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The destruction of low concentrations (<600 ppm) of nitric oxide using a low-temperature, dielectric barrier/packed-bed corona reactor has been studied. We compare the chemistry and energy efficiencies observed using various packing materials in warm moist air under oxidative (lean-burn) conditions. Measurements of NO and NOx removal in the effluent gas were made as a function of energy dissipated in the reactor. Changes in the observed fate of NO as a function of the packing material are discussed.

The hole stretchability of two Aluminum Alloys (AA6111 and AA6022) are studied by using a two stages integrated finite element framework where the edge geometry and edge damages from the hole piercing processes were considered in the subsequent hole expansion processes. Experimentally it has been found that AA6022 has higher hole expansion ratios than those of AA6111. This observation has been nicely captured by finite element simulations. The main cause of differences have been identified to the volume fractions of the random distributed second phase hard particles which play a critical role in determining the fracture strains of the materials.

Automobile body and truck cab structures are composed primarily of stampings formed from monolithic and constant gage blanks. Cost and weight penalties can arise when strength or other requirements in one small area of the part leads to the use of a material or gage that is overmatched to the needs of the rest of the stamping. Tailor Welded Blanks (TWBs) are hybrid sheet products composed of either different materials or different thickness sheets that are joined together, then subjected to a stamping operation to create a formed assembly. The strategy is employed generally to save weight and material costs in the formed assembly by placing higher strength or thicker sections only where needed. The forming or stamping process requires the joint to be severely deformed along with the parent sheets. Aluminum TWBs for automotive applications are particularly problematic because of the low formability of aluminum weld metal.

The bending fatigue performance of high temperature (1050 °C) vacuum carburized Nb modified 8620 steel, with niobium additions of 0.02, 0.06 and 0.1 wt pct, was evaluated utilizing a modified Brugger specimen geometry. Samples were heated at two different rates (20 and 114 °C min-1) to the carburizing temperature resulting in different prior austenite grain structures that depended on the specific Nb addition and heating rate employed. At the lower heating rate, uniform fine grained prior austenite grain structures developed in the 0.06 and 0.1 Nb steels while a duplex grain structure with the presence of large (>200 μm grains) developed in the 0.02 Nb steel. At the higher heating rate the propensity for abnormal grain growth was highest in the 0.02 Nb steel and complete suppression of abnormal grain growth was achieved only with the 0.1 Nb steel.

The effect of hydroforming on the mechanical properties and dynamic crush behaviors of tapered aluminum 6063-T4 tubes with octagonal cross section are investigated by experiments. First, the thickness profile of the hydroformed tube is measured by non-destructive examination technique using ultrasonic thickness gauge. The effect of hydroforming on the mechanical properties of the tube is investigated by quasi-static tensile tests of specimens prepared from different regions of the tube based on the thickness profile. The effect of hydroforming on the dynamic crush behaviors of the tube is investigated by axial crush tests under dynamic loads. Specimens and tubes are tested in two different heat treatment conditions: hydroformed-T4 (as-received) and T6. The results of the quasi-static tensile tests for the specimens in hydroformed-T4 condition show different amounts of work hardening depending on the regions, which the specimens are prepared from.

In stamping advanced high strength steels (AHSS), the deviations from desired part geometry caused by springback from a radius, curl, twist, and bow are major impediments to successfully producing AHSS parts. In general, the conventional elastic modulus is used to quantify the strain that occurs on unloading. This unloading strain causes deviations from desired part geometry. Considerable evidence in the literature indicates that for tensile testing, the conventional elastic modulus does not accurately describe the unloading strain. The present study uses new data and results from the literature to examine the average slope of tensile stress strain curves on unloading. This slope is termed the effective unloading modulus. The results from this study quantitatively describe how the effective unloading modulus decreases with increasing strength, prestrain, and unloading time.

High strain rate sheet tensile tests (up to 300s-1) and Ohio State University (OSU) formability tests (up to an estimated strain rate of 10s-1) were performed to examine the effect of strain rate on the mechanical properties and formability of five ferritic stainless steels: HIGH PERFORMANCE-10™ 409 (HP-10 409), ULTRA FORM® 409 (UF 409), HIGH PERFORMANCE-10™ 439 (HP-10 439), two thicknesses of 18 Cr-Cb™ stainless steel, all supplied by AK Steel, and Duracorr®, a ferrite-tempered martensite dual-phase stainless steel supplied by Bethlehem Steel Corporation. Tensile results show that increasing strain rate resulted in increases in yield stress, flow stress, and stress at instability for all alloys tested. In addition, increases in uniform and total elongation were also found for each of the five alloys.

The effects of austenite grain size on the bending fatigue crack initiation and fatigue performance of gas carburized, modified 4320 steels were studied. The steels were identical in composition except for phosphorus concentration which ranged between 0.005 and 0.031 wt%. Following the carburizing cycle, specimens were subjected to single and triple reheat treatments of 820°C for 30 minutes to refine the austenite grain structure, and oil quenched and tempered at 150°C. Specimens subjected to bending fatigue were characterized by light metallography to determine microstructure and grain size, X-ray analysis for retained austenite and residual stress measurements, and scanning electron microscopy for examination of fatigue crack initiation and propagation. The surface austenite grain size ranged from 15 μm in the as-carburized condition to 6 and 4 μm diameter grain size for the single and triple reheat conditions, respectively.

Forging simulations with a 1522 steel microalloyed by additions of 0.25% Mo, 0.13% V and 0.01% Ti were performed on a laboratory thermomechanical processing simulator. The forging conditions included a strain rate of 22s-1, 50% strain, and temperatures in the range from 1200°C to 950°C. The true stress was found to increase with decreasing deformation temperature for all values of instantaneous true strain. The maximum flow stress increased two-fold as deformation temperature decreased from 1200°C to 950°C, and the recrystallized austenite grain size decreased by a factor of two for this same decrease in temperature. Microstructures evolve from bainitic/ferritic at a cooling rate of 1.4°C/s, to fully martensitic at 16.8°C/s, independent of deformation temperature. Room temperature hardnesses depended primarily on cooling rate and were essentially independent of deformation temperature.

With the increased use of tubular steel products, especially for automotive hydroforming applications, there is increased interest in understanding the mechanical properties measured by tensile tests from specimens of different orientations in the tube. In this study, two orientations of tensile specimens were evaluated -- axial specimens with and without flattening and flattened circumferential specimens. Three steels were evaluated -- two thicknesses of aluminum killed drawing quality (AKDQ) steel and one thickness of high strength low alloy (HSLA) steel. Mechanical property data were obtained from the flat stock, conventional production tubes and quasi tubes. Quasi tubes were produced from the flat stock on a 3-roll bender, but the quasi tube was not welded or sized.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

We developed a non-destructive and non-contact method for measuring stress at the mid-plane of tempered glass plates that uses Bragg scattering from a pair of thermal gratings. These gratings are formed by 1064 nm beams from a seeded Nd:YAG laser and we measure the polarization state of light from a 532 nm beam that scatters from both these thermal gratings. The change in polarization of the doubly scattered light with separation between the two gratings allows measurement of the in-plane stress. Stress measurements are reported.

Knowledge of the net thinning strain that occurs in a sheet as it is bent over a single radius is an important component in understanding sheet metal formability. The present study extends the initial work of Swift on thinning during plane-strain bending to sheet steels with power law stress-strain behavior and with the inclusion of friction. The experimental data come from studies on the enhanced forming limit curve on DQSK steel and analysis of the curl behavior of 590R and DP600 steels. Results for single radius bending from these studies are used in the present investigation. It has been found that the amount of net thinning strain depends on back tension, initial plane-strain yield strength, and the maximum true bending strain calculated for the neutral plane at the mid-thickness of the sheet.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.

The influences of laboratory-induced hydrogen on the tensile deformation and fracture behavior of selected sheet steels including conventional DQSK and HSLA steels as well as newer DP and TRIP grades were evaluated. The effects of cold work, simulated paint baking, and natural aging were considered. Hydrogen effects were observable by increased flow stress, decreased ductility, altered neck geometry, and altered fracture mechanisms. Differences among the steels and conditions were observed and interpreted on the basis of microstructure, fracture behavior, and theories of hydrogen embrittlement.

A noticeable degree of inconsistent forming behaviors has been observed for the 1st generation advanced high strength steels (AHSS) in production, and they appear to be associated with the inherent microstructural-level inhomogeneities for various AHSS. This indicates that the basic material property requirements and screening methods currently used for the mild steels and high strength low alloys (HSLA) are no longer sufficient for qualifying today's AHSS. In order to establish more relevant material acceptance criteria for AHSS, the fundamental understandings on key mechanical properties and microstructural features influencing the local formability of AHSS need to be developed. For this purpose, in this study, DP980 was selected as model steels and eight different types of DP980 sheet steels were acquired from various steel suppliers.

This paper describes a method for predicting structural failure probabilities for automotive windshields. The predictive model is supported by the data from strength tests performed on specimens of automotive glass. Evaluations of stresses can be based on finite element calculations, or measurements of the residual stresses that arise from fabrication. Failure probabilities for each subregion of a windshield are estimated from the local state of stress, the surface area or length (for edge elements) of the subregion, and statistical distributions of glass strengths. Example calculations are presented that show the relative contributions of edge stresses, surface stresses and residual stresses to calculated failure probabilities.

Drawbeads in production stamping dies often have insufficient penetration of the male bead into the female cavity. With insufficient penetration, the actual bending radii of the sheet metal are larger than the geometrical radii of the drawbead. The actual bending radii in the sheet directly affect the force that restrains sheet movement. To predict the restraining stress due to a drawbead, it is necessary to know the actual bending radii in the sheet as it passes though the drawbead. Data from a previous study are used to develop empirical regression equations for predicting measured radii of the sheet that is bent around the radii in a drawbead. A physical model for the evolution of the sheet radii as the drawbead closes is proposed. This model is consistent with the empirical equations and the mechanics of the sheet bending process.

In this paper, a three-dimensional (3D) microstructure-based finite element modeling method (i.e., extrinsic modeling method) is developed, which can be used in examining the effects of porosity on the ductility/fracture of Mg castings. For this purpose, AM60 Mg tensile samples were generated under high-pressure die-casting in a specially-designed mold. Before the tensile test, the samples were CT-scanned to obtain the pore distributions within the samples. 3D microstructure-based finite element models were then developed based on the obtained actual pore distributions of the gauge area. The input properties for the matrix material were determined by fitting the simulation result to the experimental result of a selected sample, and then used for all the other samples’ simulation. The results show that the ductility and fracture locations predicted from simulations agree well with the experimental results.