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The objectives of this project were to investigate the corrosivity of condensate in a stoichiometric spark-ignited (SI) engine when running exhaust gas recirculation (EGR) and to determine the effects of sulfur-in-fuel on corrosion. A 2.0 L turbocharged direct-injected SI engine was operated with low-pressure EGR for this study. The engine was instrumented for visual, thermodynamic, and electrochemical analyses to determine the potential for corrosion at locations where condensation was deemed likely in a low-pressure loop EGR (LPL-EGR) engine. The electrochemical analysis was performed using multi-electrode array (MEA) corrosion probes. Condensate was also collected and analyzed. These analyses were performed downstream of both the charge air cooler (CAC) and the EGR cooler. It was found that while conditions existed for sulfuric acid to form with high-sulfur fuel, no sulfuric acid was detected by any of the measurement methods.

The confluence of fuel economy improvement requirements and increased use of ethanol as a gasoline blend component has led to various studies into the efficiency and performance benefits to be had when using high octane number, high ethanol content fuels in modern engines. As part of a comprehensive study of the autoignition of fuels in both the CFR octane rating engine and a modern, direct injection, turbocharged spark ignited engine, a series of fuel blends were prepared with market relevant ranges of octane numbers and ethanol blends levels. The paper reports on the first part of this study where fuel flow measurements were done on a single cylinder research engine, utilizing a GM LHU combustion system, and then used to predict drive cycle fuel economy. For a range of engine speeds and manifold air pressures, spark timing was adjusted to achieve either the maximum brake torque (MBT) or a matched 50 % mass fraction burnt location.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

A project was conducted by Southwest Research Institute on behalf of the California Air Resources Board and the South Coast Air Quality Management District to demonstrate the technical feasibility of utilizing closed-loop three-way catalyst technology in off-road equipment applications. Five representative engines were selected, and baseline emission-tested using both gasoline and LPG. Emission reduction systems, employing three-way catalyst technology with electronic fuel control, were designed and installed on two of the engines. The engines were then installed in a fork lift and a pump system, and limited durability testing was performed. Results showed that low emission levels, easily meeting CARB's newly adopted large spark-ignited engine emission standards, could be achieved.

The objective was to demonstrate the feasibility of operating a natural gas two-stroke engine using glow plug ignition with very lean mixtures. Based on the results obtained, the term SCGI (stratified charge glow plug ignition) was coined to describe the engine. An JLO two-stroke diesel engine was converted first to a natural gas fueled spark-ignited engine for the baseline tests, and then to an SCGI engine. The SCGI engine used a gas operated valve in the cylinder head to admit the natural gas fuel, and a glow plug was used as a means to initiate the combustion. The engine was successfully run, but was found to be sensitive to various conditions such as the glow plug temperature. The engine would run very lean, to an overall equivalence ratio of 0.33, offering the potential of good fuel economy and low NOx emissions.

The spark ignition (SI) engine has been known to exhibit several different abnormal combustion phenomena, such as knock or pre-ignition, which have been addressed with improved engine design or control schemes. However, in highly boosted SI engines, Low-Speed Pre-Ignition (LSPI), a pre-ignition event typically followed by heavy knock, has developed into a topic of major interest due to its potential for engine damage. Previous experiments associated increases in hydrocarbon emissions with the blowdown event of an LSPI cycle [1]. Also, the same experiments showed that there was a dependency of the LSPI activity on fuel and/or lubricant compositions [1]. Based on these findings it was hypothesized that accumulated hydrocarbons play a role in LSPI and are consumed during LSPI events. A potential source for accumulated HC is the top land piston crevice.

Because of the thermodynamic relationship of pressure, temperature and volume for processes which occur in an internal-combustion engine (ICE), and their relationship to ideal efficiency and efficiency-limiting phenomena e.g. knock in spark-ignition engines, changing the thermo-chemical properties of the in-cylinder charge should be considered as an increment in the development of the ICE engine for future efficiency improvements. Exhaust gas recirculation (EGR) in spark-ignited gasoline engines is one increment that has been made to alter the in-cylinder charge. EGR gives proven thermal efficiency benefits for SI engines which improve vehicle fuel economy, as demonstrated through literature and production applications. The thermal efficiency benefit of EGR is due to lower in-cylinder temperatures, reduced heat transfer and reduced pumping losses. The next major increment could be modifying the constituents of the EGR stream, potentially through the means of a membrane.

The effect of combustion chamber wall-wetting on the emissions of unburned and partially-burned hydrocarbons (HCs) from gasoline-fueled SI engines was investigated experimentally. A spark-plug mounted directional injection probe was developed to study the fate of liquid fuel which impinges on different surfaces of the combustion chamber, and to quantify its contribution to the HC emissions from direct-injected (DI) and port-fuel injected (PFI) engines. With this probe, a controlled amount of liquid fuel was deposited on a given location within the combustion chamber at a desired crank angle while the engine was operated on pre-mixed LPG. Thus, with this technique, the HC emissions due to in-cylinder wall wetting were studied independently of all other HC sources. Results from these tests show that the location where liquid fuel impinges on the combustion chamber has a very important effect on the resulting HC emissions.

Small (up to 1% by volume) amounts of hydrogen (H2) were added to the intake charge of a single-cylinder, stoichiometric spark ignited engine to determine the effect of H2 addition on EGR tolerance. Two types of tests were performed at 1500 rpm, two loads (3.1 bar and 5.5 bar IMEP), two compression ratios (11:1 and 14:1) and with two fuels (gasoline and natural gas). The first test involved holding EGR level constant and increasing the H2 concentration. The EGR level of the engine was increased until the CoV of IMEP was > 5% and then small amounts of hydrogen were added until the total was 1% by volume. The effect of increasing the amount of H2 on engine stability was measured along with combustion parameters and engine emissions. The results showed that only a very small amount of H2 was necessary to stabilize the engine. At amounts past that level, increasing the level of H2 had no or only a very small effect.

The spark ignition (SI) engine has been known to exhibit several different abnormal combustion phenomena, such as knock or pre-ignition, which have been addressed with improved engine design or control schemes. However, in highly boosted SI engines - where the engine displacement is reduced and turbocharging is employed to increase specific power - a new combustion phenomenon, described as Low-Speed Pre-Ignition (LSPI), has been exhibited. LSPI is characterized as a pre-ignition event typically followed by heavy knock, which has the potential to cause degradation of the engine. However, because LSPI events occur only sporadically and in an uncontrolled fashion, it is difficult to identify the causes for this phenomenon and to develop solutions to suppress it. Some countermeasures exist that OEMs can use to avoid LSPI, such as load limiting, but these have drawbacks.

Spray angle and penetration length data were taken under cold start conditions for a Direct Injection Spark Ignition engine to investigate the effect of transient conditions on spray development. The results show that during cold start, spray development depends primarily on fuel pressure, followed by Manifold Absolute Pressure (MAP). Injection frequency had little effect on spray development. The spray for this single hole, pressure-swirl fuel injector was characterized using high speed imaging. The fuel spray was characterized by three different regimes. Regime 1 comprised fuel pressures from 6 - 13 bar, MAPs from 0.7 - 1 bar, and was characterized by a large pre-spray along with large drop sizes. The spray angle and penetration lengths were comparatively small. Regime 2 comprised fuel pressures from 30 - 39 bar and MAPs from 0.51 - 0.54 bar. A large pre-spray and large drop sizes were still present but reduced compared to Regime 1.

The performance of an organic Rankine cycle (ORC) used to recover waste heat from the exhaust of a diesel and a spark ignition engine for electric power generation was modeled. The design elements of the ORC incorporated into the thermodynamic model were based on an experimental study performed at Oak Ridge National Laboratory in which a regenerative organic Rankine cycle system was designed, assembled and integrated into the exhaust of a 1.9 liter 4-cylinder automotive turbo-diesel. This engine was operated at a single fixed-load point at which Rankine cycle state point temperatures as well as the electrical power output of an electric generator coupled to a turbine that expanded R245fa refrigerant were measured. These data were used for model calibration.

Biodiesel produced from soybean oil, canola oil, yellow grease, and beef tallow was tested in two heavy-duty engines. The biodiesels were tested neat and as 20% by volume blends with a 15 ppm sulfur petroleum-derived diesel fuel. The test engines were a 2002 Cummins ISB and 2003 DDC Series 60. Both engines met the 2004 U.S. emission standard of 2.5 g/bhp-h NOx+HC (3.35 g/kW-h) and utilized exhaust gas recirculation (EGR). All emission tests employed the heavy-duty transient procedure as specified in the U.S. Code of Federal Regulations. Reduction in PM emissions and increase in NOx emissions were observed for all biodiesels in all engines, confirming observations made in older engines. On average PM was reduced by 25% and NOx increased by 3% for the two engines tested for a variety of B20 blends. These changes are slightly larger in magnitude, but in the same range as observed in older engines.

The use of early intake valve closing (EIVC) can lead to improvements in spark-ignition engine efficiency. One of the greatest barriers facing adoption of EIVC for high power-density applications is the challenge of boosting as EIVC strategies reduce volumetric efficiency. Turbochargers with variable nozzle turbines (VNT) have recently been developed for gasoline applications operating at high exhaust gas temperatures. The use of a single VNT as a boost device may provide a lower-cost option compared to two-stage boosting systems or 48 V electronic boost devices for some EIVC applications. A predictive model was created based on engine testing results from a 1.6 L turbocharged gasoline direct injection engine [1]. The model was tuned so that it predicted burn-rates and end-gas knock over an engine operating map with varying speeds, loads, compression ratios and fuel types.

Particle size distribution and number concentration were measured in the dilute exhaust of a heavy-duty diesel engine for steady-state and transient engine operation using two different dilution systems that included a full flow CVS that was coupled to an ejector pump (CVS-EP), and a double-ejector micro-dilution tunnel (DEMDT) that was connected to engine exhaust close to turbocharger outlet. Measurements were performed using a scanning mobility particle sizer (SMPS), an electrical low pressure impactor (ELPI), and a parallel flow diffusion battery (PFDB). Fuels with sulfur content of about 385 ppm and 1 ppm were used for this work. The PFDB performed well in measuring nanoparticles in the size range below 56 nm when compared with the SMPS. This was especially valid when a distinct log-normal size distribution in the size range below 56 nm in diameter, the upper size limit of the PFDB, was present.

The size and distribution of a vehicle’s tailpipe particulate emissions can have a strong impact on human health, especially if the particles are small enough to enter the human respiratory system. Gasoline direct injection (GDI) has been adopted widely to meet stringent fuel economy and CO2 regulations across the globe for recent engine architectures. However, the introduction of GDI has led to challenges concerning the particulate matter (PM) and particle number (PN) emissions from such engines. This study aimed to compare the particulate emissions of three SI combustion strategies: conventional SI, conventional stoichiometric low-pressure exhaust gas recirculation (LP-EGR), and Dedicated-EGR (D-EGR) at four specific test conditions. It was shown that the engine-out PM/PN for both the EGR strategies was lower than the conventional SI combustion under normal operating conditions. The test conditions were chosen to represent the WLTC test conditions.

The overall program objectives were three fold: assess the benefits and limitations of oxygenated diesel fuels on engine performance and emissions identify oxygenates most suitable for potential use in future diesel formulations based on physico-chemical properties (e.g. flash point), toxicity, biodegradability and estimated cost of production perform limited emissions and performance testing of the oxygenated diesel blends select at least two oxygenated compounds for advanced engine testing In Part 1 of this program which is described in this paper, an extensive literature review was conducted to identify potential oxygenates for blending into diesel fuels. As many as 71 oxygenates were identified for the initial screening process. Based on a set of physical and chemical properties, a screening methodology was developed to select the 8 oxygenates that will be eligible for engine testing.

Low-Speed pre-ignition (LSPI) in modern-day, heavily downsized, boosted, and direct-injection spark ignition (SI) engines is a well-known problem. Several mechanisms contribute towards stochastic pre-ignition (SPI), the most prominent being crevice material droplet induced and deposit induced pre-ignition mechanisms. The droplet mechanism is typically dominated by the detergent additives present in the lubricant formulation; more specifically calcium and sodium-based detergent additives correlate strongly with the increased LSPI rates. Deposits flaking off the combustion chamber surfaces can also induce LSPI under certain conditions. This study aimed to develop an optical method designed to investigate the nature of pre-ignition precursors. Southwest Research Institute (SwRI) utilized an optically accessible GM 2.0 L LHU engine to study the pre-ignition phenomenon and studied the nature of pre-ignition precursors using spectral information from one of the cylinders in this engine.

The dual-fuel combustion process of ethanol and n-heptane was characterized experimentally in an optically accessible engine and numerically through a chemical kinetic 3D-CFD investigation. Previously reported formaldehyde PLIF distributions were used as a tracer of low-temperature oxidation of straight-chained hydrocarbons and the numerical results were observed to be in agreement with the experimental data. The numerical and experimental evidence suggests that a change in the speed of flame propagation is responsible for the observed behavior of the dual-fuel combustion, where the energy release duration is increased and the maximum rate of pressure rise is decreased. Further, an explanation is provided for the asymmetrical energy release profile reported in literature which has been previously attributed to an increase in the diffusion-controlled combustion phase.

A zero-dimensional cycle simulation model coupled with a chemical equilibrium model and a two-zone combustion model has been extended to predict nitric oxide formation and emissions from spark-ignited, lean-burn natural gas engines. It is demonstrated that using the extended Zeldovich mechanism alone, the NOx emissions from an 8.1-liter, 6-cylinder, natural gas engine were significantly under predicted. However, by combining the predicted NOx formation from both the extended Zeldovich thermal NO and the Fenimore prompt NO mechanisms, the NOx emissions were predicted with fair accuracy over a range of engine powers and lean-burn equivalence ratios. The effect of injection timing on NOx emissions was under predicted. Humidity effects on NOx formation were slightly under predicted in another engine, a 6.8-liter, 6-cylinder, natural gas engine. Engine power was well predicted in both engines, which is a prerequisite to accurate NOx predictions.