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RADIATION can produce almost instantaneous failure of modern aircraft lubricants, tests at Southwest Research Institute show. Two types of failures demonstrated are rapid viscosity rise and loss of heat conductivity. Furthermore, it was found that lubricants can become excessively corrosive under high-level radiation. Generally speaking, the better lubricants appeared to improve in performance while marginal ones deteriorated to a greater extent under radiation. When the better lubricants were subjected to static irradiation prior to the deposition test, there was a minor increase in deposition number as the total dose was increased.

All around the world, steps are being taken to improve the quality of our environment. Prominent among these are the definition, implementation, and attainment of increasingly stringent emissions regulations for all types of engines, including off-highway diesels. These rigorous regulations have driven use of technologies like after-treatment, advanced air systems, and advanced fuel systems. Fuel dispensed off-highway is routinely and significantly dirtier than fuel from on-highway outlets. Furthermore, fuels used in developing countries can be up to 30 times dirtier than the average fuels in North America. Poor fuel cleanliness, coupled with the higher pressures and performance demands of modern fuel systems, create life challenges greater than encountered with cleaner fuels. This can result in costly disruption of operations, loss of productivity, and customer dissatisfaction in the off-highway market.

The objectives of this project were to investigate the corrosivity of condensate in a stoichiometric spark-ignited (SI) engine when running exhaust gas recirculation (EGR) and to determine the effects of sulfur-in-fuel on corrosion. A 2.0 L turbocharged direct-injected SI engine was operated with low-pressure EGR for this study. The engine was instrumented for visual, thermodynamic, and electrochemical analyses to determine the potential for corrosion at locations where condensation was deemed likely in a low-pressure loop EGR (LPL-EGR) engine. The electrochemical analysis was performed using multi-electrode array (MEA) corrosion probes. Condensate was also collected and analyzed. These analyses were performed downstream of both the charge air cooler (CAC) and the EGR cooler. It was found that while conditions existed for sulfuric acid to form with high-sulfur fuel, no sulfuric acid was detected by any of the measurement methods.

This paper summarizes the validation testing of the Horiba Instruments OBS-2200 gaseous portable emissions measurement system (PEMS) for in-use compliance testing per Title 40 of the Code of Federal Regulations (CFR) Part 1065.920 (Section 1065.920). The qualification process included analyzer verifications as well as engine testing on a model-year 2007 heavy-duty diesel engine produced by Volvo Powertrain. The measurements of brake-specific emissions with the OBS-2200 were compared to those of a CFR Part 1065-compliant CVS test cell over a series of not-to-exceed (NTE) events. The OBS-2200 passed all linearity verifications and analyzer checks required of PEMS. Engine test validation was achieved for all three regulated gaseous emissions (CO, NMHC, and NOX) per 40 CFR Part 1065.920(b)(5)(i), which requires a minimum of 91 percent of the measurement allowance adjusted deltas to be less than or equal to zero.

A family of cross-linkable acrylic copolymer resins - which uniquely have a thermoplastic “B-stage” that enables thermoplastic prepregs and semi-finished goods to be produced - is providing the opportunity to manufacture durable automotive interior trim-panel substrates with comparable or higher performance at lower weight and fewer processing steps than common thermoplastic and thermoset composites long used in such applications. Owing to their special chemistry and very-low initial viscosity, the acrylic copolymers provide excellent wetout / impregnation of fibrous or particulate reinforcements, facilitating the production of composite parts with very-high fiber volume fractions (FVFs). Loading levels as high as 70-90% have already been achieved with natural fibers. In the presence of heat and pressure, the material cross-links to form durable copolymers with excellent thermo-mechanical properties.

Transmission of light through automotive topcoat and primer layers can lead to degradation of the underlying electrocoat layer and to topcoat delamination. In order to protect against this, it is critical that transmission of both ultraviolet wavelengths and certain visible wavelengths be effectively blocked by the topcoat and primer layers. The clearcoat, basecoat and primer each have their own role and combine to protect against light transmission. The transmittance of these combined layers is typically measured by the Integrating Sphere UV-Visible Spectrophotometer. It would both simplify measurement of the topcoat systems and allow better system modeling if these layers could be measured separately and combined mathematically. We demonstrate here that absorbing and reflecting pigments can be effectively modeled using the Beer-Lambert law while results for scattering pigments are consistent with the Kubelka-Munk theory.

The Exhaust Composition Transient Operation LaboratoryTM (ECTO-LabTM) is a burner system developed at Southwest Research Institute (SwRI) for simulation of IC engine exhaust. The current system design requires metering and combustion of nitromethane in conjunction with the primary fuel source as the means of NOX generation. While this method affords highly tunable NOX concentrations even over transient cycles, no method is currently in place for dictating the speciation of nitric oxide (NO) and nitrogen dioxide (NO2) that constitute the NOX mixture. NOX generated through combustion of nitromethane is dominated by NO, and generally results in an NO2:NOX ratio of < 5 %. Generation of any appreciable quantities of NO2 is therefore dependent on an oxidation catalyst to oxidize a fraction of the NO to NO2.

The history and state of the art use of pigments known as transparent titanium dioxides in automotive coatings is described. This pigment, also known as microfine TiO2, produces a unique and patented color effect in combination with Al flake pigments via Rayleigh light scattering. The potential for styling new “effect colors” has been investigated extensivley at BASF Corporation. Early feasibility and durability problems have been resolved with a better understanding of the mechanisms responsible for color effect and film degradation in sun light. Florida exposure data in both solventborne and waterborne coatings systems has shown this pigment to be very durable when used within certain formulating guide lines. Critical is the choice of pigment particle size and encapsulation chemistry. First used in 1989 in a color styled for the Ford Motor Company, production colors have expanded to other US and Japanese car manufacturers.

Octane appetite of modern engines has changed as engine designs have evolved to meet performance, emissions, fuel economy and other demands. The octane appetite of seven modern vehicles was studied in accordance with the octane index equation OI=RON-KS, where K is an operating condition specific constant and S is the fuel sensitivity (RONMON). Engines with a displacement of 2.0L and below and different combinations of boosting, fuel injection, and compression ratios were tested using a decorrelated RONMON matrix of eight fuels. Power and acceleration performance were used to determine the K values for corresponding operating points. Previous studies have shown that vehicles manufactured up to 20 years ago mostly exhibited negative K values and the fuels with higher RON and higher sensitivity tended to perform better.

Radioactive tracer technology is an important tool for measuring component wear on a real-time basis and is especially useful in measuring engine wear as it is affected by combustion system operation and lubricant performance. Combustion system operation including the use of early and/or late fuel injection and EGR for emissions control can have a profound effect on aftertreatment contamination and engine reliability due to wear. Liner wear caused by localized fuel impingement can lead to excessive oil consumption and fuel dilution can cause excessive wear of rings and bearings. To facilitate typical wear measurement, the engine's compression rings and connecting rod bearings are initially exposed to thermal neutrons in a nuclear reactor to produce artificial radioisotopes that are separately characteristic of the ring and bearing wear surfaces.

Radioactive tracer technology (RAT) is an important tool in measuring component wear in an operating engine on a real-time basis. This paper will discuss the use of RAT to study and evaluate boundary lubricant and surfactant chemistries aimed at providing benefits in wear control. In particular, RAT was employed to study ring and bearing wear as a function of engine operating condition (speed, load, and temperature) and lubricant characteristics. Prior to testing, the engine's compression rings and connecting rod bearings were subjected to bulk thermal neutron bombardment in a nuclear reactor to produce artificial radioisotopes that were separately characteristic of the ring and bearing wear surfaces. The irradiated parts were installed in the test engine, after which testing to a specific test matrix was accomplished.

Nitrites have long been added to heavy-duty coolant to inhibit iron cylinder liner corrosion initiated by cavitation. However, in heavy-duty use, nitrites deplete from the coolant, which then must be refortified using supplemental coolant additives (SCA's). Recently, carboxylates have also been found to provide excellent cylinder liner protection in heavy-duty application. Unlike nitrites, carboxylate inhibitors deplete slowly and thus do not require continual refortification with SCA's. In the present paper laboratory aging experiments shed light on the mechanism of cylinder liner protection by these inhibitors. The performance of carboxylates, nitrites and mixtures of the two inhibitors are compared. Results correlate well with previously published fleet data. Specifically, rapid nitrite and slow carboxylate depletion are observed. More importantly, when nitrite and carboxylates are used in combination, nitrite depletion is repressed while carboxylates deplete at a very slow rate.

The impact of additive and oil chemistry on low speed pre-ignition (LSPI) was evaluated. An additive metals matrix varied the levels of zinc dialkyldithiophosphate (ZDDP), calcium sulfonate, and molybdenum within the range of commercially available engine lubricants. A separate test matrix varied the detergent chemistry (calcium vs. magnesium), lubricant volatility, and base stock chemistry. All lubricants were evaluated on a LSPI test cycle developed by Southwest Research Institute within its Pre-Ignition Prevention Program (P3) using a GM LHU 2.0 L turbocharged GDI engine. It was observed that increasing the concentration of calcium leads to an increase in the LSPI rate. At low calcium levels, near-zero LSPI rates were observed. The addition of zinc and molybdenum additives had a negative effect on the LSPI rate; however, this was only seen at higher calcium concentrations.

Mat material durability data in the form of fragility curves were generated in a critical temperature region for three intumescent mat materials considered for low temperature converter applications. The mat materials were tested in a tourniquet wrap converter configuration employing a cylindrical ceramic substrate. Prior to developing durability data for these mat materials, the test items were subjected to various environmental thermal and/or vibration aging conditions. Mat material fragility data were generated in terms of the dynamic force required to impose prescribed differential motion between the can and substrate, thereby, subjecting the mat material to a dynamic shearing like that expected during resonant excitation. As expected, it was found that the mat material capacity to resist shearing deformation decreased when the test samples were subjected to 36 hours of low temperature thermal cyclic aging.

Several techniques have been developed to measure the relative amount of splash and spray produced by vehicles when driven on wet roads at highway speeds under controlled conditions. This paper discusses considerations in the development of measurement techniques such as those utilizing photographs, a photometer, densitometer, spraymeter, and spray collector. The development of each technique is described. Some test data utilizing the photometer and densitometer techniques are presented in a comparison of two different trucks run on two different road surfaces with new and worn tires, fully loaded and unloaded, and under light and heavy road moisture conditions.

Forty-five cars were entered from 37 universities across the U.S. and Canada in the ninth annual Formula SAE Student Design Competition held on May 25, 26 and 27 at the University of Texas at San Antonio (UTSA). Thirty-six cars from 31 schools actually competed, but only 22 cars finished. The event included many firsts in Formula SAE. The SAE South Texas Section set a precedent by co-hosting the competition with the UTSA. The GM Sunraycer display and demonstration exhibited high technology and corporate support of Formula SAE. Total award funds (from various sponsors) exceeded those of previous events. New awards were given by new sponsors in 1989.

There has been an ongoing interest in replacing mineral oil with more biodegradable and/or fire-resistant hydraulic fluids in many mobile equipment applications. Although many alternative fluids may be more biodegradable, or fire-resistant, or both than mineral oil, they often suffer from other limitations such as poorer wear, oxidative stability, and yellow metal corrosion which inhibit their performance in high-pressure hydraulic systems, particularly high pressure piston pump applications. From the fluid supplier's viewpoint, the development of a definitive test, or series of tests, that provides sufficient information to determine how a given fluid would perform with various hydraulic components would be of interest because it would minimize extensive testing. This is often too slow or prohibitively expensive. Furthermore, from OEM's (original equipment manufacturer's) point of view, it would be advantageous to develop a more effective, industry accepted fluid analysis screening.

This paper discusses the techniques and diagnostic significance of atomic absorption, atomic emission, and infrared spectrometric analysis of crankcase lubricants, with the use of supplementary data where pertinent. The parameters affecting used oil analytical data are discussed in terms of examples from Army general purpose vehicle test engines. Wear metals in used gear oils are also discussed and examples are given. Analytical methods and their applications are fully described, and the equipment and procedures for infrared spectroscopy and gas chromatography techniques are outlined.

An untreated heavy distillate fraction from a mixture of Geokinetics and Occidental shale oils was hydrogenated at three levels of severity. The three products showed good ignition quality and met most of the current specifications for No. 2-D diesel fuel. Nitrogen contents ranged from 250 to 1890 parts per million. Good oxidation stability was obtained in the product with lowest nitrogen content. Stability of the other two products was marginal but would be improved by use of an antioxidant additive. The test fuels will be used in engine and combustion studies.

Polyurethane dispersions (PUDs) have seen rapid growth in recent years as alternatives to their solvent-based analogs. They offer the advantages of enabling low VOC formulations while providing superior appearance and mechanical properties. Polyurethane-acrylic hybrids combine the advantages of a polyurethane dispersion with the benefits of an acrylic emulsion. This synergistic combination offers properties such as good hardness development and chemical resistance in addition to enhanced mechanical properties. In this paper, we discuss new PUD-acrylic hybrids that are NMP and solvent-free, have a pendulum hardness of 100 oscillations compared to a standard acrylic emulsion that has 80; and offer excellent scratch and chemical resistance equivalent to that of an acrylic system. In addition to these, the new polyurethane dispersions provide good haptic qualities and have excellent adhesion to plastic substrates such as ABS, PC and PVC.