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Knock-limited engine operation is one of the most important constraints on fuel efficiency and performance that must be considered during the design, control algorithm development and calibration of spark-ignition engines. This research evaluates the accuracy of model-based knock prediction routines and their applicability for control-oriented applications over various engine operating conditions using commercial fuels. Two common methods of knock prediction, a generalized chemical kinetics model and an empirical induction-time correlation, are evaluated and compared against experimental data. The experimental investigation is conducted using a naturally aspirated 3.6L V6 engine, retrofitted with cooled Exhaust Gas Recirculation (EGR). Data are acquired from spark timing sweeps under knocking conditions at different engine speeds and loads in an engine dynamometer cell.