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Nitrites have long been added to heavy-duty coolant to inhibit iron cylinder liner corrosion initiated by cavitation. However, in heavy-duty use, nitrites deplete from the coolant, which then must be refortified using supplemental coolant additives (SCA's). Recently, carboxylates have also been found to provide excellent cylinder liner protection in heavy-duty application. Unlike nitrites, carboxylate inhibitors deplete slowly and thus do not require continual refortification with SCA's. In the present paper laboratory aging experiments shed light on the mechanism of cylinder liner protection by these inhibitors. The performance of carboxylates, nitrites and mixtures of the two inhibitors are compared. Results correlate well with previously published fleet data. Specifically, rapid nitrite and slow carboxylate depletion are observed. More importantly, when nitrite and carboxylates are used in combination, nitrite depletion is repressed while carboxylates deplete at a very slow rate.

There has been an ongoing interest in replacing mineral oil with more biodegradable and/or fire-resistant hydraulic fluids in many mobile equipment applications. Although many alternative fluids may be more biodegradable, or fire-resistant, or both than mineral oil, they often suffer from other limitations such as poorer wear, oxidative stability, and yellow metal corrosion which inhibit their performance in high-pressure hydraulic systems, particularly high pressure piston pump applications. From the fluid supplier's viewpoint, the development of a definitive test, or series of tests, that provides sufficient information to determine how a given fluid would perform with various hydraulic components would be of interest because it would minimize extensive testing. This is often too slow or prohibitively expensive. Furthermore, from OEM's (original equipment manufacturer's) point of view, it would be advantageous to develop a more effective, industry accepted fluid analysis screening.

Silicate-free, carboxylate based technology as typified by Texaco Extended Life Coolant (TELC) and Caterpillar Extended Life Coolant (ELC), both meeting Caterpillar's EC-1 Coolant Specification, offer excellent corrosion protection for commercial lead solders commonly used in the fabrication of copper/brass radiators and heater cores throughout the trucking industry. Results of laboratory testing using solders from commercial radiators manufacturers and extensive field coolant analysis compare extended life technology with the popular conventional coolant technologies. In the laboratory, the effect of coolant concentration on solder protection is explored using the glassware corrosion test, ASTM D-1384. At concentrations ranging from 33% up to 75% the carboxylate technology offers comparable to superior protection when compared to the popular heavy-duty conventional coolant containing silicates and phosphates.

Coolant formulations based on organic acid corrosion inhibitor technology have been tested in over 180 heavy duty engines for a total of more than 50 million kilometers. This testing has been used to document long life coolant performance in various engine types from four major engine manufacturers. Inspections of engines using organic acid based coolant (with no supplemental coolant additive) for up to 610,000 kilometers showed excellent protection of metal engine components. Improved protection was observed against cylinder liner, water pump, and aluminum spacer deck corrosion. In addition, data accumulated from this testing were used to develop depletion rate curves for long life coolant corrosion inhibitors, including tolyltriazole and nitrite. Nitrite was observed to deplete less rapidly in long life coolants than in conventional formulations.

A number of oxidation catalysts have been prepared using different types of advanced support materials such as ceria-zirconia, silica-titania, spinels and perovskites. Active metals such as Pd and Au-Pd were loaded by conventional impregnation techniques and/or deposition-precipitation methods. A liquid hydrocarbon delivery system was designed and implemented for the catalyst test benches in order to simulate the diesel engine exhaust environment. The activity of fresh (no degreening) catalysts was evaluated with traditional CO and light hydrocarbons (C2H4, C3H6) as well as with heavy hydrocarbons such as C10 H22.

In lightweight structures with dissimilar metal designs, structural adhesive joining is a potential joining method. Adhesives help in reducing galvanic corrosion by minimizing physical contact between two dissimilar metals. Along with adhesives, fasteners are often used as a secondary joining method to hold the assembly together during adhesive curing. Therefore, a hybrid joint which is a combination of adhesives and mechanical fasteners is potential joining method to join dissimilar metals. However, when two dissimilar metals such as aluminum to steel are joined with hybrid joint by adhesive curing at elevated temperature, the distortion of assembly is observed when cooled at room temperature. This is due to the mismatch between coefficients of thermal expansion of aluminum vs steel. The adhesive may also experience residual stress and fracture. In this study, adhesive curing induced distortion is studied using 1.1 meter-long specimens of aluminum to steel hybrid joint assembly.

Field testing of an extended life coolant technology in Class 8 trucks, equipped with Caterpillar C-12 engines revealed excellent coolant life with negligible inhibitor depletion to 400,000 miles with no refortification and no coolant top-off. In separate evaluations in Caterpillar 3406E equipped trucks, extended corrosion protection and component durability were established out to 700,000 miles, without the need for refortification other than top-off.

Engine cooling fan systems for off-highway machinery require a significant amount of horsepower and contribute to the overall noise level of the machine. Reducing fan speed in times of low cooling demand provides a means to reduce vehicle noise levels and divert engine horsepower from the fan to do productive work. The fan must, however, continue to provide adequate airflow when demanded by the cooling system. Electronic fan controls that modulate fan speed to meet changing cooling system requirements provide the above advantages.

A method is presented for precise mounting of a hose model with any specified twist. Once mounting points and directions are specified, a hose of a specified length can be developed using discrete beams. A divide and conquer approach is employed to position, orient, decouple the free end of the hose model in a twist free state that is then twisted to a specified angle. The development of the kinematic elements necessary to do this is presented. Some Cosserat models have been shown to branch into multiple solutions while the method presented here has always converged to the minimum energy solution. The method for linking the hose model to other linkages is discussed as well one common error committed by users in implementing the link. In order to model the torsional properties of the hose, the torsional stiffness must be modified. A method for doing this using digital scans is discussed.

Evaluations of the liner pitting protection performance provided by engine coolant corrosion inhibitors and supplemental coolant additives have presented many problems. Current practice involves the use of full scale engine tests to show that engine coolant inhibitors provide sufficient liner pitting protection. These are too time-consuming and expensive to use as the basis for industry-wide specifications. Ultrasonic vibratory test rigs have been used for screening purposes in individual labs, but these have suffered from poor reproducibility and insufficient additive differentiation. A new test procedure has been developed that reduces these problems. The new procedure compares candidate formulations against a good and bad reference fluid to reduce the concern for problems with calibration and equipment variability. Cast iron test coupons with well-defined microstructure and processing requirements significantly reduce test variability.