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Styrene, or ethylbenzene, is mainly used as a monomer for the production of polymers, most notably Styrofoam. In the synthetis of styrene, the feedstock of benzene and ethylene is converted into aromatic oxygenates such as benzaldehyde, 2-phenyl ethanol and acetophenone. Benzaldehyde and phenyl ethanol are low value side streams, while acetophenone is a high value intermediate product. The side streams are now principally rejected from the process and burnt for process heat. Previous in-house research has shown that such aromatic oxygenates are suitable as diesel fuel additives and can in some cases improve the soot-NOx trade-off. In this study acetophenone, benzaldehyde and 2-phenyl ethanol are each added to commercial EN590 diesel at a ratio of 1:9, with the goal to ascertain whether or not the lower value benzaldehyde and 2-phenyl ethanol can perform on par with the higher value acetophenone. These compounds are now used in pure form.

In an earlier study, a novel type of diesel fuel injector was proposed. This prototype injects fuel via porous (sintered) micro pores instead of via the conventional 6-8 holes. The micro pores are typically 10-50 micrometer in diameter, versus 120-200 micrometer in the conventional case. The expected advantages of the so-called Porous Fuel Air Mixing Enhancing Nozzle (PFAMEN) injector are lower soot- and CO2 emissions. However, from previous in-house measurements, it has been concluded that the emissions of the porous injector are still not satisfactory. Roughly, this may have multiple reasons. The first one is that the spray distribution is not good enough, the second one is that the droplet sizing is too big due to the lack of droplet breakup. Furthermore air entrainment into the fuel jets might be insufficient. All reasons lead to fuel rich zones and associated soot formation.

The Flamelet Generated Manifold (FGM) method is a promising technique in engine combustion modeling to include tabulated chemistry. Different methodologies can be used for the generation of the manifold. Two approaches, based on igniting counterflow diffusion flamelets (ICDF) and homogeneous reactors (HR) are implemented and compared with Engine Combustion Network (ECN) experimental database for the baseline n-heptane case. Before analyzing the combustion results, the spray model is optimized after performing a sensitivity study with respect to turbulence models, cell sizes and time steps. The standard High Reynolds (Re) k-ε model leads to the best match of all turbulence models with the experimental data. For the convergence of the mixture fraction field an appropriate cell size is found to be smaller than that for an adequate spray penetration length which appears to be less influenced by the cell size.