electron microscopy was also used to determine whether the treatments actually removed the biofilm.

An evaporative heat sink has been designed and built by AlliedSignal for NASA's Johnson Space Center. The unit is a demonstrator of a primary heat exchanger for NASA's prototype Crew Return Vehicle (CRV), designated the X-38. The primary heat exchanger is responsible for rejecting the heat produced by both the flight crew and the avionics. Spacecraft evaporative heat sinks utilize space vacuum as a resource to control the vapor pressure of a liquid. For the X-38, water has been chosen as the heat transport fluid. A portion of this coolant flow is bled off for use as the evaporant. At sufficiently low pressures, the water can be made to boil at temperatures approaching its freezing point. Heat transferred to liquid water in this state will cause the liquid to evaporate, thus creating a heat sink for the spacecraft's coolant loop. The CRV mission requires the heat exchanger to be compact and low in mass.

Metabolically produced carbon dioxide (CO2) removal in spacesuit applications has traditionally been accomplished utilizing non-regenerative Lithium Hydroxide (LiOH) canisters. In recent years, regenerative Metal Oxide (MetOx) has been developed to replace the Extravehicular Mobility Unity (EMU) LiOH canister for extravehicular activity (EVA) missions in micro-gravity, however, MetOx may carry a significant weight burden for potential use in future Lunar or planetary EVA exploration missions. Additionally, both of these methods of CO2 removal have a finite capacity sized for the particular mission profile. Metabolically produced water vapor removal in spacesuits has historically been accomplished by a condensing heat exchanger within the ventilation process loop of the suit life support system.

During the period July 2001 to March 2002, the performance of a water-jacketed high intensity discharge lamp of advanced design was evaluated within a lamp test stand at The University of Arizona (UA), Controlled Environment Agriculture Center (CEAC) in Tucson, Arizona. The lamps and test stand system were developed by Mr. Phil Sadler of Sadler Machine Company, Tempe, Arizona, and supported by a Space Act Agreement between NASA-Johnson Space Center (JSC) and UA. The purpose was for long term testing of the prototype lamp and demonstration of an improved procedure for use of water-jacketed lamps for plant production within the close confines of controlled environment facilities envisioned by NASA within Bioregenerative Life Support Systems. The lamp test stand consisted of six, 400 watt water-cooled, high pressure sodium HID lamps, mounted within a framework.

The Space Shuttle humidity separator prefilter was developed to remove debris from the air/water stream that flows from the cabin condensing heat exchanger to the humidity separator. Debris in this flow stream has caused humidity separator pitot tube clogging and subsequent water carryover on several Shuttle flights. The first design concept of the prefilter was flown on STS-40 in June, 1991. The prefilter was installed on-orbit. Video footage of its operation revealed that the prefilter did not pass water at a constant rate, resulting in a tendency to slug the humidity separator. The results from this flight test have resulted in a complete redesign of the prefilter. In this paper the first prefilter design is described, the flight results from STS-40 are examined, and the on-orbit performance of the prefilter is explained. The redesigned prefilter is described with emphasis on the features that should allow successful reduced gravity operation.

Approximately 50% of the water consumed by International Space Station crewmembers is water recovered from cabin humidity condensate. Condensing heat exchangers in the Russian Service Module (SM) and the United States On-Orbit Segment (USOS) are used to control cabin humidity levels. In the SM, humidity condensate flows directly from the heat exchanger to a water recovery system. In the USOS, a metal bellows tank located in the US Laboratory Module (LAB) collects and stores condensate, which is periodically off-loaded in about 20-liter batches to Contingency Water Containers (CWCs). The CWCs can then be transferred to the SM and connected to a Condensate Feed Unit that pumps the condensate from the CWCs into the water recovery system for processing. Samples of the condensate in the tank are collected during the off-loads and returned to Earth for analyses.

Two simulated spacecraft water systems are being used to evaluate the effectiveness of iodine for controlling microbial contamination within such systems. An iodine concentration of about 2.0 mg/L is maintained in one system by passing ultrapure water through an iodinated ion exchange resin. Stainless steel coupons with electropolished and mechanically-polished sides are being used to monitor biofilm formation. Results after three years of operation show a single episode of significant bacterial growth in the iodinated system when the iodine level dropped to 1.9 mg/L. This growth was apparently controlled by replacing the iodinated ion exchange resin, thereby increasing the iodine level. The second batch of resin has remained effective in controlling microbial growth down to an iodine level of 1.0 mg/L. Scanning electron microscopy indicates that the iodine has impeded but may have not completely eliminated the formation of biofilm.

Recent efforts have been pursued to establish the usefulness of Space Shuttle Orbiter lithium hydroxide (LiOH) canisters beyond their certified two-year shelf life, at which time they are currently considered “expired.” A stockpile of Orbiter LiOH canisters are stowed on the International Space Station (ISS) as a backup system for maintaining ISS carbon dioxide Canisters with older (CO2) control. Canister with older pack dates must routinely be replaced with newly packed canisters off-loaded from the Orbiter Middeck. Since conservation of upmass is critical for every mission, the minimization of canister swap-out rate is paramount. LiOH samples from canisters with expired dates that had been returned from the ISS were tested for CO2 removal performance at the NASA Johnson Space Center (JSC) Crew and Thermal Systems Division (CTSD). Through this test series and subsequent analysis, performance degradation was established.

During an ExtraVehicular Activity (EVA), both the heat generated by the astronaut's metabolism and that produced by the Portable Life Support System (PLSS) must be rejected to space. The heat sources include the heat of adsorption of metabolic CO2, the heat of condensation of water, the heat removed from the body by the liquid cooling garment, the load from the electrical components and incident radiation. Although the sublimator hardware to reject this load weighs only 1.58 kg (3.48 lbm), an additional 3.6 kg (8 lbm) of water are loaded into the unit, most of which is sublimated and lost to space, thus becoming the single largest expendable during an eight-hour EVA. Using a radiator to reject heat from the astronaut during an EVA can reduce the amount of expendable water consumed in the sublimator. Radiators have no moving parts and are thus simple and highly reliable. However, past freezable radiators have been too heavy.