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Technical Paper

Towards an Aspect Driven Approach for the Analysis, Evaluation and Optimization of Safety Within the Automotive Industry

2010-04-12
2010-01-0208
An approach will be presented how development projects for safety-related and software-intensive automotive systems can be controlled through the application of model-based risk assessment. Therefore specific control measures have to be developed, which represent the degree of fulfilment of several aspects of safety-related developments. The control measures are evaluated through the analysis of risk-reducing aspects, for which the process of identification and specification is described. Thus, a framework for the creation of a probabilistic and aspect-oriented risk-analysis model (AORA) for safety related projects within automotive industries is currently under development. With respect to the upcoming safety standard ISO 26262 the twofold approach focuses on both, the identification and specification of risk-reducing aspects within the development as well as the application of a probabilistic reasoning model.
Technical Paper

The Role of Mercedes Benz do Brasil in the Global Production Network of Daimler Trucks - Based on a Nationalization Project

2008-10-07
2008-36-0120
The commercial vehicle division of Daimler AG developed in the last decades a strong production network, driving the company to a large exchange of parts and aggregates, especially between the plants in Europe and South America. In this article the decision taking methodology for new investments inside this production network is described. The industrialization of engine core parts in Brazil was analyzed by the support of an evaluation tool, and considering the major aspects of a new production site and its supply relationships. The results of the evaluation give transparency about the feasibility of different production network configurations, their interdependencies and the impact of the main influencing factors and drove the board of management to a clear decision, as it happened in other projects which used the same methodology.
Journal Article

The NH3 Inhibition Effect in the Standard SCR Reaction over a Commercial Fe-zeolite Catalyst for Diesel Exhaust Aftertreatment: An Experimental and Modeling Study

2011-04-12
2011-01-1319
Transient and steady-state kinetic data are herein presented to analyze the inhibiting effect of ammonia on the NH₃-SCR of NO at low temperatures over a Fe-zeolite commercial catalyst for vehicles. It is shown that in SCR converter models a rate expression accounting for NH₃ inhibition of the Standard SCR reaction is needed in order to predict the specific dynamics observed both in lab-scale and in engine test bench runs upon switching on and off the ammonia feed. Two redox, dual site kinetic models are developed which ascribe such inhibition to the spill-over of ammonia from its adsorption sites, associated with the zeolite, to the redox sites, associated with the Fe promoter. Better agreement both with lab-scale intrinsic kinetic runs and with engine test-bench data, particularly during transients associated with dosing of ammonia to the SCR catalyst, is obtained assuming slow migration of NH₃ between the two sites.
Technical Paper

Specifics of Daimler's new SCR system (BLUETEC) in the Diesel Sprinter Van - Certified for NAFTA 2010

2010-04-12
2010-01-1172
Beginning in 2010, Daimler's well-known Diesel Sprinter van has to fulfill the new and clearly tighter NOx emission standards of NAFTA10 (EPA, CARB). This requires an integrated approach of further engine optimizations and the implementation of an innovative exhaust aftertreatment technology. The goal was to develop an overall concept which meets simultaneously the tightened emission standards (including OBD limits) and the increasing customer demands of more power and torque without losing the high fuel efficiency of the small and highly efficient 3-liter V6 diesel engine OM642, which already has been installed in the NAFTA07 Sprinter. In the early stages of the concept phase, the most appropriate NOx aftertreatment technology and certification form (engine or vehicle) had to be selected for this specific vehicle class in the van segment with enhanced requirements to durability, economical efficiency and specific driving behavior.
Technical Paper

Sensor for Directly Determining the State of a NOx Storage Catalyst

2008-04-14
2008-01-0447
In order to control NOx reduction with NOx storing lean NOx traps (LNT), a gas sensor downstream of the LNT is presently preferred. It is a disadvantage that no means are available to gauge directly the LNT NOx loading level and the catalyst quality. The presented novel sensor consists of interdigital electrodes that are deposited on a planar substrate. On its reverse side, a temperature sensor is applied. Both sides are covered with the original catalyst coating, allowing detecting directly electrical impedance and temperature of the coating. Such sensors were integrated in different positions of an LNT. It is shown in synthetic exhausts as well as in engine tests that in-situ measurements of the electrical impedance of the LNT coating are appropriate to determine directly the catalyst status. Hence, the local degree of NOx loading as well as the local regeneration status can be measured. Furthermore, sulfur poisoning, desulfurization, and thermal ageing can be directly seen.
Technical Paper

Physical 1-D System Simulation Model for Monotube Shock Absorbers for Simulation with Excitation up to 70Hz

2015-06-15
2015-01-2353
In an automotive suspension, the shock absorber plays a significant role to enable the vehicle performances, especially in ride, handling and Noise-Vibration-Harshness (NVH). Understanding its physical characteristics is of great importance, as it has a main influence on the overall vehicle performance. Within this research project simulation models for different passive monotube shock absorber systems have been created in a 1-D system simulation software. The simulation models are designed and parameterized physically. To validate the simulation models measurements on different hydropulse-shaker with specially designed control signals to investigate the response during high frequency excitation, have been done. A detailed discussion of the several models and results of a simulation to measurement comparison is given. After detailed investigation the shock absorber simulation models are now adaptable to the multi body simulation.
Journal Article

On Road Durability and Performance Test of Diesel Particulate Filter with BS III and BS IV Fuel for Indian Market

2016-04-05
2016-01-0959
The future emission regulation (BS V) in India is expected to create new challenges to meet the particulate matter (PM) limit for diesel cars. The upcoming emission norms will bring down the limit of PM by 80 % when compared to BS IV emission norms. The diesel particulate filter (DPF) is one of the promising technologies to achieve this emission target. The implementation of DPF system into Indian market poses challenges against fuel quality, driving cycles and warranty. Hence, it is necessary to do a detailed on-road evaluation of the DPF system with commercially available fuel under country specific drive cycles. Therefore, we conducted full vehicle durability testing with DPF system which is available in the European market to evaluate its robustness and reliability with BS III fuel (≤350ppm sulfur) & BS IV (≤50ppm sulfur) fuel under real Indian driving conditions.
Technical Paper

Numerical Simulation of the Transient Heat-Up of a Passenger Vehicle during a Trailer Towing Uphill Drive

2013-04-08
2013-01-0873
In the digital prototype development process of a new Mercedes-Benz, thermal protection is an important task that has to be fulfilled. In the early stages of development, numerical methods are used to detect thermal hotspots in order to protect temperature sensitive parts. These methods involve transient full Vehicle Thermal Management (VTM) simulations to predict dynamic vehicle heat-up during critical load cases. In order to simulate thermal control mechanisms, a coupled 1D to 3D thermal vehicle model is built in which the coolant and oil circuit of the engine, as well as the exhaust flow are captured in detail. When performing a transient 3D VTM analysis, the conduction and radiation phenomena are simulated using a transient structure model while the convective phenomena are co-simulated in a steady state fluid model. Both models are brought to interaction at predetermined points by an automatized coupling method.
Journal Article

Numerical Simulation of DOC+DPF+SCR systems:DOC Influence on SCR Performance

2008-04-14
2008-01-0867
A numerical model for a diesel oxidation catalyst (DOC) is presented. It is based on a spatially 1D, physical and chemically based modeling of the relevant processes within the catalytic monolith. A global reaction kinetic approach has been chosen to describe the chemical reactions. Water condensation and evaporation was also considered, in order to predict the cold start behavior. Reaction kinetic parameters have been evaluated from a series of laboratory experiments. A correlation between the kinetic parameters and the noble metal loading was developed. The model was used in combination with a SCR-Model to study the influence of changes of noble metal loading and DOC volume on the overall transient NOx performance of a DOC+DPF+SCR system.
Technical Paper

New V6-Diesel-Engine for the Daimler Van “Sprinter” Certified to Emission-Regulation NAFTA2007

2008-04-14
2008-01-1194
The new Sprinter targets the USA and Canada markets nationwide to reconfirm Daimlers statement for Diesel engine in vans. Consequentially, the MY2007 Sprinter follows his successful predecessor as again the first - and up to now the only - Diesel vehicle in its class now meeting even the strict EPA07 requirement in California. For the growing market in North America an unique development for the successor for the previous 5-cylinder Diesel Sprinter had been made. The new 3 liter V6 Diesel engine is based on numerous corporate wide versions from Mercedes and Chrysler Passenger cars and SUVs and has its roots also in smaller and larger Mercedes vans. Effective January 2007 the NAFTA04 requirements have been replaced by the NAFTA07 values. Meeting those led to significant changes of the latest Sprinter in European EURO4 version. Both, engine and exhaust hardware as well as the ECU-data had been modified consequentially.
Journal Article

Modelling of NOx Storage + SCR Exhaust Gas Aftertreatment System with Internal Generation of Ammonia

2010-04-12
2010-01-0887
Combination of an NOx storage and reduction catalyst (NSRC, called also lean NOx trap, LNT) and a catalyst for the selective catalytic reduction of NOx by NH₃ (NH₃-SCR) offers a potential to significantly increase the efficiency of NSRC-based exhaust gas aftertreatment systems. Under most situations the SCR catalyst is able to adsorb the NH₃ peaks generated in the NSRC during the regeneration and utilize it for additional NOx reduction in the course of the consequent lean phase. This synergy becomes more important with the aged NSRC, where generally lower NOx conversions and higher NH₃ yields in wider range of operating temperatures are observed (in comparison with the fresh or de-greened NSRC). In this paper we present global kinetic models for the NSRC (Pt/Ba/Ce/gγ-Al₂O₃ catalyst type) and NH₃-SCR (Fe-ZSM5 catalyst type).
Technical Paper

Model-based Optimization of Catalyst Zoning in Diesel Particulate Filters

2008-04-14
2008-01-0445
Catalyzed wall-flow particulate filters are increasingly applied in diesel exhaust after-treatment for multiple purposes, including low-temperature catalytic regeneration, CO and hydrocarbon conversion, as well as exothermic heat generation during forced regeneration. In order to optimize Precious Metals usage, it may be advantageous to apply the catalytic coating non-uniformly in the DPF, a technology referred to as “catalyst zoning”. In order to simulate the behavior of such a filter, one has to consider coupled transport-reaction modeling. In this work, a previously developed model is calibrated versus experimental data obtained with full-scale catalyzed filters on the engine dynamometer. In a next step, the model is validated under a variety of operating conditions using engine experiments with zoned filters. The performance of the zoned catalyst is analyzed by examining the transient temperature and species profiles in the inlet and outlet channels.
Technical Paper

Investigations on Chemical Ageing of Diesel Oxidation Catalysts and Coated Diesel Particulate Filters

2010-04-12
2010-01-1212
For medium- and heavy-duty diesel engines, the development of new catalyst technologies and particulate filters is necessary to fulfill increasingly stringent emission regulations. An important aspect is the durability of the after-treatment system and therefore its efficiency over lifetime. Lubrication oil additives contain components such as phosphorous or zinc to ensure engine durability. Diesel oxidation catalyst (DOC) and coated diesel particulate filter (cDPF) catalytic coatings are negatively influenced by contamination on the surface with these components (chemical ageing). The components have a negative impact on the exhaust after-treatment systems performance. Additionally the cDPF is filled with oil ash. Engine tests are conducted to analyze the effect of lubrication oil additives on after-treatment system performance. In one study, lubrication oil with increased sulfur ash content is used.
Journal Article

Cold Start Effect Phenomena over Zeolite SCR Catalysts for Exhaust Gas Aftertreatment

2013-04-08
2013-01-1064
NH₃/urea SCR is a very effective and widely used technology for the abatement of NOx from diesel exhaust. The SCR mechanism is well understood and the catalyst behavior can be predicted by mathematical models - as long as operation above the temperature limit for AdBlue® injection is considered. The behavior below this level is less understood. During the first seconds up to minutes after cold start, complete NOx abatement can be observed over an SCR catalyst in test bench experiments, together with a significant increase in temperature after the converter (ca. 100 K). In this work these effects have been investigated over a monolith Cu-zeolite SCR catalyst. Concentration step experiments varying NO, NO₂ and H₂O have been carried out in lab scale, starting from room temperature. Further, the interaction of C₃H₆ and CO with NOx over the SCR has been investigated.
Technical Paper

Challenges for the Next Generation of BlueTEC Emission Technology

2011-04-12
2011-01-0294
Mercedes-Benz BlueTEC passenger cars have been on the cutting edge of clean diesel technology since 2006. These BlueTEC vehicles furthermore passed millions of kilometers in the hands of customers. SCR-equipped passenger cars already meet the most stringent exhaust emissions standards in international markets such as the USA, Europe and Japan. Diesel engines with BlueTEC technology also reduce CO₂ emissions and provide the high torque and performance associated with the diesel engine in addition to keeping exhaust emissions at the lowest possible level. Nowadays the requirements for SCR emission concepts are increasing continuously. In fact the emission legislation is getting stricter with the LEVIII emission standards in 2015. Additionally the requirements and effort for on-board diagnosis are increasing year after year. In combination with ambitious CO₂ targets all these issues constitute the further challenges of BlueTEC SCR emission concepts for worldwide markets.
Technical Paper

Bluetec Emission Control System for the US Tier 2 Bin 5 Legislation

2008-04-14
2008-01-1184
While the market share for diesel engines for LD vehicles in Europe has grown continuously in the past years, the market share in North America is still negligible. Until now, it has been possible to fulfill the limits for nitrogen oxides (NOx) both in Europe and in North America by engine measures alone, without using an active NOx aftertreatment system. With the introduction of Tier II Bin 8 and Tier II Bin 5 emissions legislation in the US in 2007, most new diesel applications will now require NOx aftertreatment. One of the possible technologies for the reduction of nitrogen oxides in lean exhaust gas is the NOx storage catalyst which has become the generally-accepted choice for engines with gasoline direct injection systems and which is also utilized in the current diesel Bluetec I systems from Daimler. For heavier applications urea-SCR is the preferred technology to fulfill NOx legislation limits.
Technical Paper

BLUETEC Diesel Technology - Clean, Efficient and Powerful

2008-04-14
2008-01-1182
Diesel engines have a strong contribution to the CO2 reduction in Europe in the past years. To enable these C02 reduction potential to the US market Mercedes Benz developed the BLUETEC technology for light duty diesel engines. The BLUETEC technology contains an optimized diesel engine and combustion system, an aftertreatment system with DOC, DPF and an active SCR catalyst with AdBlue Dosing System and an enhanced ECU functionality and calibration. For fulfilling the world strongest emission limits of the US legislation there have to be solutions developed for the handling of AdBlue under cold climate below -11°C, managing the refilling event, and the onboard diagnostic. To ensure the emission stability over full useful life on high NOx conversions level, intensive testing of the catalyst technology had to be done. In addition there are self learning functionalities for adapting the dosing strategy to ensure the maximum NOx performance.
Technical Paper

Ash Transport in Diesel Particle Filters

2012-09-10
2012-01-1732
Lubricant oil derived ash deposits still represent a major issue in diesel particulate filter operation in vehicles. In literature various ash deposition patterns are described. The two boundary deposition patterns are (a) wall layer and (b) filling at the back end of the inlet channels. The patterns are often associated with different regeneration methods. Continuous regeneration is supposed to result in a homogeneous ash layer, whereas periodic (active) regeneration is reported to result in back end filling. The current contribution describes the basic mechanisms associated with ash transport phenomena in particle filters. On the basis of (a) frequency of ash exposure to flow (b) ash particle structure re-entrainment and finally (c) axial ash transport the different deposition pattern can be explained. Exposure to flow accomplished by periodical soot removal, either by passive or active regeneration is the first step.
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