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Technical Paper

Vehicle Study on the Impact of Diesel Fuel Sulfur Content on the Performance of DeNOX Catalysts and the Influence of DeNOX Catalysts on Particle Size and Number

2000-06-19
2000-01-1877
A vehicle investigation programme was initiated to evaluate the influence of diesel fuel sulfur content on the performance of a DeNOx catalyst for NOx control. The programme was conducted with a passive DeNOx catalyst, selected for its good NOx reduction performance and two specially prepared fuels with different sulfur contents. Regulated emissions were measured and analysed during the course of the programme. The NOx conversion efficiency of the DeNOx catalyst increased from 14 to 26% over the new European test cycle when the sulfur content of the diesel fuel was reduced from 49 to 6 wt.-ppm. In addition the number and size of particles produced using 6 wt.-ppm sulfur fuel were measured by two different techniques: mobility diameter by SMPS and aerodynamic diameter by impactor. The influence of the assumed density of the particulate on the apparent diameters measured by the two techniques is discussed.
Technical Paper

Utilization of Advanced Three-Way Catalyst Formulations on Ceramic Ultra Thin Wall Substrates for Future Legislation

2002-03-04
2002-01-0349
The LEV II and SULEV/PZEV emission standards legislated by the US EPA and the Californian ARB will require continuous reduction in the vehicles' emission over the next several years. Similar requirements are under discussion in the European Union (EU) in the EU Stage V program. These future emission standards will require a more efficient after treatment device that exhibits high activity and excellent durabilty over an extended lifetime. The present study summarizes the findings of a joint development program targeting such demanding future emission challenges, which can only be met by a close and intensive co-operation of the individual expert teams. The use of active systems, e.g. HC-adsorber or electrically heated light-off catalysts, was not considered in this study. The following parameters were investigated in detail: The development of a high-tech three-way catalyst technology is described being tailored for applications on ultra thin wall ceramic substrates (UTWS).
Technical Paper

Utilization of Advanced Pt/Rh TWC Technologies for Advanced Gasoline Applications with Different Cold Start Strategies

2001-03-05
2001-01-0927
This paper describes the results of a joint development program focussing on the introduction of the new generation of Pt/Rh-technology for current and future emission standards as a cost effective alternative to the in serial Pd/Rh based exhaust gas concepts. In the initial phase of the program combinations of Pd- and Pt-based three-way catalyst technologies were evaluated on vehicles equipped with a 8 cylinder engine. One goal in this portion of the study was to achieve technical equivalence between a viable Pd-based technology and the new Pt/Rh technology in the underfloor position at lower precious metal loading. A combination of a close-coupled Pd/Rh technology and the new Pt/Rh in the underfloor position was able to meet the emission targets at significant lower costs of the system after a catalyst aging that resembles more than 100.000 km of vehicle German highway driving.
Journal Article

Tomorrows Diesel Fuel Diversity - Challenges and Solutions

2008-06-23
2008-01-1731
Regulated emissions, CO2-values, comfort, good driveability, high reliability and costs, this is the main frame for all future powertrain developments. In this frame, the diesel powertrain, not only for passenger cars, but also for commercial vehicle applications, faces some challenges in order to fulfil the future European and current US emission legislations while keeping the fuel consumption benefit, good driveability and an acceptable cost frame. One of these challenges is the varying fuel qualities of diesel fuel in different countries including different cetane number, volatility, sulphur content and different molecular composition. In addition to that in the future, more and more alternative fuels with various fuel qualities and properties will be launched into the market for economical and environmental reasons. At present, the control algorithms of the injection system applied in most diesel engines is open loop control.
Technical Paper

The Influence of Rotating Wheels on Vehicle Aerodynamics - Numerical and Experimental Investigations

2007-04-16
2007-01-0107
Investigations of the aerodynamic influence of rotating wheels on a simplified vehicle model as well as on a series production car are presented. For this research CFD simulations are used together with wind tunnel measurements like LDV and aerodynamic forces. Several wheel rim geometries are examined in stationary and in rotating condition. A good agreement could be achieved between CFD simulations and wind tunnel measurements. Based on the CFD analysis the major aerodynamic mechanisms at rotating wheels are characterized. The flow topology around the wheels in a wheel arch is revealed. It is shown, that the reduction of drag and lift caused by the wheel rotation on the isolated wheel and the wheel in the wheel arch are based on different effects of the airflow. Though the forces decrease at the front wheel due to the wheel rotation locally, the major change in drag and lift happens directly on the automotive body itself.
Technical Paper

The Impact of High Cell Density Ceramic Substrates and Washcoat Properties on the Catalytic Activity of Three Way Catalysts

1999-03-01
1999-01-0272
The present paper describes the results of a joint development program focussing on a system approach to meet the EURO IV emission standards for an upper class passenger car equipped with a newly developed high displacement gasoline engine. Based on the well known catalyst systems of recent V6- and V8-engines for the EURO III emission standards with a combination of close coupled catalysts and underfloor catalysts, the specific boundary conditions of an engine with an even larger engine displacement had to be considered. These boundary conditions consist of the space requirements in the engine compartment, the power/torque requirements and the cost requirements for the complete aftertreatment system. Theoretical studies and computer modeling showed essential improvements in catalyst performance by introducing thin wall substrates with low thermal inertia as well as high cell densities with increased geometric surface area.
Technical Paper

The Impact of Different Biofuel Components in Diesel Blends on Engine Efficiency and Emission Performance

2010-10-25
2010-01-2119
Within the Cluster of Excellence “Tailor-Made Fuels from Biomass” at RWTH Aachen University, the Institute for Combustion Engines carried out an investigation program to explore the potential of future biofuel components in Diesel blends. In this paper, thermodynamic single cylinder engine results of today's and future biofuel components are presented with respect to their engine-out emissions and engine efficiency. The investigations were divided into two phases: In the first phase, investigations were performed with rapeseed oil methyl ester (B100) and an Ethanol-Gasoline blend (E85). In order to analyze the impact of different fuel blends, mixtures with 10 vol-% of B100 or E85 and 90 vol-% of standardized EN590 Diesel were investigated. Due to the low cetane number of E85, it cannot be used purely in a Diesel engine.
Technical Paper

The Diesel Exhaust Aftertreatment (DEXA) Cluster: A Systematic Approach to Diesel Particulate Emission Control in Europe

2004-03-08
2004-01-0694
The DEXA Cluster consisted of three closely interlinked projects. In 2003 the DEXA Cluster concluded by demonstrating the successful development of critical technologies for Diesel exhaust particulate after-treatment, without adverse effects on NOx emissions and maintaining the fuel economy advantages of the Diesel engine well beyond the EURO IV (2000) emission standards horizon. In the present paper the most important results of the DEXA Cluster projects in the demonstration of advanced particulate control technologies, the development of a simulation toolkit for the design of diesel exhaust after-treatment systems and the development of novel particulate characterization methodologies, are presented. The motivation for the DEXA Cluster research was to increase the market competitiveness of diesel engine powertrains for passenger cars worldwide, and to accelerate the adoption of particulate control technology.
Technical Paper

Tailor-Made Fuels: The Potential of Oxygen Content in Fuels for Advanced Diesel Combustion Systems

2009-11-02
2009-01-2765
Fuels derived from biomass will most likely contain oxygen due to the high amount of hydrogen needed to remove oxygen in the production process. Today, alcohol fuels (e. g. ethanol) are well understood for spark ignition engines. The Institute for Combustion Engines at RWTH Aachen University carried out a fuel investigation program to explore the potential of alcohol fuels as candidates for future compression ignition engines to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. The soot formation and oxidation process when using alcohol fuels in diesel engines is not yet sufficiently understood. Depending on the chain length, alcohol fuels vary in cetane number and boiling temperature. Decanol possesses a diesel-like cetane number and a boiling point in the range of the diesel boiling curve. Thus, decanol was selected as an alcohol representative to investigate the influence of the oxygen content of an alcohol on the combustion performance.
Technical Paper

Tailor-Made Fuels for Future Advanced Diesel Combustion Engines

2009-06-15
2009-01-1811
The finite nature and instability of fossil fuel supply has led to an increasing and enduring investigation demand of alternative and regenerative fuels. The Institute for Combustion Engines at the RWTH Aachen University carried out an investigation program to explore the potential of tailor made fuels to reduce engine-out emissions while maintaining engine efficiency and an acceptable noise level. To enable optimum engine performance a range of different hydrocarbons having different fuel properties like cetane number, boiling temperature and different molecular compositions have been investigated. Paraffines and naphthenes were selected in order to better understand the effects of molecular composition and chain length on emissions and performance of an engine that was already optimized for advanced combustion performance. The diesel single-cylinder research engine used in this study will be used to meet Euro 6 emissions limits and beyond.
Technical Paper

Study of a Sintered Metal Diesel Particulate Trap

2005-04-11
2005-01-0968
This paper describes work supporting the development of a new Diesel particulate trap system for heavy duty vehicles based on porous sintered metal materials that exhibit interesting characteristics with respect to ash tolerance. Experimental data characterizing the material (permeability, soot and ash deposit properties) are obtained in a dedicated experimental setup in the side-stream of a modern Diesel engine as well as in an accelerated ash loading rig. System level simulations coupling the new media characteristics to 3-D CFD software for the optimization of complete filter systems are then performed and comparative assessment results of example designs are given.
Technical Paper

Studies on Enhanced CVS Technology to Achieve SULEV Certification

2002-03-04
2002-01-0048
For the measurement of exhaust emissions, Constant Volume Sampling (CVS) technology is recommended by legislation and has proven its practical capability in the past. However, the introduction of new low emission standards has raised questions regarding the accuracy and variability of the CVS system when measuring very low emission levels. This paper will show that CVS has the potential to achieve sufficient precision for certification of SULEV concepts. Thus, there is no need for the introduction of new test methods involving high cost. An analysis of the CVS basic equations indicates the importance of the Dilution Factor (DF) for calculating true mass emissions. A test series will demonstrate that, by adjusting the dilution and using state of the art analyzers, the consistency of exhaust results is comparable with those of LEV concepts, measured with conventional CVS systems and former standard analyzers.
Technical Paper

Strategies to Reduce HC-Emissions During the Cold Starting of a Port Fuel Injected Gasoline Engine

2003-03-03
2003-01-0627
In view of tight emission standards, injection strategies to reduce raw HC-emissions during the cold starting of port fuel injected engines are evaluated in this study. The relevance of spray targeting and atomization is outlined in the first part of this paper. The foundation and performance of different injector concepts with respect to spray characteristics are discussed. Laboratory experiments demonstrate that concepts relying on auxiliary energy, such as air-assistance, fuel heating and injection at elevated system pressures, are capable of producing spray droplet sizes in the SMD-range of 25μm. For future injection strategies aimed at the compliance of SULEV emission levels, this target value is considered to be essential. In the second part of this paper, emission tests of selected injector concepts are carried out using a V6-3.2I ULEV engine operated both in a vehicle and on a test bench.
Technical Paper

Start-Up Behavior of Fuel Processors for PEM Fuel Cell Applications

2003-03-03
2003-01-0420
This paper focuses on start-up technology for fuel processing systems with special emphasis on gasoline fueled burners. Initially two different fuel processing systems, an autothermal reformer with preferential oxidation and a steam reformer with membrane, are introduced and their possible starting strategies are discussed. Energy consumption for preheating up to light-off temperature and the start-up time is estimated. Subsequently electrical preheating is compared with start-up burners and the different types of heat generation are rated with respect to the requirements on start-up systems. Preheating power for fuel cell propulsion systems necessarily reaches up to the magnitude of the electrical fuel cell power output. A gasoline fueled burner with thermal combustion has been build-up, which covers the required preheating power.
Technical Paper

Simulation Of NOx Storage and Reduction Catalyst: Model Development And Application

2007-04-16
2007-01-1117
To fulfill future emission standards for diesel engines, combined after-treatment systems consisting of different catalyst technologies and diesel particulate filters (DPF) are necessary. For designing and optimizing the resulting systems of considerable complexity, effective simulation models of different catalyst and DPF technologies have been developed and integrated into a common simulation environment called ExACT (Exhaust After-treatment Components Toolbox). This publication focuses on a model for the NOx storage and reduction catalyst as a part of that simulation environment. A heterogeneous, spatially one-dimensional (1D), physically and chemically based mathematical model of the catalytic monolith has been developed. A global reaction kinetic approach has been chosen to describe reaction conversions on the washcoat. Reaction kinetic parameters have been evaluated from a series of laboratory experiments.
Technical Paper

Shape Optimization of a Single Cylinder Engine Crankshaft

2011-04-12
2011-01-1077
Due to increasing demand for environment friendly vehicles with better fuel economy and strict legislations on greenhouse gas emissions, lightweight design has become one of the most important issues concerning the automobile industry. Within the scope of this work lightweight design potentials that a conventional single cylinder engine crankshaft offers are researched through utilization of structural optimization techniques. The objective of the study is to reduce mass and moment of inertia of the crankshaft with the least possible effect on the stiffness and strength. For precise definition of boundary conditions and loading scenarios multi body simulations are integrated into the optimization process. The loading conditions are updated at the beginning of each optimization loop, in which a multi body simulation of the output structure from the previous optimization loop is carried out.
Technical Paper

Relationship between Fuel Properties and Sensitivity Analysis of Non-Aromatic and Aromatic Fuels Used in a Single Cylinder Heavy Duty Diesel Engine

2011-04-12
2011-01-0333
Fuel properties are always considered as one of the main factors to diesel engines concerning performance and emission discussions. There are still challenges for researchers to identify the most correlating and non-correlating fuel properties and their effects on engine behavior. Statistical analyses have been applied in this study to derive the most un-correlating properties. In parallel, sensitivity analysis was performed for the fuel properties as well as to the emission and performance of the engine. On one hand, two different analyses were implemented; one with consideration of both, non-aromatic and aromatic fuels, and the other were performed separately for each individual fuel group. The results offer a different influence on each type of analysis. Finally, by considering both methods, most common correlating and non-correlating properties have been derived.
Technical Paper

Real-Time Estimation of the Exhaust Gas Recirculation Ratio Based on Cylinder Pressure Signals

2007-04-16
2007-01-0493
External Exhaust Gas Recirculation, EGR, is a central issue in controlling emissions in up-to-date diesel engines. An empirical model has been developed that calculates the EGR ratio as a function of the engine speed, the engine load and special characteristics of the heat release rate. It was found that three combustion characteristics correlate well with the EGR ratio. These characteristics are the ignition delay, the premixed combustion ratio and the mixing-controlled combustion ratio. The calculation of these characteristics is based on parameter subsets, which were determined using an optimization routine. The model presented was developed based on these optimized characteristics.
Technical Paper

Quantitative Laser Diagnostic Studies of the NO Distribution in a DI Diesel Engine with PLN and CR Injection Systems

2001-09-24
2001-01-3500
The NO distribution in a directly-injected Diesel engine with realistic combustion chamber geometry was investigated with laser-induced fluorescence (LIF) imaging with KrF excimer laser excitation. The highest possible level of selectivity has been ensured using spectrally resolved LIF investigations inside the Diesel engine. To minimize interference from both, oxygen and polycyclic aromatic hydrocarbon (PAH) LIF the NO signal was detected around 237 nm, blue-shifted compared to the excitation wavelength resulting in a background contribution below 10% at the earliest detection timing possible in the engine under study (20°ca after top dead center, TDC). The in-cylinder NO LIF intensities were compared for different injection systems and operating conditions and correlated to variations in pressure traces and soot temperature measurements.
Journal Article

Quantitative Fuel-Air-Mixing Measurements in Diesel-Like Sprays Emanating from Convergent and Divergent Multi-Layer Nozzles

2012-04-16
2012-01-0464
It is the objective of this work to characterize mixture formation in the sprays emanating from Multi-Layer (ML) nozzles under approximately engine-like conditions by quantitative, spatially, and temporally resolved fuel-air ratio and temperature measurements. ML nozzles are cluster nozzles which have more than one circle of orifices. They were introduced previously, in order to overcome the limitations of conventional nozzles. In particular, the ML design yields the potential of variable spray interaction, so that mixture formation could be controlled according to the operating condition. In general, it was also a primary aim of the cluster-nozzle concepts to combine the enhanced atomization and pre-mixing of small nozzle holes with the longer spray penetration lengths of large holes. The applied diagnostic, which is based on 1d spontaneous Raman scattering, yields the quantitative stoichiometric ratio and the temperature in the vapor phase.
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