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A new gas phase kinetic model using Westbrook's gas phase n-heptane model and Frenklach's soot model was constructed. This model was then used to predict the impact on PAH formation as an indices of soot formation on ethanol/diesel fuel blends. The results were then compared to soot levels measured by various researchers. The ignition delay characteristics of ethanol were validated against experimental results in the literature. In this paper the results of the model and the comparison with experimental results will be discussed along with implications on the method of incorporation of additives and alternative fuels.

Experiments have been conducted in a laminar flow system and in a research engine to investigate the effect of additives on the combustion of gasoline-like fuels. The purpose of the laminar system is to enable rapid screening of additives to determine which, if any, have an enhancing effect on the early stages of combustion, especially under conditions of poor fuel vaporization which exist during cold-start in a spark ignited engine and which make flame propagation difficult to start and sustain. The base fuel used in the laminar and engine systems was a 9 component mixture formulated to simulate those components of gasoline expected to be present in the vapor phase in the intake system of an engine under cold-start conditions. In the laminar system, the pre-mixed, pre-vaporized fuel-air mixture is ignited and a time history of the combustion generated, hydroxyl radical chemiluminescence is recorded.