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The application of crash durable structural adhesives in modern cars design, to improve the driving durability, the overall vehicle stiffness, the crash resistance and to make real light weight constructions feasible is significantly gaining in importance. 1-component systems are already introduced in the market and used in automotive industries. Usually the use of these bonds in automotive industries is limited by a relatively low wash off resistance in the pre-treatment tanks of the paint shop. If no additional actions are taken, there is a severe risk of wash off of the adhesives up to the partial loss in functionality. Respectively contamination of the pre-treatment tanks and aftereffects damage the surface of the coated cars. To avoid wash off a thermal process (oven) to pre-gel the adhesive in the flanges of the Body-In-White (BIW)- bodies before entering the pre-treatment utility is necessary. This is a save but cost intensive solution.

The destruction of low concentrations (<600 ppm) of nitric oxide using a low-temperature, dielectric barrier/packed-bed corona reactor has been studied. We compare the chemistry and energy efficiencies observed using various packing materials in warm moist air under oxidative (lean-burn) conditions. Measurements of NO and NOx removal in the effluent gas were made as a function of energy dissipated in the reactor. Changes in the observed fate of NO as a function of the packing material are discussed.

Since their introduction in automobiles, polymeric materials have enabled designers and engineers to differentiate products based on performance attributes, mechanical response, aesthetics, and manufacturing techniques. A large segment of these applications utilizes polypropylene (PP) resins. One of the attractive features of PP polymers is the ability to tailor their mechanical, thermal and processing performance envelope via modification of their composition and the addition of fillers. Key to the successful application of PP resins in structural systems is the ability of designers and engineers to understand the material response and to properly model the behavior of PP structures upon different mechanical and thermal loading conditions.

To meet automotive legal, consumer and insurance test requirements, the process for designing energy absorption countermeasures usually comprises Finite Element simulations of the specified test. Finite element simulations are used first to see if there is a need for an Energy Absorption countermeasure at all and if so, what type, material and shape. A widely used class of energy absorption countermeasures in automotive interior applications is honeycomb extruded polypropylene foams (HXPP). Under compression, these foams exhibit a constant plateau stress until late densification. This enables these foams to minimize packaging space for a given amount of energy to be absorbed or maximize energy absorption for a given packaging space. Robust and easy to use isotropic CAE material models have been developed for HXPP, however the true material properties are anisotropic and such a material model could be necessary in some cases.

The hole stretchability of two Aluminum Alloys (AA6111 and AA6022) are studied by using a two stages integrated finite element framework where the edge geometry and edge damages from the hole piercing processes were considered in the subsequent hole expansion processes. Experimentally it has been found that AA6022 has higher hole expansion ratios than those of AA6111. This observation has been nicely captured by finite element simulations. The main cause of differences have been identified to the volume fractions of the random distributed second phase hard particles which play a critical role in determining the fracture strains of the materials.

Automobile body and truck cab structures are composed primarily of stampings formed from monolithic and constant gage blanks. Cost and weight penalties can arise when strength or other requirements in one small area of the part leads to the use of a material or gage that is overmatched to the needs of the rest of the stamping. Tailor Welded Blanks (TWBs) are hybrid sheet products composed of either different materials or different thickness sheets that are joined together, then subjected to a stamping operation to create a formed assembly. The strategy is employed generally to save weight and material costs in the formed assembly by placing higher strength or thicker sections only where needed. The forming or stamping process requires the joint to be severely deformed along with the parent sheets. Aluminum TWBs for automotive applications are particularly problematic because of the low formability of aluminum weld metal.

The effect of hydroforming on the mechanical properties and dynamic crush behaviors of tapered aluminum 6063-T4 tubes with octagonal cross section are investigated by experiments. First, the thickness profile of the hydroformed tube is measured by non-destructive examination technique using ultrasonic thickness gauge. The effect of hydroforming on the mechanical properties of the tube is investigated by quasi-static tensile tests of specimens prepared from different regions of the tube based on the thickness profile. The effect of hydroforming on the dynamic crush behaviors of the tube is investigated by axial crush tests under dynamic loads. Specimens and tubes are tested in two different heat treatment conditions: hydroformed-T4 (as-received) and T6. The results of the quasi-static tensile tests for the specimens in hydroformed-T4 condition show different amounts of work hardening depending on the regions, which the specimens are prepared from.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

Modular front-end carriers to pre-assemble front-end components such as cooling systems, lights, and bumper beam have been in production in different vehicles for several years. Compression molded or overmolded steel/plastic carriers have traditionally been used. The present paper explains the design, material options, and engineering optimization of a composite front-end carrier, which utilizes long glass fiber injection moldable resins and adhesively bonded steel reinforcements. Experimental evaluation of prototypes shows the system met the functional performance requirements at minimum weight.

We developed a non-destructive and non-contact method for measuring stress at the mid-plane of tempered glass plates that uses Bragg scattering from a pair of thermal gratings. These gratings are formed by 1064 nm beams from a seeded Nd:YAG laser and we measure the polarization state of light from a 532 nm beam that scatters from both these thermal gratings. The change in polarization of the doubly scattered light with separation between the two gratings allows measurement of the in-plane stress. Stress measurements are reported.

The catalytic activity of selected materials (BaY and NaY zeolites, and γ-alumina) for selective NOx reduction in combination with a non-thermal plasma was investigated. Our studies suggest that aldehydes, formed during the plasma treatment of simulated diesel exhaust, are the important species for the reduction of NOx to N2. Indeed, all materials that are active in plasma-assisted catalysis were found to be very effective for the thermal reduction of NOx in the presence of aldehydes. For example, the thermal catalytic activity of a BaY zeolite with aldehydes gives 80-90% NOx removal at 250°C with 200ppm NOx at the inlet and a VHSV=12,000 h-1. The hydrocarbon reductants, n-octane and 1-propyl alcohol, have also shown high thermal catalytic activity for NOx removal over BaY, NaY and γ-alumina.

We describe a study to identify potential biofuels that enable advanced spark ignition (SI) engine efficiency strategies to be pursued more aggressively. A list of potential biomass-derived blendstocks was developed. An online database of properties and characteristics of these bioblendstocks was created and populated. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a bioblendstock met the requirements for advanced SI engines. Criteria included melting point (or cloud point) < -10°C and boiling point (or T90) <165°C. Compounds insoluble or poorly soluble in hydrocarbon were eliminated from consideration, as were those known to cause corrosion (carboxylic acids or high acid number mixtures) and those with hazard classification as known or suspected carcinogens or reproductive toxins.

Mixing controlled compression ignition, i.e., diesel engines are efficient and are likely to continue to be the primary means for movement of goods for many years. Low-net-carbon biofuels have the potential to significantly reduce the carbon footprint of diesel combustion and could have advantageous properties for combustion, such as high cetane number and reduced engine-out particle and NOx emissions. We developed a list of over 400 potential biomass-derived diesel blendstocks and populated a database with the properties and characteristics of these materials. Fuel properties were determined by measurement, model prediction, or literature review. Screening criteria were developed to determine if a blendstock met the basic requirements for handling in the diesel distribution system and use as a blend with conventional diesel. Criteria included cetane number ≥40, flashpoint ≥52°C, and boiling point or T90 ≤338°C.

The Pacific Northwest National Laboratory (PNNL) and the Volpentest Hazardous Materials Management and Emergency Response (HAMMER) Training and Education Center are helping to prepare emergency responders and permitting/code enforcement officials for their respective roles in the gradual transition to the hydrogen economy. Safety will be a critical component of the anticipated hydrogen transition. Public confidence goes hand in hand with perceived safety to such an extent that, without it, the envisioned transition is unlikely to occur. Stakeholders and the public must be reassured that hydrogen, although very different from gasoline and other conventional fuels, is no more dangerous. Ensuring safety in the hydrogen infrastructure will require a suitably trained emergency response force for containing the inevitable incidents as they occur, coupled with knowledgeable code officials to ensure that such incidents are kept to a minimum.

A noticeable degree of inconsistent forming behaviors has been observed for the 1st generation advanced high strength steels (AHSS) in production, and they appear to be associated with the inherent microstructural-level inhomogeneities for various AHSS. This indicates that the basic material property requirements and screening methods currently used for the mild steels and high strength low alloys (HSLA) are no longer sufficient for qualifying today's AHSS. In order to establish more relevant material acceptance criteria for AHSS, the fundamental understandings on key mechanical properties and microstructural features influencing the local formability of AHSS need to be developed. For this purpose, in this study, DP980 was selected as model steels and eight different types of DP980 sheet steels were acquired from various steel suppliers.

A new advanced ceramic material (ACM) has been developed and examined for diesel emission control systems, especially for diesel particulate filter (DPF) applications. Lab tests have shown that ACM possesses suitable mechanical and chemical properties for a durable DPF. Engine dynamometer tests have shown that a DPF made from ACM possesses high performance in the key application requirements of high filtration efficiency, low filtration back pressure, fast regeneration, and suitability for catalyst coating applications. The experimental results from this investigation demonstrate that a DPF made from ACM can be used for advanced diesel PM emission control systems, including potential four-way diesel catalytic converter systems.

This paper describes a method for predicting structural failure probabilities for automotive windshields. The predictive model is supported by the data from strength tests performed on specimens of automotive glass. Evaluations of stresses can be based on finite element calculations, or measurements of the residual stresses that arise from fabrication. Failure probabilities for each subregion of a windshield are estimated from the local state of stress, the surface area or length (for edge elements) of the subregion, and statistical distributions of glass strengths. Example calculations are presented that show the relative contributions of edge stresses, surface stresses and residual stresses to calculated failure probabilities.

In this paper, a three-dimensional (3D) microstructure-based finite element modeling method (i.e., extrinsic modeling method) is developed, which can be used in examining the effects of porosity on the ductility/fracture of Mg castings. For this purpose, AM60 Mg tensile samples were generated under high-pressure die-casting in a specially-designed mold. Before the tensile test, the samples were CT-scanned to obtain the pore distributions within the samples. 3D microstructure-based finite element models were then developed based on the obtained actual pore distributions of the gauge area. The input properties for the matrix material were determined by fitting the simulation result to the experimental result of a selected sample, and then used for all the other samples’ simulation. The results show that the ductility and fracture locations predicted from simulations agree well with the experimental results.

Recently, automotive engineers have been looking at rigid polyurethane foam systems for the advantages their application brings to vehicle design and performance. The benefits range from NVH management achieved through effective body cavity sealing and improved structural dynamics, to enhanced vehicle crashworthiness. These benefits can be realized through application of polyurethane foam systems designed for energy management. These systems offer multifunctional, low cost solutions to traditional approaches and can be modeled early in the vehicle design stage. In many cases, the overall vehicle mass is reduced as reinforcements are eliminated and/or sheet metal thickness is decreased. Dow Automotive has developed a family of water blown polyurethane foams specifically for these applications. Development has focused on foam systems designed for impact optimization, allowing OEM's to optimize the body structure content.

The application of two-component polyurethane (PU) foam materials for acoustical and structural performance enhancements in vehicle structures have increased significantly in the past ten years. The benefits include NVH management (through effective cavity sealing), body stiffness improvements and energy management in crash applications. These PU foams can either be pumped into body cavities in the OEM assembly plants (bulk applied) or can be pre-molded into Structural Foam Inserts (SFI) and installed in the body-shop prior to full frame assembly. The choice of application type depends on vehicle-specific requirements and assembly plant criteria. The chemistry, plant application and benefits associated with bulk PU foam has already been cited in previous work.1, 2, 3 This paper showcases BETAFOAM™ SFI technology developed by Dow Automotive that complements traditional bulk foam technology.