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The Internal Active Thermal Control System (IATCS) aboard the International Space Station (ISS) contains an aqueous, alkaline fluid (pH 9.5±0.5) that aids in maintaining a habitable environment for the crew. Because microbes have significant potential to cause disease, adverse effects on astronaut health, and microbe-induced corrosion, the presence of both bacteria and viruses within IATCS fluids is of concern. This study sought to detect and identify viral populations in IATCS samples obtained from the Kennedy Space Center as a first step towards characterizing and understanding potential risks associated with them. Samples were concentrated and viral nucleic acids (NA) extracted providing solutions containing 8.87-22.67 μg NA per mL of heat transfer fluid. After further amplification viral DNA and cDNA were then pooled, fluorescently labeled, and hybridized onto a Combimatrix panvira 12K microarray containing probes for ∼1,000 known human viruses.

To meet the challenge of future deep space programs an accurate and efficient engineering code for analyzing the shielding requirements against high-energy galactic heavy radiations is needed. Such engineering design codes require establishing validation processes using laboratory ion beams and space flight measurements in realistic geometries. In consequence, a new version of the HZETRN code capable of simulating HZE ions with either laboratory or space boundary conditions is currently under development. The new code, GRNTRN, is based on a Green's function approach to the solution of Boltzmann's transport equation and like its predecessor is deterministic in nature. Code validation in the laboratory environment is addressed by showing that GRNTRN accurately predicts energy loss spectra as measured by solid-state detectors in ion beam experiments.

The 2007 Diesel particulate matter (DPM) standard of 0.01 g/bhp-hr represents a 90% reduction of the previous standard and corresponds to roughly 100 micrograms (μg) gained on the filter sample used to determine compliance. The factors that influence the accuracy and precision by which this filter can be weighed are analyzed and quantified. The total uncertainty, representing best and typical cases, is between 1 and 5 μg. These uncertainties are used to compute the total uncertainty of the brake specific emission calculation. This uncertainty also depends on flowrate uncertainty, face velocity, and secondary dilution ratio. For a typical case, the total fractional uncertainty is in the range of ∼5 – 70% at 10% of the standard and ∼1 – 10% at 90% of the standard.

Particulate emissions from heavy-duty buses were measured in real time under conditions encountered during the standard Central Business District (CBD) driving cycle. The buses tested were equipped with 1994 Detroit Diesel Engine Corporation 6V92-TA engines, and some included after treatment devices on the exhaust. Instantaneous, time-resolved measurements of CO2 and amorphous carbon concentrations were obtained using an optical extinction technique and compared to simultaneous results obtained using conventional dilution tunnel sampling methods. Good agreement was obtained between the real-time extinction measurements and the diluted CO2 and cycle-integrated filter measurements. The instantaneous measurements revealed that acceleration transients accounted for roughly 80% of the particulate mass emitted during the cycle but only about 45% of the fuel consumption.

Results of comparisons of computed and measured soot and NO in a direct-injection Diesel engine are presented. The computations are carried out using a three-dimensional model for flows, sprays and combustion in Diesel engines. Autoignition of the Diesel spray is modeled using an equation for a progress variable which measures the local and instantaneous tendency of the fuel to autoignite. High temperature chemistry is modeled using a local chemical equilibrium model coupled to a combination of laminar kinetic and turbulent characteristic times. Soot formation is kinetically controlled and soot oxidation is represented by a model which has a combination of laminar kinetic and turbulent mixing times. Soot oxidation appears to be controlled near top-dead-center by mixing and by kinetics as the exhaust is approached. NO is modeled using the Zeldovich mechanism.

Earlier work [1] shows that kinetics of Diesel soot oxidation is different from that of ethylene diffusion flame soot oxidation [2], possibly due to metals from lube oil. This study investigates the influence of metals on soot oxidation and the exhaust particle emissions using lube oil dosed fuel (2 % by volume). This method does not simulate normal lube oil consumption, but is used as a means of adding metals to particles for oxidation studies. This study also provides insight into the effect of systems that mix lube oil with fuel to minimize oil change service. The HTO-TDMA (High Temperature Oxidation-Tandem Differential Mobility Analyzer) technique [1] was used to measure the surface specific oxidation rate of Diesel particles over the temperature range 500-750 °C. Diesel particles sampled from the exhaust stream of a Diesel engine were size segregated by differential mobility and oxidized in situ in air in a heated flow tube of known residence time and temperature profile.

Particle size distribution and number concentration measurements have been made in the diluted exhaust of a medium-duty, turbocharged, aftercooled, direct-injection Diesel engine using a unique variable residence time micro-dilution system that allows systematic variation of dilution and sampling conditions, and a scanning mobility particle sizer (SMPS). The measurements show that the number concentrations in the nanoparticle (Dp < 50 nm) and the ultrafine (Dp < 100 nm) ranges are very sensitive to dilution conditions and fuel sulfur content. Changes in concentration of up to two orders of magnitude have been observed when conditions are varied over the range that might be encountered in typical laboratory dilution systems. For example, at a dilution ratio of 12, dilution temperature of 32 °C, and a residence time of 1000 ms, the number concentrations reach 6 × 108 part.

In this work, the influences of ethanol and iso-butanol blended with gasoline on engine-out and post three-way catalyst (TWC) particle size distribution and number concentration were studied using a General Motors (GM) 2.0L turbocharged spark ignition direct injection (SIDI) engine. The engine was operated using the production engine control unit (ECU) with a dynamometer controlling the engine speed and the accelerator pedal position controlling the engine load. A TSI Fast Mobility Particle Sizer (FMPS) spectrometer was used to measure the particle size distribution in the range from 5.6 to 560 nm with a sampling rate of 1 Hz. U.S. federal certification gasoline (E0), two ethanol-blended fuels (E10 and E20), and 11.7% iso-butanol blended fuel (BU12) were tested. Measurements were conducted at 10 selected steady-state engine operation conditions. Bi-modal particle size distributions were observed for all operating conditions with peak values at particle sizes of 10 nm and 70 nm.

Progress made in reducing engine-out particulate emissions has prompted a revival in the design of flow-through oxidation catalysts for diesel engine applications. Effort in this area has focused primarily in the area of SOF control for the further reduction of particulate emissions. The work reported here covers some of the catalyst design parameters important for SOF and gas phase pollutant control. This is illustrated with both laboratory reactor and engine evaluation data for several formulary and operating parameters. Platinum-based catalysts are shown to be generally the most active, but they require treatments or additives to reduce the inherently high activity of platinum for the oxidation of SO2 present in the exhaust. The effect of additives and their loading on the oxidation activity of Pt/alumina for HC, CO, SOF and SO2 oxidation is discussed in detail and additives are identified which reduce SO2 oxidation with minimal effect on HC, CO or SOF oxidation activity.

This paper summarizes the Next Generation Natural Gas Vehicle (NG-NGV) Program that is led by the U.S. Department Of Energy's (DOE's) Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of this program is to develop and implement one Class 3-6 compressed natural gas (CNG) prototype vehicle and one Class 7-8 liquefied natural gas (LNG) prototype vehicle in the 2004 to 2007 timeframe. OHVT intends for these vehicles to have 0.5 g/bhp-hr or lower emissions of oxides of nitrogen (NOx) by 2004 and 0.2 g/bhp-hr or lower NOx by 2007. These vehicles will also have particulate matter (PM) emissions of 0.01 g/bhp-hr or lower by 2004. In addition to ambitious emissions goals, these vehicles will target life-cycle economics that are compatible with their conventionally fueled counterparts.

This paper summarizes the several of the studies in the Environmental Science Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The goal of the Environmental Science Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based fuels and alternative transportation fuels from mobile sources. The Program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. Each project in the Program is designed to address policy-relevant objectives. Current projects in the Environmental Science Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements; emission inventory development/improvement; ambient impacts, including health effects.

This paper summarizes current work in the Environmental Science & Health Effects (ES&HE) Program being sponsored by DOE's Office of Heavy Vehicle Technologies (OHVT) through the National Renewable Energy Laboratory (NREL). The program is regulatory-driven, and focuses on ozone, airborne particles, visibility and regional haze, air toxics, and health effects of air pollutants. The goal of the ES&HE Program is to understand atmospheric impacts and potential health effects that may be caused by the use of petroleum-based and alternative transportation fuels. Each project in the program is designed to address policy-relevant objectives. Studies in the ES&HE Program have four areas of focus: improving technology for emissions measurements; vehicle emissions measurements, emission inventory development/improvement; and ambient impacts, including health effects.

A study was performed in the spring of 2001 to chemically characterize exhaust emissions from trucks and buses fueled by various test fuels and operated with and without diesel particle filters. This study was part of a multi-year technology validation program designed to evaluate the emissions impact of ultra-low sulfur diesel fuels and passive diesel particle filters (DPF) in several different heavy-duty vehicle fleets operating in Southern California. The overall study of exhaust chemical composition included organic compounds, inorganic ions, individual elements, and particulate matter in various size-cuts. Detailed descriptions of the overall technology validation program and chemical speciation methodology have been provided in previous SAE publications (2002-01-0432 and 2002-01-0433).

Meeting radiation protection requirements during EVA is predominantly an operational issue with some potential considerations for temporary shelter. The issue of spacesuit shielding is mainly guided by the potential of accidental exposure when operational and temporary shelter considerations fail to maintain exposures within operational limits. In this case, very high exposure levels are possible which could result in observable health effects and even be life threatening. Under these assumptions, potential spacesuit radiation exposures have been studied using known historical solar particle events to gain insight on the usefulness of modification of spacesuit design in which the control of skin exposure is a critical design issue and reduction of blood forming organ exposure is desirable.

In this work, engine-out particle mass (PM) and particle number (PN) emissions were experimentally examined from a gasoline direct injection (GDI) engine operating in two lean combustion modes and one stoichiometric mode with a fuel of known properties. Ten steady state operating points, two constant speed load steps, and an engine cold start were examined. Results showed that solid particles emitted from the engine under steady state stoichiometric conditions had a uniquely broad size distribution that was relatively flat between the diameters of 10 and 100 nm. In most operating conditions, lean homogenous modes can achieve lower particle emissions than stoichiometric modes while improving engine thermal efficiency. Alternatively, lean stratified operating modes resulted in significantly higher PN and PM emissions than both lean homogeneous and stoichiometric modes with increased efficiency only at low engine load.

The 2001 Mars Odyssey spacecraft Martian Radiation Environment Experiment (MARIE) is a solid-state silicon telescope high-energy particle detector designed to measure galactic cosmic radiation (GCR) and solar particle events (SPEs) in the 20 – 500 MeV/nucleon energy range. In this paper we discuss the instrument design and focus on the observations and measurements of SPEs at Mars. These are the first-ever SPE measurements at Mars. The measurements are compared with the geostationary GOES satellite SPE measurements. We also discuss some of the current interplanetary particle propagation and diffusion theories and models. The MARIE SPE measurements are compared with these existing models.

A one-stage dilution tunnel has been developed to sample and dilute diesel exhaust. The tunnel has the capability of simulating many aspects of the atmospheric dilution process. The dilution rate and overall dilution ratio, temperature, relative humidity, and residence time in the tunnel, as well as residence time and temperature in the transfer line between the tunnel and exhaust sampling point may be varied. In this work we studied the influence of the exhaust transfer line, tunnel residence time, and dilution air temperature on the exhaust particle size distribution. The influences of fuel sulfur content on the size distribution and on the sensitivity of the size distribution to dilution and sampling conditions were also examined. We do not suggest an optimum dilution scheme, but do identify critical variables.

The effects of fuel sulfur content and dilution conditions on diesel engine PM number emissions have been researched extensively through steady state testing. Most results show that the concentration of nuclei-mode particles emitted increases with fuel sulfur content. A few studies further observed that fuel sulfur content has little effect on the emissions of heavily-used engines. It has also been found that primary dilution conditions can have a large impact on the size and number distribution of the nuclei-mode particles. These effects, however, have not yet been fully understood through transient testing, the method used by governments worldwide to certify engines and regulate emissions, and a means of experimentation which generates realistic conditions of on-road vehicles by varying the load and speed of the engine.

As shielding materials are developed for protection against the hazards of galactic cosmic rays, it is desirable to develop a protocol for rapid assessment of shielding properties. Solid state energy loss detectors are often used to estimate the charge and energy of particles in ion beam experiments. The direct measurement is energy deposited in the detector. As a means of separating the charge components in typical shield transmission studies with observation, a stack of many such detectors is used. With high-energy beams and thin targets, surviving primaries and fragments emerging from the target have nearly-equal velocities and deposited energy scales with the square of the charge, simplifying the data analysis. The development of a transport model for the shield and detector arrangement and evaluation of prediction of the energy loss spectrum for direct comparison with the experimentally derived data allows a rapid assessment of the shield transmission characteristics.

Regulated and unregulated emissions (individual hydrocarbons, ethanol, aldehydes and ketones, polynuclear aromatic hydrocarbons (PAH), nitro-PAH, and soluble organic fraction of particulate matter) were characterized in engines utilizing duplicate ISO 8178-C1 eight-mode tests and FTP smoke tests. Certification No. 2 diesel (400 ppm sulfur) and three ethanol/diesel blends, containing 7.7 percent, 10 percent, and 15 percent ethanol, respectively, were used. The three, Tier II, off-road engines were 6.8-L, 8.1-L, and 12.5-L in displacement and each had differing fuel injection system designs. It was found that smoke and particulate matter emissions decreased with increasing ethanol content. Changes to the emissions of carbon monoxide and oxides of nitrogen varied with engine design, with some increases and some decreases. As expected, increasing ethanol concentration led to higher emissions of acetaldehyde (increases ranging from 27 to 139 percent).