Search Results

Cu- and Fe-zeolite SCR catalysts emerged in recent years as the primary candidates for meeting the increasingly stringent lean exhaust emission regulations, due to their outstanding activity and durability characteristics. It is commonly known that Cu-zeolite catalysts possess superior activity to Fe-zeolites, in particular at low temperatures and sub-optimal NO₂/NOx ratios. In this work, we elucidate some underlying mechanistic differences between these two classes of catalysts, first based on their NO oxidation abilities, and then based on the relative properties of the two types of exchanged metal sites. Finally, by using the ammonia coverage-dependent NOx performance, we illustrate that state-of-the-art Fe-zeolites can perform better under certain transient conditions than in steady-state.

An LNT + SCR diesel aftertreatment system was developed in order to meet the 2010 US HD EPA on-road, and tier 4 US HD EPA off-road emission standards. This system consists of a fuel reformer (REF), lean NOx trap (LNT), catalyzed diesel particulate filter (DPF), and selective catalytic reduction (SCR) catalyst arranged in series to reduce tailpipe nitrogen oxides (NOx) and particulate matter (PM). This system utilizes a REF to produce hydrogen (H2), carbon monoxide (CO) and heat to regenerate the LNT, desulfate the LNT, and actively regenerate the DPF. The NOx stored on the LNT is reduced by the H2 and CO generated in the REF converting it to nitrogen (N2) and ammonia (NH3). NH3, which is normally an undesired byproduct of LNT regeneration, is stored in the downstream SCR which is utilized to further reduce NOx that passes through the LNT. Engine exhaust PM is filtered and trapped by the DPF reducing the tailpipe PM emissions.

Diesel oxidation catalyst (DOC) is one of the critical catalyst components in modern diesel aftertreatment systems. It mainly converts unburned hydrocarbon (HC) and CO to CO2 and H2O before they are released to the environment. In addition, it also oxidizes a portion of NO to NO2, which improves the NOx conversion efficiency via fast SCR over the downstream selective catalytic reduction (SCR) catalyst. HC light-off tests, with or without the presence of NOx, has been typically used for DOC evaluation in laboratory. In this work, we aim to understand the influences of DOC light-off experimental conditions, such as initial temperature, initial holding time, HC species, with or without the presence of NOx, on the DOC HC light-off behavior. The results indicate that light-off test with lower initial temperature and longer initial holding time (at its initial temperature) leads to higher DOC light-off temperature.

Cu/CHA catalysts have been widely used in the industry, due to their desirable performance characteristics including the unmatched hydrothermal stability. While broadly recognized for their outstanding activity at or above 200°C, these catalysts may not show desired levels of NOx conversion at lower temperatures. To achieve high NOx conversions it is desirable to have NO2/NOx close to 0.5 for fast SCR. However even under such optimal gas feed conditions, sustained use of Cu/CHA below 200°C leads to ammonium nitrate formation and accumulation, resulting in the inhibition of NOx conversion. In this contribution, the formation and decomposition of NH4NO3 on a commercial Cu/CHA catalyst have been investigated systematically. First, the impact of NH4NO3 self-inhibition on SCR activity as a function of temperature and NO2/NOx ratios was investigated through reactor testing.

Sustained NOx reduction at low temperatures, especially in the 150-200 °C range, shares some similarities with the more commonly discussed cold-start challenge, however, poses a number of additional and distinct technical problems. In this project, we set a bold target of achieving and maintaining 90% NOx conversion at the SCR catalyst inlet temperature of 150 °C. This project is intended to push the boundaries of the existing technologies, while staying within the realm of realistic future practical implementation. In order to meet the resulting challenges at the levels of catalyst fundamentals, system components, and system integration, Cummins has partnered with the DOE, Johnson Matthey, and Pacific Northwest National Lab and initiated the Sustained Low-Temperature NOx Reduction program at the beginning of 2015 and completed in 2017.

A detailed study, by finite element method (FEM), was conducted on an automotive engine exhaust valve subject to various loads (i.e. spring load, combustion pressure load, temperature profile and valve impact closing velocity). The 3D nonlinear (contact element and temperature-dependent) thermal-mechanical model was constructed and implicit time integration method was employed in transient dynamics under impact velocity. The predicted temperatures and maximum valve stress under impact velocity via FEM were compared with the measured test data, which were in good agreement. In addition, this study finds that the energy transfer during valve closing in normal engine operation is mainly conservative, and a linear relation exists between valve closing velocity and maximum stem stress, that was also confirmed by both test data and analytical expression presented using elastic wave and vibration theory.

The low-temperature performance characteristics of a commercial lean NOX trap catalyst were evaluated using infra-red thermography (IRT) before and after a high-temperature aging step. Reaction tests included propylene oxidation, oxygen storage capacity measurements, and simulated cycling conditions for NOX reduction, using H₂ as the reductant during the regeneration step of the cycle. Testing with and without NO in the lean phase showed thermal differences between the reductant used in reducing the stored oxygen and that for nitrate decomposition and reduction. IRT clearly demonstrated where NOX trapping and regeneration were occurring spatially as a function of regeneration conditions, with variables including hydrogen content of the regeneration phase and lean- and rich-phase cycle times.

Production NO sensors have a strong cross-sensitivity to ammonia which limits their use for closed-loop SCR control and diagnostics since increases in sensor output can be caused by either gas component. Recently, Ammonia/NO Ratio (ANR) perturbation methods have been proposed for determining the dominant component in the post-SCR exhaust as part of the overall SCR control strategy, but these methods or the issue of sensor cross-sensitivity have not been critically evaluated or studied in their own right. In this paper the dynamic sensor direct- and cross-sensitivities are estimated from experimental FTIR data (after compensating for the dynamics of the gas sampling system) and compared to nominal values provided by the manufacturer. The ANR perturbation method and the use of different input excitations are then discussed within an analytical framework, and applied to experimental data from a large diesel engine.

The performance of an organic Rankine cycle (ORC) that recovers heat from the exhaust of a heavy-duty diesel engine was simulated. The work was an extension of a prior study that simulated the performance of an experimental ORC system developed and tested at Oak Ridge National laboratory (ORNL). The experimental data were used to set model parameters and validate the results of that simulation. For the current study the model was adapted to consider a 15 liter turbocharged engine versus the original 1.9 liter light-duty automotive turbodiesel studied by ORNL. Exhaust flow rate and temperature data for the heavy-duty engine were obtained from Southwest Research Institute (SwRI) for a range of steady-state engine speeds and loads without EGR. Because of the considerably higher exhaust gas flow rates of the heavy-duty engine, relative to the engine tested by ORNL, a different heat exchanger type was considered in order to keep exhaust pressure drop within practical bounds.

An aftertreatment system for medium and heavy-duty diesel engines has been modeled for U.S. 2010 application. The aftertreatment system is comprised of a lean NOx trap (LNT) and an ammonia selective catalytic reduction (SCR) catalyst in series. Descriptions of the fully transient, one-dimensional LNT and SCR models are presented. The models simulate flow, heat transfer, and chemical reactions in the LNT and SCR catalysts. The models can be used to predict catalyst performance over a range of operating conditions and driving cycles. Simulated results of NOx conversion efficiency, species concentrations, and gas temperature were compared to experimental data for a 13-mode test. The model results showed the LNT-SCR model predicts system performance with reasonable accuracy in comparison to experimental data. Therefore, two model applications were investigated. First, LNT and SCR volumes were varied to examine the effect on NOx conversion efficiency and NH3 production.

Heavy-duty diesel on-board diagnostics (OBD) regulations are being phased in around the world with varying degrees of similarity. This is occurring at a time when heavy-duty diesel emission regulations are driving complex and elaborate emission control strategies. Unique circumstances led the European heavy-duty diesel market to adopt selective catalytic reduction (SCR) as the primary solution for meeting strict Euro 4 emission levels. This paper is a review of the challenges of diagnosing an SCR system based on the Euro 4 OBD regulation and considers the future challenges of SCR diagnostics that lie ahead in the North American market.

In April 2003, a small field study was initiated to evaluate the effect of lube oil formulations on ash accumulation in heavy-duty diesel DPFs. Nine (9) Fuel Delivery Trucks were retrofitted with passive diesel particulate filters and fueled with ultra low sulfur diesel which contains less than 15 ppm sulfur. Each vehicle operated in the field for 18 months or approximately 160,000 miles (241,401 km) using one of three lube oil formulations. Ash accumulation was determined for each vehicle and compared between the three differing lube oil formulations. Ash analyses, used lube oil analysis and filter substrate evaluations were performed to provide a complete picture of DPF operations. The evaluation also examined some of the key parameters that allows for the successful implementation of the passive DPF in this heavy-duty application.

A technique for rapid in situ measurement of the fuel dilution of oil in a diesel engine is presented. Fuel dilution can occur when advanced in-cylinder fuel injection techniques are employed for the purpose of producing rich exhaust for lean NOx trap catalyst regeneration. Laser-induced fluorescence (LIF) spectroscopy is used to monitor the oil in a Mercedes 1.7-liter engine operated on a dynamometer platform. A fluorescent dye suitable for use in diesel fuel and oil systems is added to the engine fuel. The LIF spectra are monitored to detect the growth of the dye signal relative to the background oil fluorescence; fuel mass concentration is quantified based on a known sample set. The technique was implemented with fiber optic probes which can be inserted at various points in the engine oil system. A low cost 532-nm laser diode was used for excitation.

Accumulation of lubricant and fuel derived ash in the diesel particulate filter (DPF) during vehicle operation results in a significant increase of pressure drop across the after-treatment system leading to loss of fuel economy and reduced soot storage capacity over time. Under certain operating conditions, the accumulated ash and/or soot cake layer can collapse resulting in ash deposits upstream from the typical ash plug section, henceforth termed mid-channel ash deposits. In addition, ash particles can bond (either physically or chemically) with neighboring particles resulting in formation of bridges across the channels that effectively block access to the remainder of the channel for the incoming exhaust gas stream. This phenomenon creates serious long-term durability issues for the DPF, which often must be replaced. Mid-channel deposits and ash bridges are extremely difficult to remove from the channels as they often sinter to the substrate.

An advanced exhaust aftertreatment system is characterized following end-of-life catalyst aging to meet final Tier 4 off-highway emission requirements. This system consists of a fuel dosing system, mixing elements, fuel reformer, lean NOx trap (LNT), diesel particulate filter (DPF), and a selective catalytic reduction (SCR) catalyst. The fuel reformer is used to generate hydrogen (H2) and carbon monoxide (CO) from injected diesel fuel. These reductants are used to regenerate and desulfate the LNT catalyst. NOx emissions are reduced using the combination of the LNT and SCR catalysts. During LNT regeneration, ammonia (NH3) is intentionally released from the LNT and stored on the downstream SCR catalyst to further reduce NOx that passed through the LNT catalyst. This paper addresses system durability as the catalysts were aged to 500 desulfation events using an off-highway diesel engine.

An operational challenge associated with SCR catalysts is the NH3 slip control, particularly for commercial small pore Cu-zeolite formulations as a consequence of their significant ammonia storage capacity. The desorption of NH3 during increasing temperature transients is one example of this challenge. Ammonia slipping from SCR catalyst typically passes through a platinum based ammonia oxidation catalyst (AMOx), leading to the formation of the undesired byproducts NOx and N2O. We have discovered a distinctive characteristic, an overlapping NH3 desorption and oxidation, in a state-of-the-art Cu-zeolite SCR catalyst that can minimize NH3 slip during temperature transients encountered in real-world operation of a vehicle.

Mitigation of ammonia slip from SCR system is critical to meeting the evolving NH₃ emission standards, while achieving maximum NOx conversion efficiency. Ammonia slip catalysts (ASC) are expected to balance high activity, required to oxidize ammonia across a broad range of operating conditions, with high selectivity of converting NH₃ to N₂, thus avoiding such undesirable byproducts as NOx or N₂O. In this work, new insights into the behavior of an advanced ammonia slip catalyst have been developed by using accelerated progressive catalyst aging as a tool for catalyst property interrogation. The overall behavior was deconstructed to several underlying functions, and referenced to an active but non-selective NH₃ oxidation function of a diesel oxidation catalyst (DOC) and to the highly selective but minimally active NH₃ oxidation function of an SCR catalyst.

The paper covers the NOx performance evaluation of an LNT + SCR system designed to meet the 2010 on-highway heavy-duty (HD) US EPA emission standards. The system combines a fuel reformer catalyst (REF), lean NOx trap (LNT), diesel particulate filter (DPF), and selective catalytic reduction (SCR) in series, to reduce engine-out NOx and PM. System NOx reduction performance was verified in an engine dynamometer test cell, using a 2007 7.6L medium-duty engine. System NOx performance was characterized using fresh LNT and SCR along with hydrothermal aged LNT and fresh SCR. Test results show levels consistent with EPA 2010 limits under various test conditions. Catalysts performance was characterized at eight steady engine-operating conditions (A100, B50, B75, A75, B100, C100, C75, C50, across a 13-mode Supplemental Emission Test (SET), and an on-highway Heavy Duty Federal Test Procedure (HD-FTP).

The high global warming potential of nitrous oxide (N₂O) led to its recent inclusion in the list of regulated pollutants under the emerging greenhouse gas regulations. While N₂O can be present in small quantities among the combustion products, it can also be generated as a minor byproduct in various types of aftertreatment systems. In this work, a systematic review of sources of N₂O is presented, along with the potential mechanisms of formation in a typical selective-catalytic-reduction-based diesel exhaust aftertreatment system. It is demonstrated that diesel oxidation catalysts (DOC), selective catalytic reduction (SCR) catalyst, and ammonia slip catalyst (ASC) can all potentially contribute to N₂O formation, depending on the catalyst material and exhaust gas conditions, as well as aftertreatment operation strategies. Furthermore, catalysts used in SCR aftertreatment system are also shown to decompose and/or reduce N₂O to N₂ under select conditions.

Based on our error budget analysis, the urea SCR aftertreatment system is uncontrollable under EPA 2007-emission level without an effective closed-loop control strategy. The objective of the closed-loop control is to improve transient response as well as reduce the steady state control error. But the inherent large dead time in the urea SCR aftertreatment system makes the closed-loop control a challenge. In this paper, an innovative closed-loop control architecture is introduced, which combines model-based feedforward control with variable gain-scheduling feedback control. Transient response is improved with the inverse-dynamic feedforward control and the variable-gain closed-loop control. The steady-state response is improved with the closed-loop control. Based on this new strategy, a controller is designed and validated under the simulation and test cell environment. Comparison with the baseline open-loop controller is also conducted. Finally, some conclusions are presented.