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In order to provide effective cooling for astronauts during extravehicular activities (EVAs), a liquid cooling and ventilation garment (LCVG) is used to remove heat by a series of tubes through which cooling water is circulated. To better predict the effectiveness of the LCVG and determine possible modifications to improve performance, computer simulations dealing with the interaction of the cooling garment with the human body have been run using the Wissler Human Thermal Model. Simulations have been conducted to predict the heat removal rate for various liquid cooled garment configurations. The current LCVG uses 48 cooling tubes woven into a fabric with cooling water flowing through the tubes. The purpose of the current project is to decrease the overall weight of the LCVG system. In order to achieve this weight reduction, advances in the garment heat removal rates need to be obtained.

The Orbiting Carbon Observatory (OCO) instrument is scheduled for launch onboard an Orbital Sciences Corporation LEOStar-2 architecture spacecraft in December 2008. The instrument will collect data to identify CO2 sources and sinks and quantify their seasonal variability. OCO observations will permit the collection of spatially resolved, high resolution spectroscopic observations of CO2 and O2 absorption in reflected sunlight over both continents and oceans. OCO has three bore-sighted, high resolution, grating spectrometers which share a common telescope with similar optics and electronics. A 0.765 μm channel will be used for O2 observations, while the weak and strong CO2 bands will be observed with 1.61 μm and 2.06 μm channels, respectively. The OCO spacecraft circular polar orbit will be sun-synchronous with an inclination of 98.2 degrees, mean altitude of 705 km and 98.9 minute orbit period.

Flexible fiber-reinforced aerogel composites were studied for use as insulation materials of a future space suit for Moon and Mars exploration. High flexibility and good thermal insulation properties of fiber-reinforced silica aerogel composites at both high and low vacuum conditions make it a promising insulation candidate for the space suit application. This paper first presents the results of a durability (mechanical cycling) study of these aerogels composites in the context of retaining their thermal performance. The study shows that some of these Aerogels materials retained most of their insulation performance after up to 250,000 cycles of mechanical flex cycling. This paper also examines the problem of integrating these flexible aerogel composites into the current space suit elements.

A Small Loop Heat Pipe (SLHP) featuring a wick of only 1.27 cm (0.5 inches) in diameter has been designed for use in spacecraft thermal control. It has several features to accommodate a wide range of environmental conditions in both operating and non-operating states. These include flexible transport lines to facilitate hardware integration, a radiator capable of sustaining over 100 freeze-thaw cycles using ammonia as a working fluid and a structural integrity to sustain acceleration loads up to 30 g. The small LHP has a maximum heat transport capacity of 120 Watts with thermal conductance ranging from 17 to 21 W/°C. The design incorporates heaters on the compensation chamber to modulate the heat transport from full-on to full-stop conditions. A set of start up heaters are attached to the evaporator body using a specially designed fin to assist the LHP in starting up when it is connected to a large thermal mass.

For planetary exploration, new thermal insulation materials are needed to deal with unique environmental conditions presented to extravehicular activity (EVA). The thermal insulation material and system used in the existing space suit were specifically designed for low orbit environment. They are not adequate for low vacuum condition commonly found in planetary environments with a gas atmosphere. This study attempts to identify the types of lofty nonwoven thermal insulation materials and the construction parameters that yield the best performance for such application. Lofty nonwovens with different construction parameters are evaluated for their thermal conductivity performance. Three different types of fiber material: solid round fiber, hollow fiber, and grooved fiber, with various denier, needling intensity, and web density were evaluated.

This paper presents the analysis findings of a study reducing the overall mass of the lightweight liquid cooling garment (LCG). The LCG is a garment worn by crew to actively cool the body, for spacesuits and launch/entry suits. A mass reduction of 66% was desired for advanced missions. A thermal math model of the LCG was developed to predict its performance when various mass-reducing changes were implemented. Changes included varying the thermal conductivity and thickness of the garment or of the coolant tubes servicing the garment. A second model was developed to predict behavior of the suit when the cooling tubes were to be removed, and replaced with a highly-conducting (waterless) material. Findings are presented that show significant reductions in weight are theoretically possible by improving conductivity in the garment material.

Oxidative degradation of biodiesel under accelerated conditions has been examined by Fourier transform infrared (FTIR), nuclear magnetic resonance (NMR), and gravimetric measurement of deposit formation. The formation of gums and deposits caused by oxidation in storage or in an engine fuel system is a significant issue because of the potential for fuel pump and injector fouling. The results of this study indicate several important pathways for degradation and two pathways leading to formation of oligomers and, ultimately, deposits. Peroxides formed in the initial stage of oxidation can decompose to form aldehydes, ketones, and acids. These can react further in aldol condensation to form oligomers. Additionally, peroxides can react with fatty acid chains to form dimers and higher oligomers. Deposits form when the polarity and molecular weight of these oligomers is high enough.

The overall goal of this program was the development of a 10 m. diameter, self-deployable antenna based on an open-celled rigid polyurethane foam system. Advantages of such a system relative to current inflatable or self-deploying systems include high volumetric efficiency of packing, high restoring force, low (or no) outgassing, low thermal conductivity, high dynamic damping, mechanical isotropy, infinite shelf life, and easy fabrication with methods amenable to construction of large structures (i.e., spraying). As part of a NASA Phase II SBIR, Adherent Technologies and its research partners, Temeku Technologies, and NASA JPL/Caltech, conducted activities in foam formulation, interdisciplinary analysis, and RF testing to assess the viability of using open cell polyurethane foams for self-deploying antenna applications.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.

Spark-ignition engine fuel standards have been put in place to ensure acceptable hot and cold weather driveability (HWD and CWD). Vehicle manufacturers and fuel suppliers have developed systems that meet our driveability requirements so effectively that drivers overwhelmingly find that their vehicles reliably start up and operate smoothly and consistently throughout the year. For HWD, fuels that are too volatile perform more poorly than those that are less volatile. Vapor lock is the apparent cause of poor HWD, but there is conflicting evidence in the literature as to where in the fuel system it occurs. Most studies have found a correlation between degraded driveability and higher dry vapor pressure equivalent or lower TV/L = 20, and less consistently with a minimum T50. For CWD, fuels with inadequate volatility can cause difficulty in starting and rough operation during engine warmup.

The challenges of missions to the Moon and Mars presents NASA with the need for more advanced life support systems, including better technologies for CO2 removal in spacecraft atmospheres and extravehicular mobility units (EMU). Amine-coated single wall carbon nanotubes (SWCNT) have been proposed as a potential solution because of their high surface area and thermal conductivity. Initial research demonstrated the need for functionalization of SWCNT to obtain optimal adherence of the amine to the SWCNT support phase [1]. Recent efforts focus on the development of new methods to chemically bond amines to SWCNT. Synthesis and characterization methods for these materials are discussed and some preliminary materials characterization data are presented. The CO2 adsorption capacity for several versions of SWCNT supported amine-based CO2 scrubber materials is also determined.

This paper describes the need and solution for minimizing EVA airlock time and depress gas losses using a new method that minimizes EVA out-the-door time for a suited astronaut and reclaims most of the airlock depress gas. This method consists of one or more related concepts that use an evacuated reservoir tank to store and reclaim the airlock depress gas. The evacuated tank can be an inflatable tank, a spent fuel tank from a lunar lander descent stage, or a backup airlock. During EVA airlock operations, the airlock and reservoir would be equalized at some low pressure, and through proper selection of reservoir size, most of the depress gas would be stored in the reservoir for later reclamation. The benefit of this method is directly applicable to long duration lunar and Mars missions that require multiple EVA missions (up to 100, two-person lunar EVAs) and conservation of consumables, including depress pump power and depress gas.

“Gas-to-liquids” catalytic conversion technologies show promise for liberating stranded natural gas reserves and for achieving energy diversity worldwide. Some gas-to-liquids products are used as transportation fuels and as blendstocks for upgrading crude-derived fuels. Methylal (CH3-O-CH2-O-CH3), also known as dimethoxymethane or DMM, is a gas-to-liquid chemical that has been evaluated for use as a diesel fuel component. Methylal contains 42% oxygen by weight and is soluble in diesel fuel. The physical and chemical properties of neat methylal and for blends of methylal in conventional diesel fuel are presented. Methylal was found to be more volatile than diesel fuel, and special precautions for distribution and fuel tank storage are discussed. Steady state engine tests were also performed using an unmodified Cummins B5.9 turbocharged diesel engine to examine the effect of methylal blend concentration on performance and emissions.

Fiber-reinforced Aerogel composite insulations provide superior thermal insulation protection in both the low-earth orbit (LEO) and near-earth neighborhood planetary environments. The flexible nature and thermal properties of these materials make them the best insulation candidates for advanced space suit application. This paper reviews the properties of various Aerogel composite materials developed for NASA by Aspen Systems, Inc. Previous studies showed that the Aerogel materials retained acceptable thermal performance after some amount of mechanical cycling. The goal of the current work is to reach a complete understanding of the mechanical properties of these materials in the domain of space suit application. Hence, a good knowledge of the durability of the aerogel composites is needed. This paper presents the extensive testing program needed to determine the life of these insulations for advanced space suit application.

Efficient and accurate ordinary differential equation (ODE) solvers are necessary for powertrain and vehicle dynamics modeling. However, current commercial ODE solvers can be financially prohibitive, leading to a need for accessible, effective, open-source ODE solvers designed for powertrain modeling. Rust is a compiled programming language that has the potential to be used for fast and easy-to-use powertrain models, given its exceptional computational performance, robust package ecosystem, and short time required for modelers to become proficient. However, of the three commonly used (>3,000 downloads) packages in Rust with ODE solver capabilities, only one has more than four numerical methods implemented, and none are designed specifically for modeling physical systems. Therefore, the goal of the Differential Equation System Solver (DESS) was to implement accurate ODE solvers in Rust designed for the component-based problems often seen in powertrain modeling.

Conventional diesel combustion, also known as Mixing-Controlled Compression Ignition (MCCI), is expected to be the primary power source for medium- and heavy-duty vehicles for decades to come. Displacing petroleum-based ultra-low-sulfur diesel (ULSD) as much as possible with low-net-carbon biofuels will become necessary to help mitigate effects on climate change. Neat biofuels may have difficulty meeting current diesel fuel standards but blends of 30% biofuel in ULSD show potential as ‘drop-in’ fuels. These blends must not make significant changes to the combustion phasing of the MCCI process if they are to be used interchangeably with neat ULSD. An important aspect of MCCI phasing is the ignition delay (ID), i.e. the time between the start of fuel injection and the initial premixed autoignition that initiates the MCCI process.

Increasing interest in biofuels—specifically, biodiesel as a pathway to energy diversity and security—have necessitated the need for research on the performance and utilization of these fuels and fuel blends in current and future vehicle fleets. One critical research area is related to achieving a full understanding of the impact of biodiesel fuel blends on advanced emission control systems. In addition, the use of biodiesel fuel blends can degrade diesel engine oil performance and impact the oil drain interval requirements. There is limited information related to the impact of biodiesel fuel blends on oil dilution. This paper assesses the oil dilution impacts on an engine operating in conjunction with a diesel particle filter (DPF), oxides of nitrogen (NOx) storage, a selective catalytic reduction (SCR) emission control system, and a 20% biodiesel (soy-derived) fuel blend.

Adoption of high-pressure common-rail (HPCR) fuel systems, which subject diesel fuels to higher temperatures and pressures, has brought into question the veracity of ASTM International specifications for biodiesel and biodiesel blend oxidation stability, as well as the lack of any stability parameter for diesel fuel. A controlled experiment was developed to investigate the impact of a light-duty diesel HPCR fuel system on the stability of 20% biodiesel (B20) blends under conditions of intermittent use and long-term storage in a relatively hot and dry climate. B20 samples with Rancimat induction periods (IPs) near the current 6.0-hour minimum specification (6.5 hr) and roughly double the ASTM specification (13.5 hr) were prepared from a conventional diesel and a highly unsaturated biodiesel. Four 2011 model year Volkswagen Passats equipped with HPCR fuel injection systems were utilized: one on B0, two on B20-6.5 hr, and one on B20-13.5 hr.

An ultra-low sulfur diesel (ULSD) fuel was blended with three different biodiesel samples at 5 and 20 volume percent. The biodiesel fuels were derived from rapeseed and soybean oils, and in addition, a highly oxidized biodiesel was prepared from the soy biodiesel by oxidation under controlled conditions. A set of five elastomers commonly used in automotive fuel systems were examined before and after immersion in the six test blends and base fuel at 60°C for 1000 hours. The elastomers were evaluated for hardness, tensile strength, volume change and compression. Injector wear tests were also conducted on the base petrodiesel fuel and the biodiesel blends using a 500-hour test method developed for this study. Bosch VE (in-line) rotary pumps were evaluated for wear after testing for 500 hours on the base fuel, B5 and B20 test fuels. Additionally, a test procedure was developed to accelerate wear on common rail pumps over 500 hours.

This paper describes the effort and accomplishments for developing flexible fabrics with high thermal conductivity (FFHTC) for spacesuits to improve thermal performance, lower weight and reduce complexity. Commercial and additional space exploration applications that require substantial performance enhancements in removal and transport of heat away from equipment as well as from the human body can benefit from this technology. Improvements in thermal conductivity were achieved through the use of modified polymers containing thermally conductive additives. The objective of the FFHTC effort is to significantly improve the thermal conductivity of the liquid cooled ventilation garment by improving the thermal conductivity of the subcomponents (i.e., fabric and plastic tubes).