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NOx reduction activity in an oxidizing exhaust gas was significantly improved by discharging non-thermal plasma and catalysts (plasma assisted catalysis). We investigated effective catalyst for plasma assisted catalysis in view of hydrocarbon-selective catalytic reduction(HC-SCR). Plasma assist was effective for γ-alumina and alkali or alkaline earth metals loaded zeolite and γ-alumina showed the highest NOx conversion among these catalysts. On the other hand, Plasma assist was not effective for Cu-ZSM-5 and Pt loaded catalyst. The NOx conversion for the plasma assisted γ-alumina decreased by formation of a deposit on the catalyst below 400°C. It is shown that indium loading on γ-alumina improved the NOx reduction activity and suppressed the degradation of the NOx reduction activity at 300°C with plasma assist.

Through the basic research of the plasma assisted catalyst system using DeNOx catalysts and the gas analysis of the system, its conceptual use for automobile diesel engine applications has been studied. This study has shown that the length between the plasma reactor and the catalyst reactor does not affect the NOx conversion. To obtain an efficient NOx conversion, the plasma should affect both the HC as the reductant and NOx at the same time. In the case of γ-Al2O3 and C3H6, the main component for NOx reduction was CH3CHO generated by the plasma. Under 250 deg. C, the temperature was too low for the γ-Al2O3 to become effective. Therefore, the NOx conversion became low. At 400 deg. C, the NOx conversion became high. However, at 600 deg. C, the CH3CHO for reducing NOx was not generated, and the NOx conversion decreased.